分流叶片对离心泵内部固液两相流的影响

为了研究分流叶片对离心泵内部固液两相流的影响,建立固液两相流模型,对无分流叶片离心泵和3种带分流叶片的离心泵进行全流道非定常数值模拟。重点分析了添加分流叶片对离心泵外特性、叶片表面压力脉动、叶片表面颗粒体积分数分布、叶片表面颗粒滑移速度的影响。分析结果表明:添加分流叶片以后,离心泵的扬程和效率均有显著的提高,叶片表面的颗粒分布更加均匀,叶片表面颗粒的滑移速度有不同程度的下降,使颗粒对叶片表面的磨损程度得以降低;当分流叶片的进口直径为0.65D2时,叶片出水边处的压力脉动幅值最小,减小了离心泵在运行过程中的振动和噪声。     

焦炭颗粒的粒度分布及其微观结构研究

焦炭颗粒是生产碳石墨制品的主要原料，它的粒度组成、分布及其微观结构不仅对碳石墨制品的机械性能和理化性能有一定的影响，而且还直接影响到各生产工序的成品率．为此，主要对粉碎后几种焦炭颗粒的粒度组成、分布及其微观结构进行了研究．并通过分析，确立了焦炭颗粒的粒度组成及其分布规律与粉碎方式和焦炭强度之间的内在关系．     

Charge reduction and regeneration in K+, Na+, Mg2+, Ni2+ and Co2+-exchanged Wyoming Bentonite

Controlled calcination of ion-exchanged Wyoming Bentonite in the presence and absence of ammonia leads to layer charge reductions. Detailed chemical analyses of both unexchangeable and exchangeable species lead to the conclusion that in no case is there migration of the original interlamellar cations into the octahedral region of the layers although, in terms of ionic radius alone, Mg²⁺, Ni²⁺ and, possibly Co²⁺, might be expected to do so. The production of unexchangeable Mg, Ni or Co, is identified as resulting from high temperature hydrolysis leading to hydroxide or oxide formation.     

通过RAFT聚合方法合成具有高强度和高溶胀率的纳米水凝胶

为了得到具有高强度和高溶胀率的纳米水凝胶(NCgels),N-异丙基丙烯酰胺通过可逆加成断裂链转移(RAFT)聚合的方法,插层在含有质量分数为0.25%～15%的可扩展的有机化的蒙脱土(Clay-S)层间并交联。结果表明,与传统水凝胶相比,该水凝胶的强度和溶胀性能得到了很大提高,并且对温度的变化具有较快的响应速率。以质量分数为5%的蒙脱土,链转移剂的质量分数为0.5%制备的纳米水凝胶为例,该水凝胶在20℃的溶胀率为450,而传统水凝胶在相同温度时的溶胀率仅为20;该水凝胶在1min内失去75%的水,在4min内失去约90%的水,而传统水凝胶在15min内仅失去66%左右的水。     

温度影响下压实红粘土持水特性研究

通过渗析法和水汽平衡法研究不同温度控制下干密度1.7 g/cm~3压实红粘土持水特性(SWRC:soil water retention characteristics)。试验结果表明:20℃下干密度1.7 g/cm~3压实红粘土进气值约为110 k Pa;试样控制的温度越高,压实红粘土样持水能力越低,土样进气值随着温度升高而减小,且呈线性关系;Van Genuchten(1980年)土水特征模型能很好的描述干密度1.7 g/cm~3压实红粘土持水特性曲线。     

尺寸效应和约束条件对土基回弹模量的影响

室内承载板法是测定土基回弹模量的标准试验方法。尺寸效应和约束条件的影响使得室内测定的回弹模量往往与现场不符,不能直接用于公路结构设计。以红黏土为研究对象,采用室内试验和数值模拟的方法研究了试样的尺寸效应和约束条件对土基回弹模量的影响。结果表明:试样的尺寸效应(试样直径和高度)对回弹模量的影响较大,随着试样直径的增大回弹模量增大,随着试样高度的增大回弹模量减小;无侧限条件下测定的回弹模量乘以约束条件系数1.2即得有侧限条件下回弹模量值。研究成果为室内合理测定土基回弹模量值提供参考依据。     

钛酸铝基复合陶瓷的研究

提出了钛酸铝陶瓷研究中存在的问题．论述了颗粒弥散强化陶瓷基复合陶瓷的机理，叙述了第二相颗粒补强钛酸铝基复合陶瓷的国内外研究状况．认为钛酸铝基复合陶瓷是一种很有前途的抗热震冲击且耐高温的材料，并指出了今后的研究方向。     

Modification of the porosity of pillared clays by carbon deposition. I. Polymer carbonization

In order to use pillared clays (PILC) for selective adsorption, further modifications of the porous structure are necessary. The deposition of carbon residues onto the porous structure of pillared clays by the carbonization of polymers (polyvinylalcohol) was proposed to achieve a controlled modification of the pore size. Ti and Al-pillared clays (calcined and non-calcined) were impregnated with PVA (different grades and different concentrations and subsequently carbonized to form carbon phases. The effect of the carbon deposits on the porosity of Ti- and Al-PILC is discussed in terms of pore-blocking, pore-filling and pore-narrowing. The deposition of carbon using PVA resulted in a complete pore-blocking for Al-PILC and in a narrowing of the pore size distribution for Ti-PILC, without achieving a controlled pore-narrowing.     

Manipulating the phase morphology in PPS/PA66 blends using clay

By adding a small amount of clay into poly(p‐phenylene sulfide) (PPS)/polyamide 66 blends, the morphology was found to change gradually from sea–island into cocontinuity and lamellar supramolecular structure, as increasing of clay content. Clay was selectively located in the PA66 phase, and the exfoliated clay layers formed an edge‐contacted network. The change of morphology is not caused by the change of volume ratio and viscosity ratio but can be well explained by the dynamic interplay of phase separation between PPS and PA66 through preferential adsorption of PA66 onto the clay layers and through layer–layer repulsion. This provides a means of manipulating the phase morphology for the immiscible polymer blends. The mechanical and tribological properties of PPS/PA66 blends with different phase morphologies (different clay contents) were studied. Both tensile and impact strength of the blends were found obviously increased by the addition of clay. The antiwear property was greatly improved for the blends with cocontinuous phase form. Our work indicates that the phase‐separating behavior of polymer blends contained interacting clay can be exploited to create a rich diversity of new structures and useful nanocomposites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Variability of light absorption properties in optically complex inland waters of Lake Chaohu,China

Absorption coefficients of phytoplankton, colored detrital matter (CDM), non-algal particles (NAP), colored dissolved organic matter (CDOM), and their relative contributions to total non-water absorption (a_t ? w) are essential variables for bio-optical and radiative transfer models. Light absorption properties showed large range and variability sampled at 194 stations throughout Lake Chaohu between May 2013 and April 2015. The a_t ? w was dominated by phytoplankton absorption (a_ph) and NAP absorption (a_d). The contribution of CDOM absorption to a_t ? w was lower than 30%. Phytoplankton and NAP were the primary sources of spatial and vertical variability in absorption properties. Light absorption by CDOM, though significant in magnitude, was relatively constant. CDM absorption (a_dg) was dominated by NAP. The spatial variation of the absorption coefficients from each of the optically active constituents were driven by several main inflow rivers in the western and middle part of Lake Chaohu. Algal blooms and bottom resuspension contributed to vertical variability as observed by phytoplankton and NAP profiles. Specific absorption of phytoplankton had significant spatial and seasonal variations without vertical variation. The spectral slope of absorption showed no significant spatial variability (p > 0.05). Variations of absorption affected different ranges of remote sensing reflectance (R_rs) spectrum, thereby increasing the difficulty of applying the remote sensing algorithm in optically complex waters. Parameters and relationships presented in this study provide useful information for bio-optical models and remote sensing of lakes similar to Lake Chaohu in terms of optical properties.