聚变堆实验包层模块第一壁温度场及热结构分析

铍相对于众多聚变反应堆的第一壁护甲材料,有着许多优点,这些优点使它和钨及碳基材料一起被选作国际热核聚变实验堆（ITER）第一壁的候选防护材料。对中国氦冷固态增殖剂实验包层模块（CHHCSBTBM）第一壁进行多场耦合模拟分析结果表明,使用表面热负荷模拟分析时,未考虑中子负载情况下,模拟分析结果与其它结果有较大出入,故使用表面热负荷模拟分析时必须考虑中子负载情况。而对第一壁热结构分析表明,铍保护板的应力超过了其许用应力,可以寻找其它铍合金或第一壁护甲材料以满足第一壁护甲材料热结构应力要求。     

Current Status of the Fabrication of Li4SiO4 and Beryllium Pebbles for CN HCCB TBM in SWIP

Tritium breeder and neutron multiplier as functional materials play an important role not only in ITER test blanket module (TBM) but also in fusion reactor. The paper describes the status of the fabrication of the two materials in Southwestern Institute of Physics (SWIP). Li4SiO4 pebbles were fabricated by melt-spraying method. Most of the pebbles with the diameter of 1.0 mm are well spherically shaped. The properties of the pebbles have been investigated. The results show that the pebbles produced by this method have a high density of 93% TD (theoretical density). It was also found that the open/closed porosity will be decreased after thermal treatment, but the average crush load will be increased to 7 N. The rotating electrode process (REP) has been adopted to produce beryllium pebble for impurity control and mass production. The pebbles with the diameter of 1.0 mm were produced by REP. The beryllium pebbles produced by REP look almost perfectly spherical with a very smooth surface and a high density of 98% TD. The test results indicate that REP method has excellent prospects for the fabrication of beryllium pebbles and the attractiveness of their properties.     

高氟铍矿石熔炼过程中脱氟研究

高氟铍矿石在熔炼过程中配入氢氧化铝来脱除其中的氟。结果表明,在配入5%Na2CO3、9.3%Al(OH)3、1 400～1 500℃熔炼20min的情况下,BeO回收率达到96%以上,脱氟效果良好(铍玻璃F/BeO能控制在15%以内)。为高氟铍矿石的工业应用探索出新的冶炼途径。     

Calculation of Symmetric Stretching Frequency in Molten BeF2 by Molecular Dynamics Method

The molecular dynamics method was applied to molten BeF₂, in which the pair potentials of the Born-Mayer-Huggins type were employed. The Fourier transform of the distances between a Be²⁺ ion and its nearest neighboring F^? ions averaged over total 12 Be²⁺ ions gave the frequency of about 175 cm^?1 as the symmetric stretching frequency which is in satisfactory agreement with 282 cm^?1 obtained with Raman spectroscopy.

The self-diffusion coefficients of Be²⁺ and F^? ions were estimated to be 2×l0^?10m²/sec and the internal energy was ?2,559 kJ/mol at 973 K.     

Scattering of 14.1 MeV Neutrons by 6Li, 7Li, 9Be, 10B and 11B

Using a time-of-flight spectrometer, the differential cross sections were measured for the elastic and inelastic scattering of 14.1 MeV neutrons by ⁶Li, ⁷Li, ⁹Be, ¹⁰B and ¹¹B. In the case of elastic scattering by ⁷Li and ¹⁰B, correction was applied to subtract the contribution of inelastic scattering from the unresolved first excited state, after which, the elastic scattering data were compared with predictions based on the optical model. The potential parameters derived with a seven-parameter search yielded angular distributions agreeing with the present experimental data. The expressions for these parameters are presented as a function of mass number.

The experimental data on inelastic scattering were analyzed with the distorted wave Born approximation. The deformation parameters were estimated to be nearly equal to or larger than unity for these nuclei.     

The Separation of Beryllium from Selected Elements Using the Dipex® Extraction Chromatographic Resin

Abstract

An extraction chromatographic resin containing the acidic chelating organophosphorus extractant, Dipex^®, sorbed onto an inert polymeric substrate has been evaluated for the separation of beryllium from a wide range of elements. The elements selected comprise those which can interfere with the determination of beryllium by inductively coupled plasma‐atomic emission spectroscopy (ICP‐AES) and matrix elements which commonly occur in environmental and industrial samples. Based on batch uptake measurements, a method that separates beryllium from all potential ICP‐AES spectral interfering elements using a single extraction chromatographic column is outlined. The chromatographic parameters of the separation method have been optimized using simulated samples generated using the digestion process employed in beryllium analyses by the Y‐12 National Security Complex and simulated ground water samples.     

铍板材深冲压成形异形件探讨

冲压成形是金属板材加工异形件的最基本方式。金属材质不同,冲压成形异形件的难易程度不同,主要影响因素是冲压成形性能和冲压成形极限。文章结合铍板材的冲压成形性能和冲压成形极限,对铍板材冲压成形异形件的难易性作了探讨。     

铍铜合金的研究进展及应用

着重介绍了铍铜合金的性能.热处理工艺特点及研究进展,并综述了近年来铍铜在计算机、电子工业、汽车行业、模具行业等一些领域的应用.     

Be元素对7475Al合金再结晶及性能的影响

通过再结晶退火方法 ,研究了 Be元素对 7475 Al合金的硬度—保温时间关系曲线、再结晶体积百分数—保温时间关系曲线及晶粒度的影响 .结果表明 :在 7475 Al合金中加入一定量的 Be,能有效地提高合金再结晶温度 ,降低再结晶速度 ,能使合金硬度提高近 1倍 ,同时还可使合金晶粒有效地细化 .     

Mg-9Al-0.5Zn-0.3Be熔体表面氧化行为

在Mg 9Al 0 .5Zn合金中添加 0 .3%铍 ,镁合金液抗氧化性能得到极大提高 ,可以直接暴露在大气中熔炼。X射线衍射表明 ,合金表面有结构远较氧化镁致密的氧化铍生成 ,从而导致整个氧化膜致密程度提高。利用俄歇电子能谱 (AES)进行氧化膜元素深度剖析发现 ,在含 0 .3%铍的镁合金液表面生成的氧化膜可以分为 3个亚层 :最外层为氧化镁层 ;中间层为致密复合层 ,由氧化铍、氧化镁和氧化铝组成 ;内层为氧化膜向基体的过渡层。热力学分析表明 ,氧化膜中的这种分层结构同镁的高蒸汽压以及自由能变化吻合。