Electrochemical and surface-enhanced Raman spectroscopy studies of 4-phenylpyridine adsorption at the gold/solution interface

The adsorption of 4-phenylpyridine (4-PhPy) on the Au electrode was examined using conventional electrochemical techniques: cyclic voltammetry and impedance measurements and also by surface enhanced Raman spectroscopy (SERS) in a wide range of electrode potentials. Electrochemical results indicate the strong adsorption of 4-Phpy molecules, particularly at the positively charged Au electrode. The wide shoulder of capacity close to the pzc suggests that the composition and/or the structure of 4-Phpy monolayer change with the sign of the surface charge on the electrode. Investigation of integrity of adsorbed layer, however, indicates that adsorbed molecules do not form tight, compact monolayer even in the case of adsorption from saturated solution. SERS spectra provided evidence for gradual, potential-induced reorientation of the molecular plane with respect to the surface, from nearly vertical in the negatively charged electrode, to more flat at the positively charged metal surface.     

关于中压电缆网双环接线方式供电能力的分析

结合北京地区现阶段对相关技术的规定,以实际供用电方案为例,对中压电缆网双环接线方式的供电能力进行深入讨论。通过设计环网单元划分,发现某些条件下双环网供电能力可以得到进一步提升。     

离网型太阳能光伏发电系统设计研究

离网型太阳能光伏发电系统是太阳能光伏发电系统的重要组成。它具有灵活度高、分布广、项目成本低等优点。本文主要对现有离网光伏发电系统设计过程进行分析。     

城市轨道交通车站通过能力仿真模型研究

以城市轨道交通站前接轨站和站后折返站为例分析了列车在车站的详细作业过程,提出了车站的抽象模型.基于车站模型设计了列车进路搜索算法,开发了车站列车运行过程仿真系统.该系统可以对城市轨道交通车站进行仿真建模,仿真列车在车站的作业过程,并进行车站通过能力的分析计算.     

一种基于RAN架构无线接入网系统容量最大化的功率分配算法

针对新型RAN架构无线接入网中功率分配问题进行研究, 建立系统容量最大化的最优化数学模型, 提出了一种基于RAN架构无线接入网的系统容量最大化的功率分配算法, 并且应用人工鱼群算法求解了算法中目标函数的全局最优解, 即一组使系统容量最大化的发射功率。仿真结果表明, 与现有的分布式网络架构中非合作的功率控制博弈算法相比, 新算法可以显著提高系统容量, 即证明了该算法的有效性。     

Effect of birch (Betula pendula) bark and food protein level on root voles (Microtus oeconomus): II. detoxification capacity

The effect of protein and birch bark powder (BBP) content of forage on detoxification capacity of root voles (Microtus oeconomus) was studied. Young voles were fed with eight different diets for two weeks. Individuals on low (3%) protein diets had significantly lighter livers and kidneys than those on moderate (6%) or high (12%) protein diets. Birch bark powder addition did not have significant effect on organ weight. Detoxification was significantly induced, apparently due to secondary compounds in BBP. The activity of ethoxyresorufin-O-dealkylase (EROD) was high when protein content or BBP concentration in forage was high as compared to low protein diets or diets containing no BBP. Glucuronidation, on the other hand, was not induced by BBP. High BBP content caused serious physiological stress to the voles. The only individuals surviving were those capable of sufficiently allocating energy and protein to detoxification.     

基于SDN的本地综合承载传送网技术研究

该文通过对SDN本地综合承载传送网技术应用现状的分析,明确社会使用的需求,进而提出构建SDN的本地综合承载传送网技术网络架构和模型的方法,对SDN的本地综合承载传送网技术进行全面的分析。     

高负荷下聚酯工艺参数的优化

介绍原 2 0万t/a装置增容到 2 4万t/a时的工艺参数优化。PTA平均粒径 95～ 110 μm ,n(EG) /n(PTA) =2 .6～ 2 .7,酯化液位 63 %～ 64 % ,温度 2 92～ 2 96℃ ;乙二醇锑催化剂 ,稳定EG、DEG量 ,选择TiO2 消光剂 ,滤除凝聚粒子 ;预缩聚温度 2 87～ 2 89℃ ,压力 2 .4～ 2 .8kPa,液位 42～ 48cm ;终缩聚温度 2 90～ 2 91℃ ,压力 2 .5～ 3 .0hPa,液位 60～ 62cm ,搅拌速度 2 .7r/min。     

生物滴滤器净化苯/甲苯废气的对比

在不同模拟工况下研究生物滴滤器对低浓度苯、甲苯气体的净化性能.以苯和甲苯为目标污染物,采用陶瓷拉西环作为生物滴滤器填料,选用先期筛选驯化的苯、甲苯专性降解菌种对填料进行接种挂膜.结果表明:在气体流量为60～150L/h(对应的苯、甲苯停留时间分别为11.25～28.12s和10.6～26.4s),苯、甲苯入口气体浓度分别为0.61～4.14g/m3,0.43～4.40g/m3的条件下,生物滴滤器对苯、甲苯的最大生化去除负荷分别为333g/(m3.h)和593.4g/(m3.h),甲苯与苯相比更易被微生物降解,镜检表明苯、甲苯系统生物膜中的优势菌种都为短杆菌,密度分别达2.3×109CFU/ml和1.52×1011CFU/ml.     

高压旋喷桩复合地基承载特性的有限元分析

结合工程实际,运用大型有限元分析软件ANSYS分析了不同桩长、不同桩土模量比和不同桩间距情况下高压旋喷桩复合地基的承载特性.结果表明,该地基存在有效桩长,当桩土模量较合适时,该地基能够发挥最大作用;同时运用ANSYS优化功能,得出了最优桩长、最优桩体弹性模量和最优桩间距,为实际工程提供一些参考.