Experimental data for the densities, dynamic viscosities, sound speeds, and relative permittivities and for three binary systems of methyl methacrylate (MMA)+di-ethers (ethyl, isopropyl, and butyl) at 298.15 and 308.15 K and at atmospheric pressure are reported. The mixture viscosities are correlated by Grunberg–Nissan, McAllister, and Auslander equations over the complete composition range. The sound speeds for the mixtures are also calculated by using free length and collision factor theories, and Nomoto and Junjie equations. From the measured primary properties, deviation functions such as deviations in viscosities, sound speeds, relative permittivities, molar polarizations, excess isentropic compressibilities, and molar electrical susceptibilities were calculated, and the compositional dependence of each of the functions was expressed with a Redlich–Kister type equation. The variation of the Kirkwood correlation factor was determined over the complete composition range. 相似文献
The coupled system of three partial differential equations governing a flexible shallow shell dynamics is analysed. No any prior assumptions about the temperature distribution through the shell thickness are applied. The efficiency of the method used here when applied to the solution of integral-differential equations with different dimensions (three-dimensional equations related to the Kirchhoff-Love model) and of different type (heat transfer equations and the hyperbolic equations of shell theory) is demonstrated. Many computational results are reported and discussed. 相似文献
There are two purposes of this work. One is to present two accurate two-noded finite elements which are derived from the
potential energy principle and the Hellinger–Reissner functional principle respectively. The second is to show the successful
application of the internal displacement parameters in developing a high-order related displacement-rotation interpolation
field. Because the derived interpolation field is capable of accurately modeling deformation modes in extreme thin curved
beams and nearly straight beams, both shear locking and membrane shocking are avoided. Several standard numerical tests display
superior behaviors of the present elements.
Received: 5 February 2002 / Accepted: 16 September 2002 相似文献
A promising catalytic system for the low temperature oxidation of methane to a methanol derivative has been investigated under both batch and semi-continuous operation in two different reactor types. The system comprises of a bimetallic palladium and copper(II) chloride catalyst contained in a trifluoroacetic acid (TFA) and an aqueous phase. Methane, oxygen and a co-reductant carbon monoxide constitute the gas phase. Typical operating conditions were a temperature of 85 °C and a pressure of 83 bar.
The yields of the methyl trifluoroacetate product observed in this present work were less than those obtained in other batch autoclave works, which employed only 4 ml of liquid phase, compared with 50 ml in this study. Furthermore, an encouraging initial product formation rate of ca. 40 mol/m3 h, quickly decreased after the first hour, and came to an apparent end after only 2 h. This observation had not been reported previously.
Work performed in a semi-continuous porous tube reactor (300 ml of re-circulating liquid phase) also showed the same reaction characteristics as in the batch reactor. Thus, the deteriorating product formation rate cannot be attributed to gaseous reactant depletion (batch operation). The results suggest problems associated with catalyst instabilities, e.g. with the previously elucidated Wacker chemistry. 相似文献
Results of a study of tube specimens cut from hot-water boilers show that film-forming octadecyl amine (ODA) used in the process
of preservation removes deposition from the surface of the metal. An ODA film is preserved on the surface after repeated washing
of the latter with hot water. The concentration of chlorides at the surface of the metal after treatment with ODA is lower
than before the treatment.
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Translated from élektricheskie Stantsii, No. 11, November 2005, pp. 15–18. 相似文献