酯硬化水玻璃再生砂循环使用后的性能变化及应对策略

分析了酯硬化水玻璃砂多次再生使用后,其Na2O含量较大升高、溃散性显著下降、生产厚大铸型(芯)时硬透性变差并出现蠕变现象的原因,探讨了再生砂性能变化后的应对策略。认为:研究开发适于干法再生水玻璃砂的改性水玻璃、对再生砂实施表面处理、对旧砂进行高脱膜率的再生等,应是解决酯硬化水玻璃砂多次再生使用后溃散性恶化问题的主要措施;而控制再生砂的含水量、适当增加有机酯的加入量、CO2气体补充硬化等,是增加型(芯)硬透性和克服蠕变现象的主要方法。     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

Chemical nature of larval osmeterial secretions of papilionid butterflies in the generaParnassius,Sericinus andPachliopta

Volatile components of the larval osmeterial secretion ofParnassius glacialis (Parnassiinae, Parnassiini) consisted of isobutyric acid, 2-methylbutyric acid, and their methyl esters. In contrast, the osmeterial exudate ofSericinus montela (Parnassiinae, Zerynthiini) was characterized as monoterpene hydrocarbons comprising-myrcene (Major),-pinene, sabinene, limonene, and-phellandrene, whereas that ofPachliopta aristolochiae (Papilioninae, Troidini) was composed of numerous sesquiterpene hydrocarbons, including-himachalene,-amorphene, and germacrene-A, and a few oxygenated sesquiterpenoids. In these three species, the chemical nature of the secretions of the last and the penultimate instars was essentially of similar quality, suggesting that the three genera,Parnassius, Sericinus, andPachliopta, are assigned to homogeneous types.     

A Boronate Ester Driven Rechargeable Antibacterial Membrane for Fast Molecular Sieving

Membrane decorated with biocides is an effective way to suppress biofilm growth. However, their immediate biocidal effect usually suffers from a significant decline due to the irreversible consumption of the biocides. Here, a smart nanofiltration membrane is reported with rechargeable antibacterial capability that is fabricated by a facile interfacial polymerization via 3-aminophenylboronic acid and trimesoyl chloride on a polysulfone substrate. Biocides bearing diol groups can be grafted onto the membrane surface under neutral/alkaline condition and then released from the surface under acidic environment, due to the pH-responsive feature of boronate ester complexes. The resultant membrane exhibits integrated properties of fast bacterial inactivating efficiency, rechargeable antibacterial capability, and impressive stability. In addition, the achieved membrane shows remarkable separation efficiency to dye/monovalent salt system. The successful fabrication of the membrane with rechargeable anti-bacterial property provides new insights into the development of pH-responsive and sustainable antibacterial membranes.     

Analysis of image sticking on a real MVA Cell

Abstract— Image‐sticking phenomenon is one of the most important issues affecting LCDs, especially LCD TV. It is known that image sticking is caused by residual DC voltage. An analysis of the cause that induces image sticking on a real LCD cell is very difficult to perform and is rarely reported. In this paper, the impurities that cause boundary image sticking on a real MVA cell was analyzed by examining a cross section of a cell, the bulk LC layer, the vicinity of the LC layer, the LC layer/PI alignment film interface using microanalysis methods such as infrared micro‐spectroscopy (μ‐IR) and micro‐sampling mass spectrometry (μ‐MS). It is clarified that there is quite a bit of aromatic acid at the boundary of the image‐sticking area than in the normal area at the LC/PI alignment film interface on the color‐filter side, not the TFT side, and it is assumed that aromatic carboxylic acid, a negative charged material, is condensed at the LC/PI alignment film interface on the color filter side by an electrically driven DC component inducing an electric‐condenser residual DC voltage.     

Structure-activity relationships for analogs of (+)-(E)-endo-Β-bergamoten-12-oic acid,an oviposition stimulant ofHelicoverpa zea (Boddie)

-Bergamotenoic acid, a compound previously shown to stimulate oviposition inH. zea, was converted into a set of bicyclic analogs and tested with a set of acyclic side chain analogs to ascertain the molecular structure that maximizes insect behavioral response. While changes in the bicyclic ring elicited no variation in response, alteration in the side chain structure of-bergamotenoic acid resulted in significant changes in moth preference. Free rotation about the C-C bond proximal to the carboxylic acid group appears to be an important structural factor, since saturation of the side chain double bond significantly increased activity. The carboxylic acid group seems to be required for strong oviposition stimulation, since analogs lacking the carboxylic acid group exhibited no significant oviposition activity. Oviposition preference ofH. zea was also influenced by the length of the hydrocarbon chain to which the carboxylic acid is attached. While hexanoic acid was found inactive, the ovipositional preference for the heptanoic and octanoic acids was greatest for the one 8-carbon tested. This and other work suggest that carboxylic acids of specific chain lengths influence the oviposition behavior of bothHelicoverpa andHeliothis species and may be associated with host-plant selection. The potential use of this information in designing integrated pest management strategies for control ofH. zea is discussed.     

磷酸酯类表面活性剂的现状及发展

论述了磷酸酯类表面活性剂的分类、基本性能、特性及应用,介绍了磷酸酯类表面活性剂的发展状况。     

吲哚-2-羧酸的合成工艺研究

以苯肼和丙酮酸乙酯为起始原料，利用多聚磷酸催化成环，合成了重要的医药中间体吲哚-2-羟酸。每步反应平稳，总收达到66％。     

2,2-二异丙基丙腈的合成

针对原有工艺条件的操作条件苛刻和反应原料贵的缺点,设计并实施了一种制备2,2-二异丙基丙腈的方法.首先,在吡啶的存在下,甲磺酰氯与异丙醇缩合制备异丙基甲磺酸酯.不经分离,直接与丙腈反应,在氨基钠的作用下发生缩合反应,合成得到2,2-二异丙基丙腈,总收率81.3％,含量98％.结果表明:能有效通过改变起始原料和工艺过程,使得原料易得,操作条件温和,更好地满足工业化生产要求,具有潜在的工业化价值.     

循环流化床灰对聚羧酸减水剂竞争吸附的影响研究

为研究循环流化床灰对聚羧酸减水剂竞争吸附的影响,通过在Ⅱ级粉煤灰中掺加无水硫酸纳、二水硫酸钙和氧化铁的方式来改变粉煤灰中三氧化硫和氧化铁含量,使其化学成分接近循环流化床灰,利用成分单因素分析的方法,测试减水剂水泥浆体的净浆流动度、zeta电位和混凝土性能.研究结果表明循环流化床灰中的三氧化硫和氧化铁对聚羧酸减水剂的吸附有明显负面影响,当可溶性硫酸盐掺量达到胶凝材料的3%、氧化铁掺量达到6%时,相应浆体均失去流动性.Zeta电位试验表明随着无水硫酸钠和氧化铁掺量的增大,Zeta电位绝对值越小,粒子间相互斥力越弱,分散性越差,分散体系就越不稳定.混凝土性能试验表明无水硫酸钠和氧化铁的掺入使得混凝土的流动性和抗压强度均变小,坍落度由220 mm降至125 mm,强度降低幅度最高达45%.