Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

三脉冲不等强度激光片光源的研制及应用

本文报道了最近研制成功三脉冲不等强度调Q红宝石激光片光源系统.利用小颗粒对片光源90°方向的散射光对动态颗粒场进行高速摄影,从底片中能够精确直观地判断微小颗粒的瞬时分布、运动方向、速度和加速度情况.     

高能粒子辐照对零膨胀微晶玻璃光学性质和面形光学稳定性的影响

研究了高能电子，高能质子对ＶＯ２微晶玻璃辐照前后光性质和面形光学稳定性的影响，研究结果表明，高能电子辐照能引起微晶玻璃面形明显变化，且使ＶＯ２微晶玻璃强烈着色。高能质子辐照没引起面形明显变化，高能质子辐照对反射光谱特性没有影响。     

复相陶瓷导电性与其粒径级配的关系研究

通过对无序渗流模型的修正，建立了具有不同特征尺寸的两相无序体系的导电模型，推导了相关关系式，将其结果与相复合导电陶瓷的实验结果进行了比较，结论相当一致。由此揭示了陶瓷生料的两相粒径分布对复合导电陶瓷导电性的影响。     

再论变化电磁场中带电超微粒子的精确量子论

利用创新的SU(1 ,1 )Lie代数理论及SO(3)Lie代数理论 ,得到变化电磁场中带电超微粒子的精确量子论 ,由此进一步明确微观领域中的时空概念     

NUMERICAL SIMULATION OF PARTICLE SEPARATION IN AN OIL-SAND SEPARATOR

ＮＯＴＡＴＩＯＮＳＡ　Ａｒｅａｏｆｉｎｌｅｔ ,ｍ2ａ　Ｃｅｎｔｒｉｆｕｇａｌａｃｃｅｌｅｒａｔｉｏｎ ,ｍ2 /ｓｉ　Ｇｒｉｄｏｆａｘｉａｌｄｉｒｅｃｔｉｏｎｍｌ 　ＭａｘｉｍｕｍｇｒｉｄｎｕｍｂｅｒｏｆｒａｄｉａｌｄｉｒｅｃｔｉｏｎＱ　Ｆｌｕｉｄｍａｓｓｒａｔｅ ,ｍ3/ｓＲｃ 　Ｍａｘｉｍｕｍｒａｄｉｕｓｏｆｃｙｃｌｏｎｅ ,ｍＲｅ　Ｒｅｙｎｏｌｄｓｎｕｍｂｅｒｒ　Ｄｉｍｅｎｓｉｏｎｌｅｓｓｒａｄｉａｌｄｉｓｔａｎｃｅｔ　Ｄｉｍｅｎｓｉｏｎｌｅｓｓｔｉｍｅｕ　Ｄｉｍｅｎｓｉｏｎｌｅｓｓａｘｉａｌｖｅｌｏｃ…     

催化氧化法合成脂肪醇醚羧酸盐的研究进展

详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20～60℃,反应时间3～6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50～90℃反应2～6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95％,选择性达90％以上。     

重油催化裂化反应技术的新进展

近十几年来，重油催化裂化技术作为主要的重质油轻质化手段得到了迅速发展，国内外围绕催化裂化装置的提升管反应器也开发了许多新技术。综述了重油催化裂化反应技术的新进展，并对新技术的开发进行了讨论。     

Study of Desorption Agent for LADS Process

This article refers to the procedure for selection, evaluation and development of the LADS-D desorption agent associated with the LADS-A adsorbent used in the non-hydroprocessing adsorptive desulfurization (LADS) process for FCC naphtha developed by LPEC Refining Research Institute. The LADS-D desorption agent can effectively remove the sulfides adsorbed on the LADS-A adsorbent. The saturated LADS-A adsorbent can be instantly regenerated by the LADS-D desorption agent to recover its adsorption activity. The LADS-D desorption agent can not only effectively remove all impurities adsorbed on the adsorbent, but also has strong ability to dissolve the impurities to keep a stable desorption efficiency of adsorbent to be basically commensurate with fresh adsorbent after extended use.     

低压组合床重整工艺工业试验

介绍了国产500kt／a低压组合床催化重整装置首次在中国石化股份有限公司长岭分公司的工业试验情况。近两年的运转及标定结果表明试验是成功的，该技术达到了国外连续重整技术第一代与第二代之间的水平，并且投资小，适于小型固定床重整装置的改造。