聚醚型聚氨酯的氢键、微相分离及性能

用本体一步法合成了5种不同硬段含量(11.0％～46.9％)的二苯甲烷-4,4′-二异氰酸酯/环氧乙烷封端型聚环氧丙烷聚醚/乙二醇的聚醚型聚氨酯,并借助于IR,DSC,DMS和材料试验机等手段对该聚氨酯的氢键、微相分离及力学性能进行了表征。结果表明:随着硬段含量的增加,其>NH与微区中的>C=O的氢键化程度逐渐提高,软段微区中—O—的氢键化程度逐渐降低;微相分离程度逐渐提高;拉伸强度及硬度随之增加,扯断伸长率在硬段含量40％左右出现极大值。     

基于话题链的汉语语篇连贯性描述体系

汉语简洁灵活的意合型篇章组合结构,对传统的基于关联词的篇章连贯性描述体系提出了新的挑战。该文引入话题链描述形式,设计不同类型的话题评述关系集,构建了以话题链为主,融合关联词语和其他连贯形式描述机制,覆盖话题评述、并列、因果、转折四大类关系的汉语语篇连贯性描述体系。在清华句法树库TCT上进行的验证实验,发现话题链和关联词语分别覆盖了约76%和50%的汉语复句,并且两者经常同时使用,初步证明了这个体系在句子连贯性描述方面的可行性和有效性。     

基于跨场景推理的事件关系检测方法

事件关系检测是一项面向事件之间逻辑关系的自然语言处理技术。事件关系识别的核心任务是以事件为基本语义单元,通过分析事件的篇章结构信息及语义特征,实现事件逻辑关系的深层检测。该文首次建立一套事件关系检测的任务和研究体系,包括任务定义、关系体系划分、语料采集与标注、评价方法等。同时,该文提出了一种跨场景推理的事件关系检测方法,该方法认为,具有相同事件场景的“事件对”,往往具有相同的事件关系类型。该文提出的基于跨场景推理的事件关系检测方法在针对四大类事件关系类型的检测精确率为54.21%。     

基于句法语义特征的中文实体关系抽取

实体关系抽取的核心问题是实体关系特征的选择。以往的研究通常都以词法特征、实体原始特征等来刻画实体关系,其抽取效果已难再提高。在传统方法的基础上,该文提出一种基于句法特征、语义特征的实体关系抽取方法,融入了依存句法关系、核心谓词、语义角色标注等特征,选择SVM作为机器学习的实现途径,以真实新闻文本作为语料进行实验。实验结果表明该方法的F1值有明显提升。     

FRP与混凝土界面粘结性能的试验研究

纤维(FRP)与混凝土的粘结性能是外贴纤维增强聚合物加固钢筋混凝土结构技术的关键问题。采用修正梁模型,对9个外贴FRP条带加固混凝土受弯构件的粘结性能进行了试验研究。分析了FRP应变、局部粘结剪应力发展规律以及沿粘结长度在各级荷载下的分布规律。考察了混凝土强度和FRP粘结长度对粘结强度等粘结性能的影响。验证了FRP有效粘结长度,探讨了有效粘结长度的影响因素,计算得到了局部粘结剪应力滑移关系曲线。通过对试验结果的统计回归分析,提出了局部粘结剪应力滑移本构关系模型以及有效粘结长度计算公式,分析结果与试验结果都吻合较好,可供实际加固改造工程应用及完善相应规范的编制参考。     

Composing Cardinal Direction Relations Based on Interval Algebra

Direction relations between extended spatial objects are important commonsense knowledge. Skiadopoulos proposed a formal model for representing direction relations between compound regions (the finite union of simple regions), known as SK-model. It perhaps is currently one of most cognitive plausible models for qualitative direction information, and has attracted interests from artificial intelligence and geographic information system. Originating from Allen first using composition table to process time interval constraints; composing has become the key technique in qualitative spatial reasoning to check the consistency. Due to the massive number of basic directions in SK-model, its composition becomes extraordinary complex. This paper proposed a novel algorithm for the composition. Basing the concepts of smallest rectangular directions and its original directions, it transforms the composition of basic cardinal direction relations into the composition of interval relations corresponding to Allen''s interval algebra. Comparing with existing methods, this algorithm has quite good dimensional extendibility, that is, it can be easily transferred to the tridimensional space with a few modifications.     

Deformation simulation of low-temperature high-speed extrusion for 6063 Al alloy

The hot compression test of 6063 Al alloy was performed on a Gleeble-1500 thermo-simulation machine, and the forming of 6063 rod extrudate in low-temperature high-speed extrusion was simulated with extrusion ratio of 25 on the platform of DEFORM 2D successfully. From the compression experimental results, the flow stress model of this Al alloy is obtained which could be the constitutive equation in the simulation of low-temperature high-speed extrusion process. From the numerical simulation results, there is a higher strain concentration at the entrance of the die and the exit temperature reaches up to 522 °C in low-temperature high-speed extrusion, which approaches to the quenching temperature of the 6063 Al alloy. The results show that the low-temperature high-speed extrusion method as a promsing one can reduce energy consumption effectively.