全文获取类型
收费全文 | 10143篇 |
免费 | 1208篇 |
国内免费 | 616篇 |
专业分类
电工技术 | 164篇 |
综合类 | 761篇 |
化学工业 | 3539篇 |
金属工艺 | 697篇 |
机械仪表 | 315篇 |
建筑科学 | 1651篇 |
矿业工程 | 514篇 |
能源动力 | 281篇 |
轻工业 | 300篇 |
水利工程 | 481篇 |
石油天然气 | 683篇 |
武器工业 | 51篇 |
无线电 | 313篇 |
一般工业技术 | 1539篇 |
冶金工业 | 342篇 |
原子能技术 | 187篇 |
自动化技术 | 149篇 |
出版年
2024年 | 30篇 |
2023年 | 151篇 |
2022年 | 264篇 |
2021年 | 383篇 |
2020年 | 338篇 |
2019年 | 337篇 |
2018年 | 334篇 |
2017年 | 405篇 |
2016年 | 367篇 |
2015年 | 415篇 |
2014年 | 551篇 |
2013年 | 733篇 |
2012年 | 644篇 |
2011年 | 755篇 |
2010年 | 522篇 |
2009年 | 601篇 |
2008年 | 564篇 |
2007年 | 616篇 |
2006年 | 594篇 |
2005年 | 524篇 |
2004年 | 515篇 |
2003年 | 387篇 |
2002年 | 340篇 |
2001年 | 243篇 |
2000年 | 235篇 |
1999年 | 203篇 |
1998年 | 165篇 |
1997年 | 161篇 |
1996年 | 124篇 |
1995年 | 94篇 |
1994年 | 77篇 |
1993年 | 57篇 |
1992年 | 60篇 |
1991年 | 50篇 |
1990年 | 32篇 |
1989年 | 22篇 |
1988年 | 12篇 |
1987年 | 7篇 |
1986年 | 9篇 |
1985年 | 13篇 |
1984年 | 4篇 |
1983年 | 9篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Dicyanate–clay nanocomposites comprising a dicyanate resin and a type of organically modified clay were prepared and characterized, and their thermomechanical properties were investigated. The organically modified clay had silicate layers of nanometer size intercalated with an organic modifier, which improved the compatibility between the clay and organic materials, such as dicyanate resins. Dynamic mechanical analysis was performed to investigate the thermomechanical properties of the dicyanate–clay nanocomposites containing various amounts of the clay. The storage modulus of the nanocomposites below their glass‐transition temperatures slightly increased with increasing clay content. The glass‐transition temperature of the dicyanate–clay nanocomposites increased with increasing clay content. The nanostructures of the dicyanate–clay nanocomposites were characterized by transmission electron microscopy and X‐ray diffraction analysis. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2629–2633, 2003 相似文献
172.
173.
The axial dispersion-sedimentation model is commonly used to describe the axial concentrations of solids in three phase bubble columns at low liquid velocities. When the two parameters of this model, the particle settling velocity and the solids axial dispersion coefficient, are uncoupled by the use of various assumptions, physically unrealistic values of these parameters often result. Direct experimental measurements of solids settling rates in bubbly gas-liquid mixtures were carried out. The measured mean settling velocities decreased slightly with gas flow rate and were equal to or slightly less than the single particle free settling velocity in the liquid alone. Solids axial dispersion coefficients were also obtained from the solids settling rate distribution data, and gave values considerably less than the experimental liquid axial dispersion coefficient. 相似文献
174.
175.
The linear and nonlinear shear rheological behaviors of poly(propylene) (PP)/clay (organophilic‐montmorillonite) nanocomposites (PP/org‐MMT) were investigated by an ARES rheometer. The materials were prepared by melt intercalation with maleic anhydride functionalized PP as a compatibilizer. The storage moduli (G′), loss moduli (G″), and dynamic viscosities of polymer/clay nanocomposites (PPCNs) increase monotonically with org‐MMT content. The presence of org‐MMT leads to pseudo‐solid‐like behaviors and slower relaxation behaviors of PPCN melts. For all samples, the dependence of G′ and G″ on ω shows nonterminal behaviors. At lower frequency, the steady shear viscosities of PPCNs increase with org‐MMT content. However, the PPCN melts show a greater shear thinning tendency than pure PP melt because of the preferential orientation of the MMT layers. Therefore, PPCNs have higher moduli but better processibility compared with pure PP.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2427–2434,2004 相似文献
176.
This paper reports synthesis and characterization of polyurethane–urea (PU‐urea) and the nanocomposites derived from the PU‐urea with silicate clays. Organophilic montmorillonite cotreated by cetyl trimethyl ammonium bromide (CTAB) was synthesized and used to prepare PU‐urea/montmorillonite nanocomposites coatings. PU‐ureas were prepared from polyethylene glycol (PEG), polypropylene glycol (PPG), trimethylol propane (TMP), and 4,4′‐diphenylmethane diisocyanate (MDI) by reacting excess diisocyanate with polyether glycols. The excess isocyanate of the prepolymers was cured with atmospheric moisture. The synthesized moisture cured PU‐urea and nanocomposites were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetric (DSC), and angle resolved X‐ray photoelectron spectroscopy (AR‐XPS). The thermal stability of the PU‐urea nanocomposites was higher relative to the mother PU‐urea films. DSC results showed a slight enhancement in the soft segment glass transition temperature after 3 wt % clay loading. The surface properties showed an enrichment of the soft segment toward the surface. An enhancement in the hard segment composition in the nanocomposite coatings has resulted in enhancing the phase mixing process. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2393–2401, 2006 相似文献
177.
Micrometer and nanometer TiO2 particle‐filled poly(phthalazine ether sulfone ketone) (PPESK) composites with various filler volume fractions from 0.5 to 7.5 vol % were prepared by heating compression molding. The friction and wear behaviors of the PPESK composites were evaluated using the block‐on‐ring test rig by sliding PPESK‐based composite blocks against a mild carbon steel ring under dry friction conditions. The wear debris and the worn surfaces of the PPESK composites filled with micrometer and nanometer TiO2 particles were investigated by using a scanning electron microscope (SEM), while the structures of PPESK composites and wear debris were analyzed with IR spectra. Experimental results show that antiwear properties of the PPESK composites can be improved greatly by filling nanometer TiO2 particles, and the friction coefficient decreases when the filler volume fraction is below 2.5%, but when the filler volume fraction is above 2.5% the friction coefficient increases gradually with increasing filler volume fraction. In the case of micrometer TiO2 filler, wear rates increase with increasing filler volume fractions under identical test conditions, and the friction coefficients are less sensitive to the filler volume fraction. It was also found that the wear mechanism of micrometer TiO2 particle‐filled PPESK is mainly severe adhesion and abrasive wear, while that of nanometer TiO2 particle‐filled PPESK is mainly slight abrasive wear. In the former case, there are no transfer film formed on the surface of the counterpart steel, and wear debris are in the form of long and large ribbon. While in the latter case, the wear debris was granule and their size was about 10 μm. In case of 1 vol % nanometer TiO2 particle‐filled PPESK composites, the transfer film was fairly thinner and smoother, and the transfer film provided better coverage on the surface of steel ring, while that of 7.5 vol % was thicker and discrete. These account for the different friction and wear behavior of micrometer and nanometer TiO2 particle‐filled PPESK composite. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 906–914, 2004 相似文献
178.
A nanosized silica particle was used as the support to prepare an Et[Ind]2ZrCl2/MAO catalyst for propylene polymerization of polypropylene. The catalyst and the polymer produced were characterized with nitrogen adsorption, ICP, DSC, SEM, TEM, XRD, solution viscometer, 13C NMR and optical microscopy. The effects of polymerization temperature and [Al]/[Zr] ratio on catalyst activity and polymer melting point were investigated. Under identical reaction conditions, nanosized catalyst exhibited better polymerization activity than the microsized catalyst (e.g., the former had 64% higher activity than the latter at the optimum polymerization temperature (50°C) and [Al]/[Zr] = 570). DSC results indicated that polymer melting point increased with the increase of [Al]/[Zr] ratio and with the decrease of polymerization temperature. XRD results showed that the percentage of γ crystals increased with decreasing [Al]/[Zr] ratio. Electron microscopic results showed that the polymer particle size increased with increasing polymerization temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2573–2580, 2006 相似文献
179.
Saziye Ugur Ayse Alemdar Önder Pekcan 《Journal of Coatings Technology and Research》2005,2(7):565-575
This study reports a steady-state fluorescence (SSF) technique for studying film formation from surfactant-free polystyrene
(PS) latex and Na-montmorillonite (SNaM) composites. The composite films were prepared from pyrene (P)-labeled PS particles
and SNaM clay at room temperature and annealed at elevated temperatures in 10-min intervals above glass transition temperature
(t3) of polystyrene. During the annealing processes, the transparency of the film improved considerably. Scattered light (Is) and fluorescence intensity (Ip) from P were measured after each annealing step to monitor the stages of film formation. Evolution of transparency of composite
films was monitored by using photon transmission intensity, Itr. Scanning electron microscopy (SEM) was used to detect the variation in physical structure of annealed composite films. Minimum
film formation temperature, Tq, and healing temperatures, Th, were determined. Void closure and interdiffusion stages were modeled and related activation energies were determined. It
was observed that both activation energies increased as the percent of SNaM was increased in composite films. 相似文献
180.
In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO2 were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO2 could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006 相似文献