非线性地基上桩结构物空间分析

本文提出了桩结构物－非线性地基空间相互作用分析的迭代法和非线性有限元法。其中，桩基分析用ｐ－ｙ曲线法。结合实际结构物进行了大量的计算及比较分析，成果是令人满意的，可以付诸应用。     

Expressing the equivalence of non‐isothermal and isothermal heat sterilization processes

Currently, the sterility of heat‐processed food and pharmaceuticals is assessed in terms of an F₀ value, based on the equivalence of the heat treatment to an isothermal process at a reference temperature. This F₀ value, however, has a meaning if, and only if, the inactivation kinetics of the targeted spores (or cells) follow a first‐order relationship and the temperature dependence of the D value, the reciprocal of the rate constant, is log‐linear. There is growing evidence that these conditions are not satisfied by many spores, including those of Clostridium botulinum and vegetative cells. Consequently, a replacement for the F₀ value is proposed in the form of a momentary equivalent time at the reference temperature based on the actual survival pattern of the spores, which need not be log‐linear. This equivalent time can be calculated together with the theoretical survival ratio in real time, thus enabling an operator to monitor the lethality of ongoing industrial heat processes. The concept is demonstrated with published survival data of C. botulinum, for which the Weibullian and log‐logistic models served as primary and secondary models, respectively. The safety factor according to the proposed method is in the number of added minutes of processing, beyond the theoretical time needed to reduce the survival ratio of the targeted spores or cells to a level that would produce practical (or commercial) sterility. Copyright © 2006 Society of Chemical Industry     

Isometric Piecewise Polynomial Curves

The main preoccupations of research in computer-aided geometric design have been on shape-specification techniques for polynomial curves and surfaces, and on the continuity between segments or patches. When modelling with such techniques, curves and surfaces can be compressed or expanded arbitrarily. There has been relatively little work on interacting with direct spatial properties of curves and surfaces, such as their arc length or surface area. As a first step, we derive families of parametric piecewise polynomial curves that satisfy various positional and tangential constraints together with arc-length constraints. We call these curves isometric curves. A space curve is defined as a sequence of polynomial curve segments, each of which is defined by the familiar Hermite or Bézier constraints for cubic polynomials; as well, each segment is constrained to have a specified arc length. We demonstrate that this class of curves is attractive and stable. We also describe the numerical techniques used that are sufficient for achieving real time interaction with these curves on low-end workstations.     

Group codes on certain algebraic curves with many rational points

We construct a series of algebraic geometric codes using a class of curves which have many rational points. We obtain codes of lengthq ² over _q , whereq = 2q ₀ ² andq ₀ = 2 ⁿ , such that dimension + minimal distance q ² + 1 – q ₀ (q – 1). The codes are ideals in the group algebra _q [S], whereS is a Sylow-2-subgroup of orderq ² of the Suzuki-group of orderq ² (q ² + 1)(q – 1). The curves used for construction have in relation to their genera the maximal number of GF _q -rational points. This maximal number is determined by the explicit formulas of Weil and is effectively smaller than the Hasse—Weil bound.Supported by Deutsche Forschungsgemeinschaft while visiting Essen University     

矿用隔爆兼本安型计算机信号隔离器设计

针对煤矿井下电气设备要求本质安全的特点,设计了一种矿用隔爆兼本安型计算机信号隔离器,主要介绍了该隔离器的硬件电路设计。该隔离器主要用于矿井中本质安全型计算机主机与外部输入输出设备的连接,能够实时地传送键盘输入的数据,具有良好的信号隔离功能和抗干扰性能。     

致密油藏直井多层缝网压裂产量递减分析

垂向多层发育的致密油藏常采用缝网压裂进行开采,从而改善储层渗透率,提高油井产量。为此建立直井多层缝网压裂不稳定渗流数学模型,压裂后各层划分为人工裂缝区、改造区和未改造区。绘制分析Blasingame产量递减典型曲线,曲线分为7个流动阶段,总裂缝长度一定时,裂缝半长短的储层流体渗流率先到达未改造区,流体渗流阻力大,Blasingame曲线靠下;总改造体积一定时,各层改造体积差异越大,Blasingame曲线越靠下。用所建立的模型,对实测生产资料进行解释,获得各层裂缝半长、改造区渗透率等相关地层参数,该模型对进行多层缝网压裂直井产量分析具有指导意义。     

Molybdate and tungstate as corrosion inhibitors for cold rolling steel in hydrochloric acid solution

The inhibition effects of molybdate and tungstate on the corrosion of cold rolling steel (CRS) in hydrochloric acid solution (0.1-0.5 M) were investigated by weight loss and electrochemistry methods. The results reveal that both molybdate and tungstate are very good inhibitors with little concentration. The adsorption of inhibitors on the CRS surface basically obeys the Langmuir adsorption isotherm equation. The effect of temperature on the corrosion behavior of CRS was also studied at 25 °C and 35 °C, the thermodynamic parameters such as adsorption heat (ΔH⁰) and adsorption free energy (ΔG⁰) were calculated. In the same conditions, a comparative study of corrosion inhibition of molybdate and tungstate indicated that molybdate was the better inhibitor in 0.1 M HCl. However, the value of percentage inhibition efficiency (IE) was dependent on the concentration of inhibitors in 0.2-0.5 M HCl. It seemed that molybdate did not have the strong inhibitive effect compared to tungstate with relatively small concentration of inhibitors, but molybdate was a better inhibitor over a wide concentration range of inhibitors. A kinetic study of cold rolling steel in uninhibited and inhibited acid was also discussed. Various parameters such as rate constant k and the kinetic parameter B were calculated for the reactions of corrosion. Polarization curves showed that both molybdate and tungstate are mixed-type inhibitors in acidic media.     

保单调插值的奇异混合三角/双曲B样条

为了使得插值曲线保单调,设计了两类新的平面参数曲线及其保单调插值算法.计算奇异混合函数,把三角/双曲多项式B样条曲线与奇异多边形通过奇异混合函数混合,无需解方程组或繁琐的迭代,得到自动插值给定平面点列且C2(或G1)连续的带形状参数的复合曲线,尤其能得到摆线、螺旋线、双曲线、悬链线等各类超越曲线.通过把插值曲线的导矢分量转化为类Bernstein多项式,并且利用Bernstein多项式非负的充要条件,得到插值曲线单调的充要条件,获得形状参数合适的取值范围. 该方法简单方便,所得参数范围保证了插值曲线保单调.     

甲基偶氮四唑热稳定性和热分解机理的量子化学研究

采用量子化学方法全优化计算了1—甲基—5—偶氮四唑(1—MAT)和2—甲基—5—偶氮四唑(2—MAT)热分解反应位能曲线，探讨了热稳定性和分解机理。热分解活化能计算值分别为245．9，183．2k／mo1，静态分子结构和动态分解性质都显示出1—MAT比2—MAT有更好的热稳定性。裂解优先以开环方式发生。