Fast determination of critical eluent composition for polymers by gradient chromatography

Gradient chromatography was applied in order to calculate the composition at elution for different methacrylates on normal phase columns. In addition the composition at elution was determined for polyethyleneoxide on a reverse phase column. It is shown that high molar mass polymers elute for a given homopolymer irrespective of their molar mass at the same eluent composition, which varies only slightly with gradient slope. In general the composition at elution in gradient chromatography is expected to be slightly lower than the true critical composition. For high molar mass polymers we found this composition to be close to the critical composition determined by isocratic experiments. The difference between the composition at elution and the true critical composition for a variety of polymethacrylates and for polyethyleneglycol was found to be only between 0.2 and 5%. Thus, after estimating the composition at elution, only a small number of additional isocratic experiments is needed to find the exact critical composition.     

SHS of shape memory CuZnAl alloys

Aiming at preparation of shape memory alloys (SMAs), we explored the SHS of Cu_{1 − x} Zn_{1 − y} Al_{1 − z} alloys (0.29 < x < 0.30, 0.74 < y < 0.75, and 0.83 < z < 0.96). The most pronounced shape memory effect was exhibited by the alloys of the following compositions (wt %): (1) Cu(70.6)Zn(25.4)Al(4.0), (2) Cu(70.1)Zn(25.9)Al(4.0), and (3) Cu(69.9)Zn(26.1)Al(4.0). The effect of process parameters on the synthesis of CuZnAl alloys was studied by XRD, optical microscopy, and scanning electron microscopy (SEM). The grain size of CuZnAl was found to depend on the relative amount of the primary CuZn and AlZn phases. Changes in the transformation temperature and heat of transformation are discussed in terms of ignition intensity and compaction. Mechanism of the process depends on the level of the temperature attained relative to the melting point of components. At the melting point of AlZn, the process is controlled by the solid-state diffusion of AlZn into a product layer. The ignition temperature for this system depends on the temperature of the austenite-martensite transformation in CuZnAl alloys. The composition and structure of the products was found to markedly depend on process parameters. The SHS technique has been successfully used to prepare a variety of SMAs.      

简析Ⅲ类PHC管桩的成因及加固补强处理方法

本文主要通过Ⅲ类PHC管桩的形成分析,经过各方论证采用了合适的处理方法,取得了较好的效果。     

边坡支护中多种技术措施的综合应用

通过工程实例,介绍了锚杆喷射混凝土支护技术与高压喷射混凝土搅拌桩支护技术在工程中的综合利用,同时也验证了该技术的可行性及经济性。     

高温季节大体积混凝土基础施工的裂缝控制

文章以上海富华大厦工程为例,对在高温季节如何针对大体积混凝土基础施工的裂缝进行控制,提出了相关措施,达到了控制裂缝的预期目标。     

影响道路沥青低温抗裂性能的因素

用弯曲梁流变仪、直接拉伸试验机对7种国内外油源沥青样品进行了低温抗裂性能的评价，从沥青的四组分、相对分子质量及其分布来分析其对沥青低温抗裂性能的影响，结果表明，沥青的相对分子质量分布宽，对沥青的低温抗裂性能有利。     

浅谈门式刚架轻型钢结构厂房中抗风柱的设置

通过对抗风柱上下端的节点几种形式进行分析比较,提出建议性的节点连续方式。     

Surface segregation studied by low-energy ion scattering: experiment and numerical simulation

The changes in surface composition of metallic alloys caused by segregation can be very efficiently studied by low-energy ion scattering (LEIS) due to the specific surface sensitivity of this technique. Investigations of single-crystal surfaces of ordered alloys are of particular interest because they provide the possibility to investigate the interplay between segregation effects and the order-disorder phase transition when passing through the transition temperature. Exemplifying these effects for bimetallic alloys we consider in particular the CuAu-system.For the quantitative interpretation of energy and angle resolved LEIS intensity distributions we compare experimental results with those from numerical simulations using the MARLOWE code which we extended with a detailed trajectory analysis. This allows us to apply various discrimination criteria, such as number of collisions, distance of closest approach, identification of the scattering crystal layer, total path length, etc. On this basis structural effects, ion survival probabilities and the influence of thermal vibrations can be studied.We demonstrate this potential by using CuAu(1 0 0) as a special example. The scattering potential parameters were calibrated with elemental single crystals of known structures and the anisotropic Debye temperatures taken from the literature showed good agreement, neutralization was of minor importance in this case. Our procedure could be successfully used for the quantitative analysis of the composition of the first and second layer as a function of temperature. These results are in good agreement with theoretical predictions.     

大型储罐基础非平面倾斜问题的探讨

大型储罐因基础产生非平面倾斜而影响其正常使用的情况在工程中时有发生,文章通过对某油罐工程中基础沉降观测结果的分析,探讨了储罐基础产生非平面倾斜的原因。相邻储罐之间的相互影响、充水预压未达到规范要求以及地基处理措施不当是引起储罐基础非平面倾斜的主要因素。针对相邻储罐间的相互影响,根据现行《石油化工企业设计防火规范》和《石油化工企业钢储罐地基与基础设计规范》的规定,提出以下建议:储罐布置的净距除应满足防火规范规定外,有条件时也应适当考虑对基础沉降的影响,当采用复合地基时,相邻储罐间的净距不宜小于0.6 D;当占地面积成为主要矛盾,储罐间的净距只能限制在防火规范规定的最小范围时,在地基处理时就应采取有效措施,以尽可能减少相邻储罐的相互影响。     

土工带加筋地基处理施工技术

结合中铁十二局2号小区7号楼工程加筋地基处理的施工，介绍了加筋地基处理的材料要求，设计特点，施工工艺及施工要点，得出该施工技术简单易操作，质量易保证，造价低廉，效果良好。