分子振动态及其跃迁的激光相干控制

讨论了激光合成相干叠加态的原理及其性质 ,针对 XY2 型分子 ,证明了合成局域模振动的可行性 ,然后给出相干叠加态的跃迁几率特征 ,发现它仍表现出相干的特性 ,对之进行分析研究表明 ,分子的振动态具有可控性 ,态跃迁几率具有可控性。     

自旋为j的粒子在旋转磁砀中的几何相位

用相干态的方法得到旋转磁场中自旋为j的粒子的态矢量的严格表达式，由此可计算相干态和叠加相干态的Abaronov－Anandan相位（AA相让）．并具有清楚的物理图象．     

简并量子拍频三能级系统中的光场压缩效应

本文讨论了V-型简并量子拍频三能级原子与单模相干辐射场相互作用时的动力学行为，并研究了光场的压缩效应。     

An equation of state for 1,1-difluroethane (HFC 152a)

An equation of state for 1,1-difluoroethane (HFC 152a, CH₃CHF₂) has been developed on the basis of reliable experimental data including PVT, liquid C_p, and saturated-liquid-density data measured by our group. It is a non-dimensionalized virial equation whose functional form is the same as that originally developed for 1,1,1,2-tetrafluoroethane (HFC 134a) in our group. The effective range is for pressures up to 15 MPa, temperatures from 230 to 450 K, and densities to 1000 kg m⁻³. The equation represents reliable PVT measurements within ± 1% in pressure for the superheated vapour and supercritical fluid, while within ±0.5% in density for the compressed liquid. In addition, it should be noted that the equation represents the other essential thermodynamic properties including vapour pressures, saturated-liquid/ vapour densities, isobaric/isochoric specific heats and sound velocity in both the liquid and gaseous phase of HFC 152a.     

Reaction steady states and stationary states in modelling semi-batch enzyme hydrolysis

Dimensionless material balance equations describing an uninhibited enzyme hydrolysis process in a semi-batch reactor (i.e. fed-batch reactor) are formulated; numerical solution of these equations provided concentration profiles of the enzyme-substrate complex by using published kinetic parameters. The unrestricted values obtained are compared with estimates based separately on the reaction steady state and stationary state assumptions. Results are discussed in terms of the enzyme/substrate inventory used and it is found that the reaction steady state is a satisfactory approximation only when this ratio is sufficiently small. The stationary state may be a better approximation at other values, particularly when enzyme is added to substrate or when an empty tank is being filled. Reaction yields from semi-batch and batch operations are compared. Processing takes longer in the semi-batch operations and complete conversions are only practical in this mode when enzyme is added to substrate.     

Impact of uncertainties on estimations of heat pump cycle performance

Sensitivity analysis is used to show how uncertainties in basic factors, such as heat transfer, pressure drop, compressor efficiency, and thermophysical properties, influence the result of heat pump cycle performance estimations. By comparing the results of this analysis with uncertainty levels of estimations and experimental determinations, it is established to what extent improvements in accuracy are needed. The investigation was carried out for several different applications and, as working fluids, both pure substances and non-azeotropic mixtures were examined. It was found that evaporation heat transfer and compressor efficiency are two areas where improvements are needed. It is also shown that estimates using very accurate, substance-specific, equations of state differ from those using more general types by up to 1 % for COP and 2% for capacity.     

基于Patel-Teja状态方程的统一粘度模型(Ⅱ)应用于油气藏流体粘度的预测

基于(I)报根据pVT和Tμp图形的相似性和Patel-Teja状态方程建立的预测纯流体气、液相粘度的统一模型,通过引入常规的状态方程参数的混合规则,将其应用于二元轻烃混合物共计1894个数据点及模拟天然气高压粘度的预测,平均相对误差分别为13.78%和16.75%;应用于油藏原油和天然气高压粘度的预测,结果优于现有的有关油气藏流体粘度模型.     

聚苯胺锂基润滑脂载流润滑下的摩擦学性能

制备了导电聚苯胺锂基润滑脂（简称PANI脂）和铜基银镀层材料（简称银层材料）。采用摩擦磨损试验机考察在无载流、载流及边界润滑条件下，铜基体材料（简称铜基材料）和银层材料的摩擦磨损性能。采用X射线衍射（XRD）、扫描电子显微镜（SEM）和电子能谱（EDS）对银层材料晶相及其表面磨斑形貌进行表征。结果表明，载流条件下，PANI脂润滑试验时的银层材料不仅具有良好的减摩抗磨性能，而且导电能力更强，其优异的减摩和抗磨性能归功于摩擦表面的保护膜和电流热效应引起的表面软化双重作用。