静态混合器气液两相流压降的数值模拟及实验研究

气泡流经过静态混合器的压降问题涉及到舰船动力系统性能的好坏。在分析了气泡平均驰豫时间的基础上,结合k ε湍流模型,利用平衡流模型模拟静态混合器内形成的稀疏湍流气泡流,得到了混合器内两相流流场。空气—水系统的压力降实验表明,计算流体力学模拟能够很好地预测SMV型静态混合器内气泡流的压降,是静态混合器设计的有效手段。     

［Bmim］BF4-H2O-Na2CO3离子液体双水相体系液液相平衡数据的测定与关联

用浊点法测定了四氟硼酸1-丁基-3-甲基咪唑—水—碳酸钠体系在常压30℃下的溶解度曲线及密度曲线，并用经验方程进行了关联。用浊点—密度法测定了该体系的液液相平衡数据，绘制了相应的相图。结果表明：双水相体系一相以离子液体和水为主，碳酸钠的含量很少，另一相以碳酸钠和水为主，离子液体的含量很少。该体系既可作为萃取分离体系，也可作为从水溶液中分离回收离子液体的初步体系。用Othmer-Tobias+Bancroft经验方程对相平衡数据进行关联，最大相对误差为94.99%， 最大平均相对误差为15.69%，关联结果不理想。提出用Othmer-Tobias经验方程+溶解度方程对其进行关联，最大相对误差为4.52%，最大平均相对误差为2.77%，关联精度较高，该方法可适用于有一组分含量较低的体系的液液相平衡的关联计算。     

采用DSC和FTIR对木材和API胶粘剂间反应的研究

采用差示扫描星热法(Differential Scanning Calormelry,简称DSC)和傅立叶变换红外吸收光谱(Fourier Transform Infrared Spectroscopy,简称FTIR)对木材和水性高分子异氰酸酯胶粘剂(Aqueous Polymer Isocyanate,简称API)的胶接机理进行了研究。DSC和FTIR的试验结果均表明:API胶粘剂和木材间发生了化学反应:API胶粘剂和木材间发生的反应所需活化能远小于API胶粘剂的主剂+固化剂的活化能,亦即用API 胶粘剂胶接木材时发生的反应要比API胶粘剂本身的固化反应容易得多,同时从理论上证明使用API胶粘剂胶接木材时装配时间最长不应超过其活性期的一半时间,且装配时间越短越好;文中还研究了升温速率对API胶粘剂DSC图谱的影响。     

六偏磷酸钠的生产工艺

本文对六偏磷酸钠的性质、用途及生产工艺进行论述并介绍从日本引进１．５ｋｔ／ａ食品级六偏磷酸钠生产装置投产运行情况。     

On-line determination of supersaturation of a kcl-nacl aqueous solution based on density measurement

A method is developed for the calculation of the saturation temperature of a KCI-NaCI aqueous solution, based on the measurement of the density and temperature of a sample solution, and prior knowledge of the NaCl concentration. Experimental density and solubility data for solutions saturated with KCI in the temperature range of 299 to 321 K with concentrations of NaCl greater than 0.200 kg/kg H₂O were used to develop the empirical correlation allowing the calculation of the solution saturation level. The method is applicable in the on-line determination of the level of supersaturation in a KCI crystallizer in which the NaCl concentration is known. Knowledge of the prevailing supersaturation is necessary for the control of crystal purity and crystal size distribution in industrial potash crystallizers.     

鞋用水性聚氨酯胶粘剂的研究进展

介绍了水性聚氨酯鞋用胶粘剂制备方法、性能,以及用于提高水性聚氨酯耐水性、耐溶剂性和耐热性能的交联改性技术,综述了水性聚氨酯的国内外研究进展及其在制鞋领域中的应用情况。     

颗粒多孔表面强化沸腾传热动力学研究

通过对颗粒多孔层几何结构、沸腾两相流及传热的理论分析，提出了微型通道薄膜环状蒸发物理模型和沸腾传热机理，建立了颗粒多孔表面强化沸腾传热动力学模型。该动力学模型与实验数据吻合良好，可用于工程设计。     

丙烯酸改性聚氨酯的合成与性能的研究

采用聚丙烯酸酯与聚氨酯共混、以水性聚氯酯为种子乳液进行丙烯酸种子乳液聚合以及水性聚氨酯与丙烯酸接枝共聚3种方法分别得到丙烯酸改性水性聚氯酯，通过激光散射粒径仪测定乳胶粒的粒径、乳胶膜的透明性、傅里叶变换红外光谱(FTIR)结构分析以及扫描电镜(SEM)对乳胶膜结构和表面形貌进行分析。结果表明：采用种子乳液聚合反应和接枝反应所得到的丙烯酸改性水性聚氯酯乳液乳胶粒粒径比水性聚氨酯的粒径显增大，表现出良好的相容性；由种子乳液聚合和接枝聚合制备的丙烯酸改性水性聚氯酯胶膜中颗粒与颗粒之间结合紧密，表面光亮、透明。     

Advancements in the design and validation of an air pollution integrated assessment model for Spain

This paper describes the design and application of the Atmospheric Evaluation and Research Integrated model for Spain (AERIS). Currently, AERIS can provide concentration profiles of NO₂, O₃, SO₂, NH₃, PM, as a response to emission variations of relevant sectors in Spain. Results are calculated using transfer matrices based on an air quality modelling system (AQMS) composed by the WRF (meteorology), SMOKE (emissions) and CMAQ (atmospheric-chemical processes) models. The AERIS outputs were statistically tested against the conventional AQMS and observations, revealing a good agreement in both cases. At the moment, integrated assessment in AERIS focuses only on the link between emissions and concentrations. The quantification of deposition, impacts (health, ecosystems) and costs will be introduced in the future. In conclusion, the main asset of AERIS is its accuracy in predicting air quality outcomes for different scenarios through a simple yet robust modelling framework, avoiding complex programming and long computing times.     

水性聚氨酯胶黏剂发展概况

简述可水分散性多异氰酸酯胶黏剂、乙烯基聚氨酯水性胶黏剂和水分散性聚氨酯(PUD)胶黏剂等水性聚氨酯胶黏剂国内外应用和技术发展状况,对我国水性聚氨酯胶黏剂的发展提出初步看法和建议。