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101.
A. Demoz C. Khulbe C. Fairbridge S. Petrovic 《Journal of Applied Electrochemistry》2008,38(6):845-851
Hydrogen is among the emerging energy vectors that are being developed to replace nonrenewable hydrocarbon energy sources.
The preferred method to produce hydrogen without generating greenhouse gases is the electrolysis of water using renewable
energy. The reduction of energy during the water electrolysis process is a desirable goal regardless of the source of electric
power. Similar to ferrous/ferric mediation, iodide can be used as a mediator in the electrolysis of an acidic suspension of
coke or coal. The iodide ion is oxidized at a far lower anodic potential than the alternative oxygen evolution reaction. This
reduces the cell electrolysis voltage and, consequently, reduces electricity use. The iodide consumed at the anode is continuously
regenerated by chemical reaction with the coke/coal in suspension. 相似文献
102.
The transitions and reactions involved in the thermal treatment of several commercial azodicarbonamides (ADC) in an inert atmosphere have been studied by dynamic thermogravimetry analysis (TGA), mass spectrometry and Fourier transform infrared (FTIR) spectroscopy. A pseudo‐mechanistic model, involving several competitive and non‐competitive reactions, has been suggested and applied to the correlation of the weight loss data. The model applied is capable of accurately representing the different processes involved, and can be of great interest in the understanding and quantification of such phenomena, including the simulation of the instantaneous amount of gases evolved in a foaming process. In addition, a brief discussion on the methodology related to the mathematical modeling of TGA data is presented, taking into account the complex thermal behaviour of the ADC. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
103.
Hybrid precursors were assembled with cerium coordination polymers, polyethyl glycohol (PEG), SrCO3 and other functional components using a modified in-situ chemical polymeric gel technology. The hybrid precursors were calcinated to achieve the Sr2CeO4 phosphors, whose particle sizes were in the range of micrometer by XRD and SEM. The photoluminescence spectra indicate that the phosphors present a strong blue emission. 相似文献
104.
总结了目前国内中、小皮化企业中存在的主要问题 :自主开发能力差 ,造成产品品种单一、配套性差 ;新产品市场推广能力也较差 ,造成即使有好的产品 ,也无法打开市场 ;而普遍存在的制革厂欠款 ,皮化企业自身体制陈旧及国外皮化公司的进一步本土化策略 ,使国内皮化企业面临更严峻的挑战。根据自身多年经营皮化材料的经验 ,提出了切实可行的应对措施 相似文献
105.
生烃化学动力学在川东北普光气田的应用 总被引:9,自引:2,他引:7
普光气田是四川盆地近期发现的规模最大、埋藏最深、资源丰度最高的气田。通过认识普光气田各个烃源岩层的贡献量、生烃关键期与构造演化的关系、油气成藏具体模式等,建立生烃化学动力学模型、标定参数,结合地区烃源岩参数和地史、热史资料,定量描述该地区的生烃过程及油裂解成气过程。认为:普光地区的主力烃源岩为下志留统泥岩;主要干酪根生油期为早二叠世末到早三叠世末期(距今286Ma至240Ma);主要干酪根生气期为中三叠世(距今240Ma至230Ma);主要气源是原油后期热裂解气,原油裂解成气的时间比较晚,主要油裂解成气期为早白垩世(距今144Ma至97.5Ma),从而决定了普光气田的成藏模式为“多期成藏,油气转化,晚期定位”。图2表3参33 相似文献
106.
The objective of this study is to determine the chemical kinetics of desulphurization of Thai limestone in an atmospheric fluidized bed combustor (AFBC). The experiments, which employed the batch technique using the limestone samples from six major sources in Thailand, were performed in a laboratory‐scale AFBC. The results obtained were analysed and correlated in the form of apparent reaction rate and deactivation rate constants as a function of operating conditions of the furnace and their properties, respectively. The formulae derived from these correlations were kept as general as possible in order that they could be used as input parameters for the selected mathematical model of desulphurization in an AFBC that is suitable for practical use. The predicted results were in good agreement with the experimental data reported in the literature. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
107.
将3组不同纤维体积分数的整体毡采用等温CVD进行沉积热解炭增密,结合CVD沉积过程中整体毡内气体传质数学模型,研究了整体毡的纤维体积分数对CVD增密过程的影响,研究结果表明:纤维体积低的整体毡沉积时增重率高;纤维体积分数高的整体毡容易获得较高密度的C/C复合材料;纤维体积分数超过35%的整体毡经过300 h的化学气相沉积,坯体的体积密度能达到1.52 g/cm~3。 相似文献
108.
109.
为提高抽油机减速器齿轮铸件的机械性能,提出以Sn代替Mo作为合金元素,并通过试验确定了合理的Si、Cu、Sn的加入量。指出Si加入量应控制在1.9%-2.1%范围内,同时加入0.36%~0.9%的Cu和0.025%~0.07%的Sn,可保证球铁的强度和延伸率都满足QT700-2的要求。鉴于试件与实际铸件的表面硬度有一定的差值,为提高铸件表面硬度,进行了余热正火试验,并给出了铸件在铸型内的时间-冷却温度曲线。最后根据球铁化学成分的选择结果,进行了齿轮生产试验。 相似文献
110.
An improved set of parameters for vanadium in the semiempirical quantum chemical SCF MO method SINDO1 is presented. It is shown that both the geometries and heats of formation of a number of vanadium-containing compounds calculated by this method are in good agreement with available experimental data. Model clusters of increasing size are used for the study of geometric and energetic properties of vanadium pentoxide. Both hydrogen atom and proton adsorption on the (010) surface of vanadium pentoxide and a subsequent formation of different oxygen vacancies have been investigated. Based on these computational results the reactivities of V2O5-surface oxygen atoms for adsorption are discussed. 相似文献