建(构)筑物机械拆除方法综述

介绍了几种常用的建(构)筑物机械拆除方法,对其工作原理、特点、应用条件及局限性加以分析和说明。     

矿用立式旋风水膜除尘器除尘性能的试验研究

本文通过对立式旋风水膜除尘器除尘性能的模型试验,揭示了几个主要参数对其除尘性能的影响,确定了合理的取值范围,对该种除尘器的设计和应用提供了依据。     

Natural zeolite utilisation in pollution control: A review of applications to metals' effluents

This paper assesses the potential of natural zeolite utilization as a low-cost ion-exchange and sorbent material in pollution control and recovery of metals. The improvement of the purity of natural zeolites coupled with their chemical modification capabilities in order to provide specific properties may provide a cost-effective alternative for the treatment of heavy metal contaminated soil and water. The application of natural zeolites in industrial pollution control is becoming important and the level of technical effort is increasingly expanding. The extent of application is unlikely to be related solely to their low cost, but also to improved properties and performance characteristics, which will advance the practical implementation of natural zeolites' technology.     

Simulation of water and nitrogen dynamics in soils during wastewater applications by using a finite-element model

A mathematical model was developed to simulate water movement, mass transport, and nitrogen transformations in soils during wastewater applications. The model is one-dimensional and based on the Galerkin finite-element method. The submodel of mass transport of nitrogen incorporates the convection-dispersion processes of ammonium and nitrate nitrogen, nitrification, denitrification, ammonium exchange and uptake of ammonium and nitrate ions. The accuracy and validity of the proposed model was examined by comparison with an explicit-implicit finite-difference model results. The model was used for simulation of water and nitrogen dynamics during wastewater application in homogeneous and multi-layered soils under different N concentration, rate, duration and scheduling of application.     

Prebiotic synthesis of sequential peptides on the Hadean beach by a molecular engine working with nitrogen oxides as energy sources

Addressing the still open question of the prebiotic origin of sequential macromolecules (peptides, nucleic acids) on the primitive Earth, we describe a molecular engine (the primary pump), which works at ambient temperature and continuously generates, elongates and complexifies sequential peptides. This new scenario is based on a cyclic reaction sequence, whose keystep is the activation of amino acids into their N‐carboxyanhydrides (NCA) through nitrosation by NOx. This process could have taken place on tidal beaches; it requires a buffered ocean, emerged land and a nitrosating atmosphere. With the help of geochemical studies and computer simulations of atmosphere photochemistry, we show that the primitive Earth during the Hadean may have satisfied all these requirements. © 2001 Society of Chemical Industry.     

Oxidative radical generation via nitrogen dioxide dimer conversions induced by amide groups of macromolecules

The features of initiation of free radical reactions in polymers by dimers of nitrogen dioxide are considered. The conversion of planar dimers into nitrosyl nitrate in the presence of amide groups of macromolecules has been revealed. Nitrosyl nitrate initiates radical reactions in oxidative primary process of electron transfer with formation of intermediate radical cations and nitric oxide. As a result of subsequent reactions, nitrogen‐containing radicals are produced. The dimer conversion has been exhibited by estimation of the oxyaminoxyl radical yield in characteristic reaction of p‐benzoquinone with nitrogen dioxide on addition of aromatic polyamide and polyvinylpyrrolidone to reacting system. The isomerization of planar dimers is efficient in their complexes with amide groups, as confirmed by ab initio calculations. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Motion compensated film restoration

Motion picture films are susceptible to local degradations such as dust spots. Other deteriorations are global such as intensity and spatial jitter. It is obvious that motion needs to be compensated for before the detection/correction of such local and dynamic defects. Therefore, we propose a hierarchical motion estimation method ideally suited for high resolution film sequences. This recursive block-based motion estimator relies on an adaptive search strategy and Radon projections to improve processing speed. The localization of dust particles then becomes straightforward. Thus, it is achieved by simple inter-frame differences between the current image and motion compensated successive and preceding frames. However, the detection of spatial and intensity jitter requires a specific process taking advantage of the high temporal correlation in the image sequence. In this paper, we present our motion compensation-based algorithms for removing dust spots, spatial and intensity jitter in degraded motion pictures. Experimental results are presented showing the usefulness of our motion estimator for film restoration at reasonable computational costs. Received: 9 July 2000 / Accepted: 13 January 2002 Correspondence to:S. Boukir     

Laboratory simulated slipstream testing of novel sulfur removal processes for gasification application

The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is investigating an Early Entrance Coproduction Plant (EECP) concept to evaluate integrated electrical power generation and methanol production from coal and other carbonaceous feedstocks. Research, development and testing (RD&T) that is currently being conducted under the project is evaluating cost effective process systems for removing contaminants, particularly sulfur species, from the generated gas which contains mainly synthesis gas (syngas), CO₂ and steam at concentrations acceptable for the methanol synthesis catalyst. The RD&T includes laboratory testing followed by bench-scale and field testing at the SG Solutions Gasification Plant located in West Terre Haute, Indiana. Actual synthesis gas produced by the plant was utilized at system pressure and temperature for bench-scale field testing.     

An integrated biodesulfurization process,including inoculum preparation,desulfurization and sulfate removal in a single step,for removing sulfur from oils

BACKGROUND: A single‐stage reactor, in which the growth of bacterial culture, induction of desulfurizing enzymes, and desulfurization reaction are carried out in a single step, was adopted to investigate desulfurization of dibenzothiophene (DBT) at high cell densities. Rhodococcus erythropolis, IGTS8 was used as the biocatalyst. Optimal conditions for bacterial growth and DBT desulfurization were investigated. RESULTS: Optimization of fermentation conditions was necessary to obtain high cell densities including controlling accumulation of acetate. Under optimal operating conditions, the maximum optical density at 600 nm (OD₆₀₀) was measured to be 26.6 at 118 h of cultivation. When biodesulfurization of DBT in model oil with a high cell density culture of IGTS8 was investigated, accumulation of sulfate was found to limit the extent of desulfurization. A sulfate removal step was added to obtain a single‐stage integrated biodesulfurization process. Sulfate removal was achieved via an aqueous bleed stream and use of a separation unit to recycle the organic phase. CONCLUSION: A proof of principle of a complete system capable of biocatalyst growth, induction, desulfurization and by‐product separation was demonstrated. This system enables simplification of the biodesulfurization process and has potential to lower the operating cost of the bioprocess. Copyright © 2008 Society of Chemical Industry