N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究

用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0～10.0,反应温度15～20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3～6.5。     

抗生素后效应对制定治疗方案的指导意义

抗生素后效应系指细菌与抗生素短暂接触后在抗生素被清除的情况下细菌生长仍受抑制的现象。本文对在临床应用中高度重视抗生素后效应的意义和方法作了阐述。     

浆砌石衬砌在渠道防渗中的应用及对策

总结了浆砌石应用的历史,介绍了浆砌石的结构特性和施工工艺,从造价方面、防渗效果及施工三方面分析了浆砌石衬砌主要存在的问题,并提出了相应的解决对策,指出浆砌石衬砌在渠道防渗应用中应控制施工质量,从而更好地提高防渗效果。     

The Dud-Alternative Effect in Likelihood Judgment.

The judged likelihood of a focal outcome should generally decrease as the list of alternative possibilities increases. For example, the likelihood that a runner will win a race goes down when 2 new entries are added to the field. However, 6 experiments demonstrate that the presence of implausible alternatives (duds) often increases the judged likelihood of a focal outcome. This dud-alternative effect was detected for judgments involving uncertainty about trivia facts and stochastic events. Nonnumeric likelihood measures and betting measures reliably detected the effect, but numeric likelihood measures did not. Time pressure increased the magnitude of the effect. The results were consistent with a contrast-effect account: The inclusion of duds increases the perceived strength of the evidence for the focal outcome, thereby affecting its judged likelihood. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Assumptions and Consequences of Treating Providers in Therapy Studies as Fixed Versus Random Effects: Reply to Crits-Christoph, Tu, and Gallop (2003) and Serlin, Wampold, and Levin (2003).

In their comments on the authors' article (see record 2003-10163-009), R. C. Serlin, B. E. Wampold, and J. R. Levin (see record 2003-10163-011) and P. Crits-Christoph, X. Tu, and R. Gallop (see record 2003-10163-010) took issue with the authors' suggestion to evaluate therapy studies with nested providers with a fixed model approach. In this rejoinder, the authors' comment on Serlin et al's critique by showing that their arguments do not apply, are based on misconceptions about the purpose and nature of statistical inference, or are based on flawed reasoning. The authors also comment on Crits-Christoph et al's critique by showing that the proposed approach is very similar to, but less inclusive than, their own suggestion. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Coincidence Doppler broadening spectroscopy in polyvinyl chloride after doping with Al2O3

Coincidence Doppler broadening of annihilation radiation (CDBAR) and Vickers hardness techniques were performed to study pure Al₂O₃, pure polyvinyl chloride (PVC), and doped PVC with different concentrations of Al₂O₃ (10–50%). The CDBAR ratio curves with respect to pure PVC were presented and reflect the momentum distribution of all the samples. The peak around 14.5 ×10^?3 m_oC in the CDBAR ratio curves suggests a large contribution of positron annihilation with the Al₂O₃. There is a linear correlation between the height of this peak and the Al₂O₃ concentration. The S‐ and W‐parameters were extracted from the CDBAR spectra and increase with increasing the Al₂O₃ concentration showing discontinuity at 30% of Al₂O₃ concentration on PVC. The present data confirmed that there is no positronium formation in pure Al₂O₃ as a result of smaller S‐parameter. The Vickers hardness increases with increasing the Al₂O₃ concentration in PVC showing a linear dependence with two different slopes depend on the Al₂O₃ concentration range. A correlation between the Vickers hardness (macroscopic data) and the W‐parameter (microscopic data) was observed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Computer simulation of the effective double layer occurring on a catalyst surface under electro-chemical promotion conditions

In this work, the structural and energetic properties of two typical catalytic surfaces, Na/Pt(111) and O/Pt(111), are studied by means of quantum mechanical calculations and Monte Carlo Grand Canonical simulations. The simulations were performed with electrostatic potentials at different truncation schemes. In order to elucidate the modification of catalyst surfaces produced by the backspillover of ionic species onto Pt(111), the electrostatic field at the interface due to the electric double layer was also analyzed.     

Towards a new definition of EPOC parameters for anionic electrochemical catalysts: case of propene combustion

The electrochemical promotion of catalysis (EPOC) of propene combustion was investigated using Pt sputtered thin film on an O²⁻ conductor, 8 mol% Y₂O₃-stabilized-ZrO₂ (YSZ). In order to separate the influence of the thermal migration of the O²⁻ oxide ions from the electrolyte to the catalyst surface and the impact of an electrical polarization on the catalytic activity, several light-off experiments (cool down and heat up procedures) were successively performed under different polarizations, i.e. OCV, +2 and −2 V. These experiments have clearly shown that the presence of O²⁻ (thermally or electrochemically induced) inhibits the catalytic activity of the platinum for the propene deep oxidation. These results demonstrate the importance to define a normalized rate enhancement ratio, ρ _n , from a reference value of the catalytic rate corresponding to a Pt surface state free of O²⁻ ions.     

The benefits and costs of repeated memory tests for young and older adults.

Repeated and prolonged searches of memory can lead to an increase in how much is recalled, but they can also lead to memory errors. These 3 experiments addressed the costs and benefits of repeated and prolonged memory tests for both young and older adults. Participants saw and imagined pictures of objects, some of which were physically or conceptually similar, and then took a series of repeated or prolonged recall tests. Both young and older adults recalled more on later tests than on earlier ones, though the increase was less marked for older adults. In addition, despite recalling less than did young adults, older adults made more similarity-based source misattributions (i.e., claiming an imagined item was seen if it was physically or conceptually similar to a seen item). Similar patterns of fewer benefits and more costs for older adults were seen on both free and forced recall tests and on timed and self-paced tests. Findings are interpreted in terms of age-related differences in binding processes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)