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101.
铒氨基酸固态配合物的光声光谱研究 总被引:2,自引:0,他引:2
合成了Er(Gly)3Cl3·3H2O、Er(Ala)3Cl3·3H2O和Er(Gly)3Phen·3H2O二元及三元固态配合物微晶粉末,在300nm~800nm范围内测定并解释了其光声光谱。通过对光声相对强度计算得到铒氨基酸固态配合物的光声支量,讨论了氨基酸配体对中心稀土离子铒f-f跃迁的微扰作用。结合Er(Ala)3Cl3·3H2O配合物的光声光谱和吸收光谱研究了其荧光性质及弛豫模型。 相似文献
102.
Yu. S. Yakovlev 《Cybernetics and Systems Analysis》2003,39(5):765-776
Distinctive features of architectural-structural organization and use of memory networks are considered with the aim of choosing an optimal configuration in designing distributed computer systems. 相似文献
103.
Gloria Galan-Marin Enrique Merida-Casermeiro Domingo Lopez-Rodriguez 《Neural Processing Letters》2007,26(2):133-143
Detection of isomorphism among kinematic chains is essential in mechanical design, but difficult and computationally expensive.
It has been shown that both traditional methods and previously presented neural networks still have a lot to be desired in
aspects such as simplifying procedure of identification and adapting automatic computation. Therefore, a new algorithm based
on a competitive Hopfield network is developed for automatic computation in the kinematic chain isomorphism problem. The neural
approach provides directly interpretable solutions and does not demand tuning of parameters. We have tested the algorithm
by solving problems reported in the recent mechanical literature. Simulation results show the effectiveness of the network
that rapidly identifies isomorphic kinematic chains. 相似文献
104.
105.
This article reviews the theory of successful intelligence and attempts to construct-validate the theory of successful intelligence. It describes 4 distinct converging operations that have been used in these attempts. Two sets involve internal validation of the structure of the theory and 2 sets external validation of the theory with outside criteria. The internal validation operations involve information-processing (componential) analyses and both exploratory and confirmatory factor analyses. The external validation operations involve correlational analysis and analyses of instructional interventions based on the theory. The results are generally supportive of the theory and suggest that conventional conceptions of intelligence may be too narrow. The theory is of use in consulting because it broadens the scope of skills one looks for in seeking "intelligent" people for hiring, retention, and promotion and in assessing a person's ability to do his or her current job. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
106.
Because of the widespread increasing application of Web services and autonomic computing, self-adaptive software is an area gaining increasing importance. Control theory provides a theoretical foundation for self-adaptive software. In this paper, we propose the use of the supervisory control theory of discrete event dynamic systems (DEDS) to provide a rigorous foundation for designing software for reactive systems. This paper focuses in particular on design of software with an attractivity requirement. It studies this problem using the polynomial dynamic system (PDS) model of DEDS. A necessary and sufficient condition for software existence and two algorithms for such software design are presented. 相似文献
107.
B. S. Seplyarskii S. V. Kostin G. B. Brauer 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(2):121-124
Explored is the filtration combustion in Ti-(Ti + 0.5C) layered powder systems in a coflow of nitrogen gas. The presence/absence
of nitrogen coflow through the layered system was found to drastically affect the character of wave propagation and structure/properties
of product. The obtained data can be regarded as a basis for fabrication of new layered and composite materials in the mode
of dynamic filtration combustion.
相似文献
108.
You-Im Chang Yu-Sheng Chen Wei-You Cheng 《Journal of the Chinese Institute of Chemical Engineers》2008,39(1):85-100
The deposition morphology of Brownian/non-Brownian particles within a constricted tube is investigated by applying the Brownian dynamics simulation method in the present paper. Two different geometric structures, the parabolic constricted tube (PCT) and the sinusoidal constricted tube (SCT), are adopted. The effect of various types of the total interaction energy curves of the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, and of the shadow area cast by those deposited particles, on the particles’ collection efficiencies are also examined. For the PCT structure, under the same interaction energy curve, it is found that the non-Brownian particles always own a higher collection efficiency than that of the Brownian particles. Since the deposition location moves closer to the constriction part of the tube, the collection efficiencies of the Brownian/non-Brownian particles increase with the decrease of flow velocity. The SCT behaves differently, it is found that the collection efficiencies of non-Brownian particles are only slightly higher than those of Brownian particles when SCT is adopted. The steep slope of the tube wall near the constriction part of SCT dominates the whole deposition process of Brownian/non-Brownian particles. In comparison with the available experimental data, it is found that the present method can give a good simulation result. 相似文献
109.
Veysel T. Yilmaz Evrim Senel Canan Kazak 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(3):407-413
The reaction of [Cu(sac)2(H2O)4] · 2H2O with 2-methylpyrazine (mpyz) leads two complexes, concomitant crystallization of a mononuclear complex [Cu(sac)2(mpyz)(H2O)2] (1) and a polymeric complex [Cu(sac)2(μ-mpyz)]n (2). Both complexes have been characterized by elemental analyses, magnetic measurements, FT-IR and ESR, TG-DTA and single-crystal
X-ray diffraction analyses. Single-crystal X-ray analyses show that complex 1 consists of discrete molecules in which the copper(II) ions exhibits a square-pyramidal coordination geometry. The individual
molecules of 1 are connected into a hydrogen-bonded chain structure, which is further assembled to form a three-dimensional network by π–π stacking interactions.
Complex 2 is an 1D coordination polymer in which copper(II) centers are bridged by the mpyz ligand. The chains are further assembled
to form two-dimensional frameworks by π–π and C–H···π stacking interactions. 相似文献
110.
分析实现永州电力通信交换网集中操作和维护的必要性,介绍了实现程控交换机远程操作和维护的两种方式,总结在实践过程中所得到的经验和教训。 相似文献