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31.
SiO2 functional films were deposited on the surface of titanium by plasma assisted chemical vapour deposition(PACVD) and the composition of films was studied by XPS. Samples deposited with SlOE films were immersed in different concentration simulated body fluid(SBF) for biomimetic deposition of hydroxyapatite(HA). The results show that SiO2 functional films deposited on titanium surface with PACVD have good bioactivity. Hydroxyapatite is formed while titanium coated with SlOE is immersed in simulated body fluid for seven days. 相似文献
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浆料发泡法制备生物活性多孔钛及其性能 总被引:10,自引:0,他引:10
应用传统的浆料发泡法,通过孔隙优化,成功制备出力学性能与骨匹配的多孔钛。扫描电镜分析发现其孔隙相互连通成三维网状结构;经碱热处理的多孔钛在模拟体液中浸泡14d后,表面被一层类骨磷灰石覆盖,具有良好的生物活性。此多孔钛有望成为理想的负重骨缺损修复材料。 相似文献
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TiO2纳米管阵列的热稳定性及生物活性的研究 总被引:4,自引:0,他引:4
通过电化学阳极氧化法,在纯钛片表面制备得到TiO2纳米管阵列。研究了TiO2纳米管阵列的热稳定性,并通过模拟体液浸泡研究了其生物活性。采用扫描电镜(SEM)和X射线衍射(XRD)分别对纳米管阵列的形貌和物相进行表征。结果表明,当热处理温度为300℃时,TiO2纳米管由无定形向锐钛型转变,温度升到500℃时转变为金红石型,升到600℃时TiO2纳米管阵列出现坍塌,700℃热处理时其形貌完全被破坏。生物活性研究表明,具有TiO2纳米管阵列的钛片经氢氧化钠溶液活化后具有良好的生物活性,能在模拟体液中诱导生成磷灰石。 相似文献
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Victor J Morris Nicola C Woodward Allan P Gunning 《Journal of the science of food and agriculture》2011,91(12):2117-2125
Atomic force microscopy (AFM) is a nanoscience tool that has been used to provide new information on the molecular structure of food materials. As an imaging tool it has led to solutions to previously intractable problems in food science. This type of information can provide a basis for tailoring food structures to optimise functional behaviour. Such an approach will be illustrated by indicating how a basic understanding of the role of interfacial stability in complex foods systems can be extended to understand how such interfacial structures behave on digestion, and how this in turn suggests routes for the rational design of processed food structures to modify lipolysis and control fat intake. As a force transducer AFM can be used to probe interactions between food structures such as emulsion droplets at the colloidal level. This use of force spectroscopy will be illustrated through showing how it allows the effect of the structural modification of interfacial structures on colloidal interactions to be probed in model emulsion systems. Direct studies on interactions between colliding soft, deformable droplets reveal new types of interactions unique to deformable particles that can be exploited to manipulate the behaviour of processed or natural emulsion structures involved in digestion processes. Force spectroscopy can be adapted to probe specific intermolecular interactions, and this application of the technique will be illustrated through its use to test molecular hypotheses for the bioactivity of modified pectin molecules. Copyright © 2011 Society of Chemical Industry 相似文献
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Zuming Liu Guangfu Yang Xianghua Qin 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2001,76(11):1154-1158
In a search for novel agrochemicals with high activity and low toxicity, a series of diheterocyclic compounds containing 1,2,4‐triazolo[1,5‐a]pyrimidine and 1,3,4‐oxadiazole rings were designed and synthesized by a four‐step synthetic route starting from 2‐mercapto‐5,7‐dimethyl‐1,2,4‐triazolo[1,5‐a]pyrimidine. The structures of all the compounds synthesized were confirmed by 1H NMR, mass spectroscopy and elemental analysis. The preliminary bioassay against Brassica campestris L and Echinochloa crusgalli Beavu indicated that the title compounds displayed herbicidal activity at the concentration of 100 ppm and that compounds 5a (R = CH3), 5d (R = C2H5) and 5f (R = i‐Bu) were found to have particularly high activities. In addition, the results of an in vivo test at a concentration of 50 ppm showed that all the compounds prepared were highly active against Rhizoctonia slain, but not active against Fusarium oxysporum, Gibberella zeave and Phoma sparagi. A further in vivo test showed that compound 5j possessed better fungicidal activity against Rhizoctonia solani at a concentration of 200 ppm than Carbendazim and Validamycin A, which are well known for their fungicidal activity against Rhizoctonia solani. To our knowledge, this is the first report that 1,2,4‐triazolo[1,5‐a]pyrimidine derivatives display fungicidal activity against Rhizoctonia solani. © 2001 Society of Chemical Industry 相似文献