Discrete-continual model of flame propagation in a gas suspension of metal particles. I. One-dimensional approximation

Experimental data on combustion of magnesium particles in oxygen-containing gas mixtures are analyzed and generalized, which allowed us to develop a semi-empirical mathematical model that takes into account the integral effect of the initial particle size, pressure, and velocity of the oxidizing flow on combustion. Flame propagation in an air suspension of fine magnesium particles is considered in a one-dimensional approximation. For this purpose, a discrete-continual model of flame propagation in a gas suspension of metal particles is developed. The flammability limits in a vessel, caused by heat losses into the ambient medium and by spatial nonuniformity of the distribution of disperse-phase particles, are numerically determined, and the influence of nonuniformity and bidispersion of a one-dimensional ensemble of particles on flame characteristics is studied.__________Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 2, pp. 81–93, March–April, 2005.     

工业聚合反应装置—Ⅶ.悬浮聚合反应器（下）

讨论了悬浮聚合反应器的放大问题及计算机控制技术，介绍了具有预分散器的悬浮聚合反应器和连续悬浮聚合反应器。     

P2成型机简介及Interbus-s总线故障分析

简要介绍了P2成型机各部分的结构组成及电控系统的组成、Interbus-s总线的结构特点。分析了Interbus-s总线上出现的故障情况，经排查及改进PLC程序排除了故障。     

高压旋喷锚杆在黄土深基坑支护中的模拟研究

为了研究高压旋喷锚杆支护体系在黄土深基坑工程中的工作性状,选取西安某深基坑支护工程为研究对象,运用MIDAS/GTS软件对该支护体系进行了有限元数值模拟,并与二次注浆锚杆支护体系的模拟结果进行了对比分析。结果表明:两种基坑支护方式均可满足该基坑支护的技术要求,但采用高压旋喷锚杆支护时,需要锚杆的总长度为二次注浆锚杆长度的62%,且高压旋喷锚杆筋体可实现回收,降低了锚杆施工对周围土层的干扰,其在黄土地区高边坡及深基坑支护工程中有着广阔的应用前景。     

超长、超大基坑开挖对邻近地铁结构安全影响的数值模拟分析

为了研究超长、超大基坑开挖对邻近地铁结构安全影响,以西安地铁2号线周边某基坑为工程实例,通过运用数值分析软件,结合场地的水文地质和工程地质条件,建立数值模型,进行施工过程的动态模拟,同时进行现场监测,经对比数值模拟结果及监测数据,表明运用PLAXIS软件能有效的模拟基坑开挖过程中的土体变形。同时工程采用的分段、分块开挖,中心岛顺做,周边预留土台反压、使用旋喷锚索的支护方案,对复杂条件下基坑开挖对邻近地铁结构的变形影响能起到有效的控制作用,可对类似工程的设计优化提供有益的参考及借鉴。     

斜拉桥预应力混凝土索塔锚固结构受力性能分析

为了研究U形与直线预应力束混合布置索塔锚固结构的受力特性,以国内某姊妹塔斜拉桥的菱形桥塔为例,采用通用有限元程序建立索塔锚固结构的节段有限元模型,分析索塔锚固结构在预应力荷载与斜拉索水平力共同作用下的受力情况。结果表明:在索塔锚固结构中采用U形与直线预应力束混合布置能较好的满足设计要求,使锚固区整体处于较为合理的压力状态之下,除局部的应力集中外,基本消除了斜拉索作用下顺桥向塔柱的拉应力;在齿块与塔柱内壁的结合处存在应力集中现象,应当引起足够的重视,施工时应严格控制施工质量。     

悬浮法合成固体粒状丙烯酸树脂

研究了悬浮法合成固体丙烯酸树脂颗粒。讨论了不同软硬单体配比对丙烯酸树脂颗粒的玻璃化转变温度、相对分子质量及其分布的影响以及不同的引发剂及悬浮剂对其聚合过程、最终产物形态及上述性能的影响。制得的丙烯酸树脂的数均相对分子质量用凝胶渗透色谱(GPC)测定为3.9×104～6.2×104,相对分子质量分布为2.04～2.32;用红外光谱图表征了制得的丙烯酸树脂结构。差示扫描量热法(DSC)测定了聚合物的玻璃化转变温度(Tg)。     

MACROPROCESS OF PARTICLE FORMATION IN SUSPENSION POLYMERIZATION OF STYRENE WITH INORGANIC STABILIZER SYSTEM

The macroprocess of particle formation from suspension droplets of styrene in a pdymerizationsystem was investigated.Inorganic hydroxyapatite or its mixture with polyvinyl alcohol as thepolymerization system was used.Those items such as the effects of the Weight fraction of dispersed-phase,the amount of the inorganic stabilizer and the agitation speed on the breakup and coalescence of thetransient dispersed drops etc.Were examined.Results showd that the dynamic behavior of the transi-ent polymer droplets changed in the presence of the suspension stabilizer during the reaction.     

LDA Measurements on a Turbulent Gas/Liquid/Fibre Suspension

Detailed continuous phase flow measurements (mean and RMS velocities) by Laser Doppler Anemometry (LDA) of a turbulent gas/fibre/liquid suspension in a rotary shear tester have been performed with simultaneous torque measurements. The model system comprises a refractive‐index matched suspension in the 4‐12% wt. range with gas contents up to 15% vol. The two transition points, found by Andersson and Rasmuson (2000), were detected also with gas present and appear at higher impeller speeds with increasing gas and fibre concentrations. Plotting RMS and mean velocities versus impeller speed and power input, it is found that both decrease with increasing gas and fibre contents.     

BaFe12O19/聚氨酯磁性复合微球的制备和表征

通过BaFe12O19硅烷偶联剂改性,聚乙二醇1000、甲苯二异氰酸酯在二甲苯溶液中预聚合,预聚物溶液在分散剂聚乙烯吡咯烷酮K30的水溶液中悬浮聚合,三步合成了BaFe12O19/聚氨酯复合微球.用扫描电镜、红外光谱仪、热重-差示扫描同步热分析仪和振动样品磁强计对微球的形貌、结构、玻璃化温度(Tg)和磁性能进行了表征.结果表明:合成的微球以BaFe12O19颗粒为核聚氨酯为壳.表面分布有微孔,微球粒径在400μm左右,粒径大小可通过控制反应条件调节.微球中磁性物质BaFe12O19的含量为11.11%(质量分数),Tg在290 ℃左右,耐热性能好,微球的饱和磁化强度为3.36×103 A/m,矫顽力为3.06×104 A/m.该复合微球是一种有潜在应用价值的新型血管内栓塞材料.