Antioxidizing component,musizin, inrumex japonicus houtt

A substance with antioxidant properties was obtained from the hexane extract of roots ofRumex japonicus Houtt. The active component of the hexane extract was isolated and characterized as 2-acetyl-1,8-dihydroxy-3-methyl naphthalene, trivially named musizin (MUS). The antioxidant activities of MUS in six types of fats and oils were higher than that of butyl hydroxyanisole (BHA) and δ-tocopherol (δ-TOC). Together, TOC and MUS have a synergistic effect, because comparable amounts of either had lower antioxidant activity than various combinations of the two antioxidants. When we studied the antioxidant properties of a mixture of MUS and δ-TOC with methyl linoleate (MeLH), we found that the rates of destruction of the two antioxidants were comparable, but that their destruction occurred sequentially, with MUS first followed by δ-TOC, after which the oxidation of MeLH quickly occurred. Comparison of the antioxidant activity of MUS and its analogs suggests that only one of the two hydroxyl groups in MUS is involved in its antioxidant activit. Intermolecular hydrogen bonding may be involved.     

远场激光能量密度分布的数值与图像估算

激光在大气传输过程中,由于同大气分子与气溶胶粒子之间的相互作用而产生了一系列的效应,即大气衰减和大气湍流效应,导致能量不断减弱,并影响激光的远场能量密度分布.根据设计的激光远场能量密度分布测试系统进行外场实际试验测试,只能获得指定位置上的远场能量密度分布数据和激光光斑图像,为了获得任意位置的激光传输特性,研究了大气衰减和大气湍流对激光传输的影响.根据上述系统测得的指定位置的光斑图像及能量分布数据,通过软件仿真分析,估算任意位置的激光光斑能量密度分布,通过伪彩色变换,将激光光斑的灰度图像转换为连续变化的伪彩色图像,可以直观地观察光斑的远场能量密度分布.     

压磁应力传感器差动信号检测电路设计

由于压磁应力传感器结构对称性存在着差异,致使传感器输出信号的零点值调节困难,而传统的电路输出交流信号,不便于信号处理。采取对两组检测信号先整流滤波,再进行分压式比较,使得输出信号直接为直流信号。利用所设计的电路进行了实验,通过调节电位器即可实现传感器零点值的准确调节。通过实验验证了电路的性能,也验证了磁测应力传感器的性能。     

宽度和长度缩减对体硅和SOI nMOSFETs热载流子效应的影响

针对标准体硅在CMOS和PD SOI CMOS两种工艺下的nMOSFETs,研究了沟道长度和宽度缩减对热载流子效应的影响。实验结果表明,在两种工艺下,热载流子的退化均随着沟道长度的减小而增强;然而,宽度的减小对两种工艺热载流子退化的影响却截然不同：体硅工艺的热载流子退化随宽度的减小而增强,SOI工艺的热载流子退化随宽度的减小而减小。基于界面态对热载流子效应的影响深入分析了长度减小导致两种工艺下热载流子退化均加重的原因;同时基于边缘电场分布对热载流子效应的影响解释了宽度减小导致两种工艺下热载流子退化规律截然相反的现象。研究结果对于实际深亚微米工艺下,集成电路设计中器件工艺尺寸和版图结构的选择具有一定指导意义。     

Loss of Curing Agent During Thin Film (Droplet) Curing of Thermoset Material

Recently, it has been reported by our group and others^1.2 that loss of curing agent is encountered during the curing of small droplets or thin films of amine cured epoxies. In our earlier study³ results were reported on loss of curing agent in small droplets used in conducting the rnicrobond, single fiber test for determination of interfacial shear strength (ISS). It was reported that use of a volatile curing agent (meta-phenylene diamine (m-PDA) with DGEBA resin) resulted in increasing amounts of curing agent being lost (as measured by T₈ of the cured droplets) with decreasing droplet size during the processing procedure. Droplets smaller than 150 micrometers were seen to lose up to 40% of the curing agent leading to alteration of the mechanical properties of the droplet and, therefore, causing measured values of ISS to be exceedingly low. Use of a less volatile curing agent (Jeffamine 700, a polyether diamine, Texaco Specialty Chemicals) in combination with DGEBA resin produced results which indicated that loss of curing agent was not occuring. This study was undertaken to show the relationships between film (or droplet) size and the amount of curing agent lost (during the processing) for three different aminecured epoxy systems.     

A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

The object of the present study was to investigate the effect of superimposed dynamic and static stresses on mechanical and thermal properties of some epoxy adhesives. It was found that combinations of shear creep and torsional oscillations, applied simultaneously to adhesive joints at temperatures within the glassy range of the adhesive, led to strengthening of the joints in shear and to an increase in the glass transition temperature of the adhesive. Similar loading stresses applied at temperatures close to the T_g of the adhesive, led to opposite effects on the above mentioned properties of the joints. The width of the glassy-rubbery transition of the adhesives increased, in the whole range of temperatures used in this study and for all epoxy compositions, as a result of subjecting the joints to superimposed dynamic and static stresses. The broadening of the glass transition was interpreted as a result of the stiffening of polymer network during the combined stressing experiments. A linear relationship was found between the area of endothermal peaks in the first DSC scan of specimens subjected prior to test to superimposed dynamic and static stresses at temperatures below T_g, and the shear strength of the joints. In agreement with this observation and with literature data, a linear relationship was revealed also between the glass transition temperature of the resins (measured in the first DSC scan) and the shear strength of the joints. Based on experimental observations and on some literature information, it was suggested that the strengthening of the joint, as well as the changes in thermal properties of the adhesives, are mainly due to physical processes, such as short-range orientation of network chains and an increase in intermolecular interaction between highly polar sites of the network. The possibility that superimposed stressing led to changes in chemical crosslinking was discussed but it seems that no such reactions occurred.     

光化学反应中的磁场效应 Ⅱ.电子转移光敏化1,2-二苯乙烯的顺反异构化反应

前文报道了外加磁场对吸附在硅胶表面上的芳砜光解反应的影响,本文报道外加磁场影响光化学反应的另一个例子——电子转移光敏化1,2-二苯乙烯的异构化。 近年来电子转移光敏化反应引起了有机光化学家们的极大注意。一些异构化、重排、裂解、氧化反应都可以通过电子转移机理敏化。电子转移光敏化的机理可以用(1)描述。图中A和D分别代表电子的受体和给体。     

SFT中的因素作用路径与作用历史

为了描述SFT中系统或元件在不同工作环境状态下经历变化的特征,提出了因素作用路径和作用历史的概念。作用路径描述系统或元件在不同工作状态变化过程中所经历状态的集合。作用历史描述经历作用路径过程中的可积累状态量。给出使用作用路径和作用历史分析问题的步骤。列举一例子,计算在设定条件下的元件维护成本。计算作用路径分别为AB和ACB两种,作用历史中使元件故障概率等于20%的维护成本,该维护成本是通过调整使用时间t和使用温度c产生的。最后给出以实例为背景的作用历史计算方法的不足、面临的问题和可能的解决方法。     

目标追求的入世和出世对框架效应的影响

采用目标追求的入世、出世量表筛选出入世水平高组(70名)和低组(72)大学生,出世水平高组(68名)和低组(71名)大学生,探讨不同入世、出世水平大学生在奖学金申请、选修课和求职应聘三种决策任务领域上的框架效应及其在性别上的特点。结果发现:(1)不同出入世水平大学生在决策任务上的框架效应特点不同,入世水平高分组和低分组、出世水平高分组和低分组在奖学金申请问题上均出现了经典的框架效应;(2)在奖学金申请问题上,男性被试和女性被试的选择出现了明显的经典的框架效应。     

狭义相对论与钟慢效应关系再认识--纪念狭义相对论创立110周年

从爱因斯坦建立狭义相对论的科学方法与狭义相对论理论的逻辑构成入手,综合运用A· P·弗伦奇在国际著名的改革教材“美国麻州理工学院物理学导论丛书”第二卷《狭义相对论》中的研究观点和闵可夫斯基的四维时空理论,阐明狭义相对论与钟慢效应之间的正确关系。