黑龙江省新林—呼中地区水系沉积物地球化学特征及找矿意义

在新林—呼中地区森林沼泽-冻土景观区,开展1∶50 000水系沉积物测量,探讨该区水系沉积物中元素含量分布、元素组合特征和区域地球化学异常特征,为下一步划分成矿远景区,开展地球化学找矿提供依据。结果显示:该区具备中高温热液型Cu、Pb、Mo、Au多金属矿成矿条件;早白垩世二长花岗岩区和白音高老组火山岩区Cu、Pb、Zn、Mo、Au显著富集,强烈分异,是寻找Pb、Cu、Mo、Au多金属矿化(床)的有利地段;区域异常与燕山早期酸性侵入体密切相关,应是晚侏罗世—早白垩世岩浆侵入、喷发以及构造运动强烈作用的结果。     

Theoretical insights into the interaction between RunPt13-n (n = 4, 7 and 9) clusters and [BMIM]+ based ionic liquids: Effect of anion

Density functional theory has been performed to systematically study the interactions between Ru_nPt_13-n (n = 4, 7 and 9) clusters and [BMIM]⁺ based ionic liquids. Ionic liquids [BMIM][Br], [BMIM][BF₄], [BMIM][PF₆], [BMIM][CF₃SO₃], and [BMIM][NTf₂] have different effects on the stability of Ru₇Pt₆. Ionic liquids with median size anions of PF₆⁻ and CF₃SO₃⁻ can better improve the stability of Ru₇Pt₆ than those with the small anions of Br⁻ and BF₄⁻ and large anion of NTf₂⁻. Based on negative relaxation energies, the stabilities of Ru₄Pt₉, Ru₇Pt₆, and Ru₉Pt₄ are all enhanced after interacting with [BMIM][CF₃SO₃]. The stability enhanced degree is in agreement with the interaction strength. For Ru₇Pt₆–n{[BMIM][CF₃SO₃]} (n = 1, 2, 3, 4), the interaction between ionic liquid and cluster plays the primary role in stabilizing the cluster in Ru₇Pt₆–[BMIM][CF₃SO₃]. With the increase of the number of [BMIM][CF₃SO₃], the role of the interaction in stabilizing the cluster is getting weaker, while the role of steric protection is getting more important.     

Development of PCA-based cluster quantile regression (PCA-CQR) framework for streamflow prediction: Application to the Xiangxi river watershed,China

In this study, a PCA-based cluster quantile regression (PCA-CQR) method was proposed through integrating principal component analysis and quantile regression approaches into a stepwise cluster analysis framework. In detail, the principal component analysis was adopted to overcome the multicollinearity among the explanatory variables, while the quantile regression approach was used to provide probabilistic information in prediction. The proposed PCA-CQR method can effectively capture discrete and nonlinear relationships between explanatory and response variables. The applicability of PCA-CQR was demonstrated by a case study of monthly streamflow prediction in the Xiangxi River, China. The nonlinearity between the hydro-meteorological variables and the streamflow measurements was characterized through the measure of maximal information coefficient (MIC), which demonstrated the need of the proposed PCA-CQR method. The results showed that the previous monthly streamflow and precipitation, as well as potential evapotranspiration in current month posed significant nonlinear impacts on the streamflow in current month. Three components could well reflect the total variance of the input variables. Comparison between traditional SCA and PCA-CQR showed that the proposed approach could provide more accurate predictions than traditional SCA methods. Moreover, probabilistic forecasts could be provided by PCA-CQR, and the 90% predictive intervals could well bracket the observations in both calibration and validation periods. Also, sensitivity analysis was performed to identify the impacts of the control parameters in PCA-CQR on the performance of the proposed model. The results showed the proposed PCA-CQR improved the robustness of traditional SCA. Finally, comparison among PCA-CQR, GRNN and MLR also showed the effectiveness of the proposed method.     

Nonlinear Elastic Wave Spectroscopy (NEWS) Techniques to Discern Material Damage,Part II: Single-Mode Nonlinear Resonance Acoustic Spectroscopy

Abstract

The presence of mesoscopic features and damage in quasi-brittle materials causes significant second-order and nonlinear effects on the acoustic wave propagation characteristics. In order to quantify the influence of such micro-inhomogeneities, a new and promising tool for nondestructive material testing has been developed and applied in the field of damage detection. The technique focuses on the acoustic nonlinear (i.e., amplitude-dependent) response of one of the material's resonance modes when driven at relatively small wave amplitudes. The method is termed single-mode nonlinear resonance acoustic spectroscopy (SIMONRAS). The behavior of damaged materials is manifested by amplitude dependent resonance frequency shifts, harmonic generation, and nonlinear attenuation. We illustrate the method by experiments on artificial slate tiles used in roofing construction. The sensitivity of this method to discern material damage is far greater than that of linear acoustic methods.     

牛庄洼陷南斜坡沙河街组原油成因类型的多参数聚类分析

通过牛庄洼陷源岩抽提物异戊二烯烃、单体烃碳同位素和甾、萜烷化合物等多种地化参数的对比,优选出植烷、伽马蜡烷、升藿烷系列、甲藻甾烷和4-甲基甾烷等生标化合物构成源岩特征指纹参数,采用聚类分析方法对沙河街组原油成因类型进行了研究,结果表明该区原油可以划分为3类:Ⅰ类原油与沙三源岩聚为一类,具有低植烷丰度、低伽马蜡烷丰度、低C35升藿烷丰度、低甲藻甾烷丰度和低4-甲基αααC29甾烷丰度的"五低"特点,体现了来源于弱氧化、低盐度环境下形成的沙三下亚段源岩的地化特征;Ⅱ类原油与沙四源岩聚为一类,具有高植烷丰度、高伽马蜡烷丰度、高C35升藿烷丰度、高甲藻甾烷丰度和高4-甲基αααC29甾烷丰度的"五高"特点,体现了来源于强还原、高盐度环境下形成的沙四上亚段源岩地化特征;Ⅲ类原油和沙三、沙四源岩没有显著的聚类关系,也与孔店组原油和源岩地化特征不同,而其主要聚类参数的均值均处于沙三下亚段、沙四上亚段源岩的均值范围之间,推测可能为2套源岩生成原油的混合油。     

气—固两相流流型检测与调节的专家系统

气－固两相流流型的检测与调节是与两相流的测量密切相关的，本文针对精确的测量往往要受众多因素影响的情况，提出了一种判断流型的新方法，通过引入领域专家的知识，改进了单纯用模糊聚类方法的不确定，建立了检测和调节的专家系统结构，进行了计算机仿真试验，运用效果良好。     

HIS变换用于数字化航空片影象同多光谱影象的复合

本文探讨ＨＩＳ变换对数字化航空片影象与ｌａｎｄｓａｔ ＴＭ多光谱影象进行复合的方法，并在此基础上提出一种改进的方法。试验结果表明本文提出的方法是一种非常行之有效的方法。复合后的影象不仅保留了ＴＭ影像的光谱特征，而且将其空间分解力由３０ｍ提高到１０ｍ，清晰度也提高了。因而复合后的影像能提高分类精度，制作专题图的精度、多时相监测能力和解译水平等。     

基于SPSS的制造企业CIMS实施Pre-EBC模型研究

对我国现阶段制造企业CIMS工程项目的实施状况,选取了国内72家已实施CIMS工程项目的企业,运用SPSS统计工具通过调研得出综合分析结果,对准备实施CIMS的企业做出基础条件预评价研究。运用SPSS统计工具,通过对已实施CIMS样本企业进行聚类分析,应用判别分析结果对待评企业得出正确的归类和预评价,为企业初步判断以现有基础条件是否可以进行CIMS工程项目实施提供有效的自评诊断工具。     

基于声发射技术的Si-Cr-Ti高温抗氧化涂层弯曲失效机理研究

本研究借助声发射技术对铌基高温抗氧化涂层在常温下的弯曲失效过程进行了研究。利用k均值聚类方法对信号进行了分类,结合截面扫描电镜观测结果确定高温抗氧化涂层在弯曲载荷下的信号分别对应基体变形、表面垂直裂纹、滑动型界面裂纹和张开型界面裂纹,通过快速傅里叶变换得到了各类信号的主频分别为100、310、590和450 kHz,借助小波分析得到了各信号的小波能量系数。涂层弯曲失效过程主要包括四个阶段,分别为受拉侧表面垂直裂纹萌生的初始损伤阶段、表面垂直裂纹增殖阶段、两侧界面裂纹快速扩展的损伤积累阶段和受压侧涂层明显剥落的宏观剥落阶段。     

团簇Co3FeP的成键方式与磁性

为研究非晶态合金Co-Fe-P体系的成键方式及磁性,在较高的量子化学水平下,利用密度泛函理论,以团簇Co₃FeP为局域模型展开研究,结果发现：团簇的自旋多重度和几何形态均会影响其成键杂化方式和磁性;团簇Co₃FeP中存在pd²、s²p²d³、p²d、p³d、p³、pd³杂化,其中Co-Fe键主要由Co3d和Fe3d、Co4p和Fe4p形成的d²和p²杂化组成;Co-P键主要是Co3d和P3p形成的pd杂化;Fe-P键主要是Fe3d和P3p形成的pd杂化。Co原子和Fe原子在提供磁性时,相互制衡。综合来看,d轨道对团簇Co₃FeP的成键方式和磁性有着重要影响。