Study of viscosity of mono-, di-, and trialkylamines

Viscosities of several mono-, di-, and trialkylamines have been measured in the temperature range 298 to 333 K. It is observed that viscosities are highly dependent on shape, size, and association through H-bond or through dipole. Following the transition state theory, energy, Gibbs free energy, and entropy of activation of viscous flow have been calculated. The values of expansion energy for these liquids have also been calculated using free volume theory, and subsequently amines have been classified as volume-restrained or energy-restrained liquids. The group contribution method of Van Velzen, Cardozo, and Langenkamp for estimating viscosity has been examined with the present and literature data, and the new group contribution increments N _i and B _i for amines have been evaluated.     

并行仿真中全状态保存技术研究

乐观时间同步机制能够显著提高并行仿真的性能,但是在乐观时间推进过程中会出现因果错误,需要根据保存的状态对事件进行回退,因此事件状态保存机制是影响乐观时间推进效率的重要因素。本文首先简要介绍了并行仿真中逻辑进程的执行过程,讨论了乐观时间推进的状态保存与回退机制;然后对全状态保存技术进行了建模和理论分析,并通过实验测试了全状态保存算法的性能,测试结果验证了理论分析的正确性。     

基于ASM的混合式情境感知共享机制研究

移动的用户能够方便地访问分布在普适计算环境中的传感器,进而获得情境信息,是情境感知系统的核心目标。本文提出了一种融合分布式P2P和Publish/Subscribe模式的混合式情境感知共享机制,基于抽象状态机对该机制的高鲁棒和可扩展的特性进行设计和规约,并采用AsmL测试工具生成有限状态机验证该机制的有效性和合理性,表明该机制可满足动态的分布式情境感知系统要求。     

可靠性技术在继电器控制中的应用

本文以可靠性技术,针对继电器在使用时主要失效模式触点失效故障进行分析,从触点材料、控制负载、抑制触点电弧,并对触点在常用环境下不合理使用等问题一并进行了较详细的阐述。     

基于红外检测的变电站设备热状态诊断

提出了一种基于红外检测的变电站设备热状态诊断方案。首先基于变电站设备的红外图像,采用局部方差映射函数和遗传算法阈值提取了变电站设备的热状态数据,以用于对异常区域进行分割。然后构建了红外图像灰度数与变电站设备温度两者之间的关系。最后采用改进的相对温差法达到了对设备热状态进行分类和诊断的目标,并捕获定位了变电站设备的热状态异常区域。实验结果表明,该方法提高了异常热区提取的精度和效率,提升了变电站设备热状态诊断的容错能力,进一步保证了变电站和整个电力系统的运行稳定性。     

基于卡尔曼滤波的电力虚假数据注入攻击检测方法

能源互联网的主体是基于状态估计下的电力系统。虚假数据注入攻击（FDIA）通过恶意篡改或注入电力数据,进而引发错误的状态估计结果。这种攻击方式存在引发大面积停电事故的风险,严重影响能源互联网的正常运行。在matpower 4.0中的IEEE-14节点系统上,利用以残差方程为基础的标准残差检测法和目标函数极值法,对FDIA进行了检测实验。提出了一种基于卡尔曼滤波的FDIA检测方法,并在MATLAB上进行了验证。实验结果表明,该方法可以在短时间内发现FDIA的发生。     

高空作业平台臂架伸缩运动的横向振动特性

为了探究高空作业平台做伸缩运动时变幅平面内的横向振动动力学特性,针对臂架的实际搭接和支承情况,将臂架等效为根部铰接、中间弹性支承且带有集中参数的变截面变长度梁. 基于牛顿第二定律建立各臂段的运动微分方程,采用模态叠加法、结合边界条件求解臂架一系列时刻的瞬态振型函数,曲线拟合时变参数以近似表示梁的振型,并依据伽辽金截断方法,得到广义坐标下的状态空间方程. 在Matlab/Simulink环境下进行动态仿真,得到伸缩过程中臂架头部的变幅平面横向振动动态响应. 结果表明,就横向振动振幅而言,搭接简化会带来15.63%计算结果误差;支承简化会加大臂架整体刚度、减小臂架振动响应,不可取。     

高强度结构钢的韧性启裂和稳态扩展

研究了具有一定韧度的高强度结构钢裂纹早期扩展阻力与材料的微观组织结构、应力状态、变形历史和应变特性之间的关系。结果表明:裂纹扩展阻力(指J_R阻力曲线中的J_i和dJ/da)主要决定于裂纹尖端的塑性约束程度和应力应变场中消耗的弹性能和塑性功。这与三轴应力状态函数σ_mσ~(1/2)有关。材料的流变曲线描述了形变过程中的变形历史和应变特性,有明显的阶段性,其中第Ⅱ阶段的变形历史和应变特性制约着裂纹的启裂过程,第Ⅲ阶段的变形历史和应变特性制约着裂纹的扩展过程。应变硬化率dσ/dε可以敏感地反映出材料内部的应力分布和微观断裂机制。     

接触疲劳过程中的诱发相变和冷作硬化SCIEI

研究了三种丝杠钢的接触疲劳性能。利用TEM和背散射Mossbauer谱研究了三种钢在接触疲劳前后的显微组织结构;测量了接触区中心线下显微硬度随层深的变化。结果表明:接触应力诱发A_R→M相变,并导致一定深度的冷作硬化。讨论了诱发相变和冷作硬化对接触疲劳性能的影响。     

The transient state in the oxidation of binary alloys forming the most-stable oxide: A numerical solution

The initial transient high-temperature oxidation stage for binary alloys forming the most-stable oxide has been examined by means of a numerical procedure based on the finite-difference method. At variance with previous models, the present treatment takes into account the effect of the rate of the reaction at the scale/gas interface over the corrosion kinetics. The calculations concerning the transient stage are developed either using the general parabolic rate law to represent the overall scaling kinetics or using the rate law of the reaction at the scale/gas interface as a boundary condition without imposing any particular rate law to the overall process. A correct analysis of the oxidation behavior of binary alloys during the transient stage must take into account the kinetics effect of the rate of the surface reaction. The concentration of the most-reactive element at the alloy/scale interface changes regularly with time, decreasing gradually from the initial bulk value to its final steady-state value. The present results are in good agreement with those obtained by means of an approximate analytical model developed previously.