Validity of dynamic electrochemical impedance spectra of some amine corrosion inhibitors in petroleum/water corrosive mixtures by Kramers-Kronig transformation

In our previous works, the corrosion inhibition properties of propylamine (PA), iso-propylamine (i-PA), butylamine (BA), tert-butylamine (t-BA), hexylamine (HA), ethylenediamine (EDA), diethanolamine (DEA), 3-amino-1-propanol (3-AP), 2-dimethylethanolamine (2-DEA), cyclohexylamine (CHA), N-methylcyclohexylamine (N-MCA) and dicyclohexylamine (DCHA) have been investigated by means of electrochemical impedance spectroscopy (EIS) with a carbon steel rotating disc electrode in some petroleum/water corrosive mixtures containing acetic acid and NaCl at 25 °C. In this work, the Kramers-Kronig transformations (KKTs) were applied to evaluate the validity of the impedance data of these amine compounds in hydrodynamic condition. The results obtained showed that experimental impedance data did not satisfy in K-K relations completely viz. indicated some errors. These errors were related to stray capacitances, external transmission line effects, pits formation and change in interface during data acquisition at high and low frequencies regions. In addition, the selection of a suitable equivalent circuit strongly emphasized to better interpret of EIS data which in turn cause better resulted KKTs spectra. With considering obtained transformations, more effective inhibitor was selected with regard to its charge transfer resistance, the corrosion capacitance and well satisfying in K-K relations.     

影响长廊阻抗式调压室配筋的几个因素分析

采用三维非线性有限元方法,对四川天全县干溪坡水电站调压室结构特性进行研究,并对几个影响配筋的因素进行敏感性分析,得出各个因素对配筋结果的影响,为调压室结构设计提供科学依据。     

Corrosion Behavior of a Sputtered K38G Nanocrystalline Coating with a Solid NaCl Deposit in Wet Oxygen at 600 to 700°C

A nanocrystalline coating of K38G alloy was obtained by means of magnetron sputtering. The corrosion behavior of cast K38G alloy and its sputtered nanocrystalline coating with a solid NaCl deposit in dry air or wet oxygen at 600 and 700°C have been studied and compared. The results indicated that the mass gain of the coating is higher than that of the cast alloy at 600 and 700°C. Therefore, nanocrystallization reduced the corrosion resistance at these temperatures. Furthermore, the mass gains of the coating and the cast alloy with a NaCl deposit in wet oxygen were less than that with a NaCl deposit in dry air. The relevant corrosion mechanisms are discussed.     

蒸馏与减粘热联合装置的设备腐蚀及防护

介绍了锦西石化分公司南蒸馏与减粘热联合装置炼制辽河高酸值原油及带炼高硫进口油在 2 0 0～40 0℃范围内对设备、管线和阀门的腐蚀特点、腐蚀机理以及针对高温环烷酸腐蚀所采取的防护措施。通过试验和理论分析 ,提出了应用新材料和新工艺解决减粘后高温渣油系统的腐蚀及低温露点腐蚀的建议     

全密封变压器用波纹油箱的波纹高计算

介绍了全密封变压器所用的液纹油相的波纹筋高的计算方法，并用试验进行了验证。     

罐装食品用电镀锡板的耐蚀性及其试验方法

综述了影响罐装食品用电镀锡板耐蚀性能的因素及其试验方法。     

氨荒酸盐抑制铜在NaCl溶液中腐蚀的电化学研究

通过电化学极化曲线和失重实验,研究了氨荒酸盐对铜在氯化钠溶液中的缓蚀性能,并与相应胺的缓蚀性能进行了对比。结果表明:氨荒酸盐对铜具有较好的缓蚀性能。     

Electrochemical impedance spectroscopy of a free-standing oxide film

The corrosion of low carbon steel in natural sea-water is characterized by the formation and growth of compact and thick layers composed of oxides, insoluble salts and organic materials. These layers are the result of corrosion processes induced by local environmental conditions, water oxygen supply; ionic species; bacteria and organic matter. The exchange of various species (ions, molecules, gas) between sea-water and the rust layers or the metal depends both on the kinetics of the Faradaic reactions of the entities with either the oxides or the metal, as well as on their transport properties through the different strata of the rust layers. In this work, an impedance study was carried out using the 4-electrodes cell arrangement with corrosion products picked up on steel sheet piling immersed for 25 years and analyzed as free standing membranes. This new approach is a good way to reach the specific transport and transfer properties of the oxide without being blurred by the metal influence. The physical model developed in this work was based on a transmission line, and accurately described the experimental diagrams. The electronic resistivity of the oxide layer, its porosity, the mean pore size and the reaction kinetics parameters could be determined from the fittings.     

常减压蒸饱装置几起典型硫腐蚀事例分析

随着高（含）硫原油加工量的增加,硫腐蚀事故也时有发生。通过对常减压装置硫腐蚀事例进行分析,指出合理的混炼比,加强“一脱三注”管理,材料升级和实施腐蚀监测是防止腐蚀事故发生的有效措施。     

钢铁表面黑色转化膜处理技术

黑色转化膜技术是目前较为先进的钢铁表面处理技术 ,本文试验研究了一种新工艺 ,提出了TB值的概念 ,通过控制TB值即可控制处理液的质量 ,获得性能优良的转化膜。此工艺性能可靠 ,可操作性强 ,并可应用于激光热处理前的预处理。