Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

SLIMLINE+K型多功能撬装双滚筒试井绞车简介

SLIMLINE K型多功能撬装双滚筒试井绞车为整体式结构，多用于海上平台，可进行电子压力计和机械压力计试井，以及井下工具的投放、震击、打捞等完井作业。该试井绞车采用先进的数控技术，使起下纲丝／电缆实现自动化控制，该系统能够对斜井、定向井进行随钻测试。     

珠钢不锈钢冶炼技术探讨

本文阐述了不锈钢冶炼的关键技术，为生产准备提供帮助。     

乳化型轧制液的质量标准研究

对国内目前所使用的冷轧薄钢板(汽车钢板)轧制液母液和乳化液的质量指标及常用试验评定方法进行了考察，并对产品的性能要求进行了研究与分析，制订出一套标准以供参考，包括乳化液稳定性、润滑性、防锈性、抗泡性、使用周期及粘度、闪点等性能。     

IF板与08Al板的成形性能研究

通过模拟成形性试验，对新型超深冲用IF钢板和传统冲压用08Al钢板的冲压成形性能进行了研究．结果表明：IF板的拉深性能、扩孔性能、胀形性能以及“拉深-胀形”复合性能等均优于08Al板，其中，扩孔性能和平面各向异性的改善最为显著；各项试验中，IF板的成形力普遍小于08Al板。     

美国钢铁企业的并购浪潮及特点分析

介绍了最近美国大型钢铁企业发生的主要并购活动。并对这些并购活动的特点进行了分析。     

Fatigue Behavior and Retrofit Investigation of Distortion-Induced Web Gap Cracking

This paper studies a Kansas Department of Transportation welded plate girder bridge that developed fatigue cracks at small web gaps close to the girder top flange. Repair had been previously performed by softening the connection plate end with a slot retrofit, but cracks were recently found to have reinitiated at some of the repaired details and are again propagating. A comprehensive finite-element method study was performed to investigate the cracking behavior observed in the bridge and to recommend appropriate measures for future bridge retrofit. The analytical results show that stresses developed at the top flange web gaps could exceed yielding under the loading of an HS15 fatigue truck. The current slot repair used in the bridge was found to have introduced higher magnitude fatigue stresses in the web gap. To achieve a permanent repair of the bridge, it is recommended that a welded connection plate to flange attachment be used during future bridge retrofit. The web gap details should be able to withstand unlimited number of load cycles once this additional repair is performed.     

含V、N无缝钢管表面外折缺陷产生原因的分析

通过对鞍钢生产的部分批号V、N微合金强化无缝钢管及生产该钢管的原料连铸坯和连轧管坯的表面缺陷进行研究，分析了含V、N钢管表面外折缺陷的成因，提出了改善钢管表面质量的方法。采用改进后工艺生产的无缝管，其表面外折废品量大幅度降低。     

薄板坯连铸生产SS400钢工艺技术研究

对唐钢薄板坯连铸机生产的SS400钢的生产工艺进行了分析,认为薄板坯连铸机生产的SS400钢,在采取了精炼站在线定氧,将钢水全氧控制在25×10~(-6)左右,同时连铸采取保护浇注和轻压下等技术后,能够确保薄板坯连铸SS400钢的顺利浇注,轧制的板带材表面质量良好,机械性能符合要求。     

爆炸焊接——热轧双相不锈钢复合钢板研制

本文主要阐述了通过爆炸焊接和热轧的方法,研制成功可焊性良好的且具有较好强度、韧性与综合性能的双相耐应力腐蚀的不锈复合钢板。还将热轧与热处理的两种试验作了较全面的常规、特殊检验试验,结果完全达到使用要求。