EFFECT OF CRACKING REACTIONS KINETICS ON THE MODEL PREDICTIONS OF AN INDUSTRIAL FLUID CATALYTIC CRACKING UNIT

Fluid catalytic cracking (FCC) is one of the most complex processes in the petroleum industry. The large degree of uncertainty in the kinetics of the cracking reactions and catalyst deactivation by coke deposition in the riser reactor are among several factors that contribute to the process complexity. The model developed by the authors (Ali and Rohani, 1995) is used lo investigate the effect of the three-lumped kinetic scheme (Weekman and Nace, 1970) and the four-lumped scheme (Lee ct ah, 1989) on the model predictability and reliability. The effect of changes in the catalyst circulation rate, gas oil feed rate, and oxygen feed concentration on various process variables is compared. It is shown that the three-lumped kinetic scheme, despite its extensive use in the literature (McFarlane et ah, 1993; Elnashaie and Elshishini, 1993; Theologos and Markatos, 1993; Arandes and de Lasa, 1992; Lopez-lsunza and Ruiz-Martinez, 1991), leads to erroneous results and should not be used in the dynamic simulation of the FCC units,     

重油接触裂解制乙烯的HCC工艺研究

重油裂解制乙烯的HCC技术采用与FCC类似的“反应—再生”工艺技术,利用重油直接裂解制乙烯,兼产丙烯、丁烯和轻质芳烃,既可扩大乙烯的原料的来源,又可降低生产成本。HCC工艺的乙烯产率可达19%～27%,总烯烃产率大于50%。     

用于数控设备的弹性环联轴器

介绍了一种适用于数控设备改造的无键联轴器，从其原理、设计、加工各方面作了阐述，并且总结了许 多实际应用经验和适用参数。     

重油催化裂化反应技术的新进展

近十几年来，重油催化裂化技术作为主要的重质油轻质化手段得到了迅速发展，国内外围绕催化裂化装置的提升管反应器也开发了许多新技术。综述了重油催化裂化反应技术的新进展，并对新技术的开发进行了讨论。     

Study of Desorption Agent for LADS Process

This article refers to the procedure for selection, evaluation and development of the LADS-D desorption agent associated with the LADS-A adsorbent used in the non-hydroprocessing adsorptive desulfurization (LADS) process for FCC naphtha developed by LPEC Refining Research Institute. The LADS-D desorption agent can effectively remove the sulfides adsorbed on the LADS-A adsorbent. The saturated LADS-A adsorbent can be instantly regenerated by the LADS-D desorption agent to recover its adsorption activity. The LADS-D desorption agent can not only effectively remove all impurities adsorbed on the adsorbent, but also has strong ability to dissolve the impurities to keep a stable desorption efficiency of adsorbent to be basically commensurate with fresh adsorbent after extended use.     

防止大型筒类薄壁件冷裂的工艺措施

采取了加强铸件薄弱断面处强度和提高砂芯整体“宏观”退让性八项工艺措施，有效地防止大型筒类薄壁件冷裂纹缺陷     

Unusual W-shaped Galvanic Cell Model of ISCC of α-brass in Neutral Mattsson''''s Solution

Intergranular stress corrosion cracking(ISCC) of α-brass in neutral Mattsson's solutionwas found to be controlled by an unusual"W"-shaped galvanic cell whose cathode is thegrain boundary oxide film (G.B.0. film) andsurface film and the anode is fresh metal atthe cracked tip on both sides of the G.B.0.film. Redox reactions involved in the cellhave been proposed here. According to thismdel, initidtion of ISCC is caused by therupturing of surface film along grain boundaries,thus forming a galvanic cell. Propagation ofISCC resulted from alternate advances of G.B.0.film and dissolution on both sides of G.B.0.film caused by the effect of electrochemicalreaction. This work developed an effective approachto investigate the embrittlement process atthe tip of the crack, by increasing the lengthof the embrittlement region through constantstrain test and distinguishing the morphologyand the nature of the corrosion products byoptical microscopy and scanning electronmicroscopy (SEH).     

分段线性动态矩匹配条带去除

由于探测器之间对接收的地物辐射信号的响应特征不同,导致遥感数据含有条带噪声,严重影响了图像质量及后续的定量计算。针对探测器响应函数在图像低值区及高值区呈非线性的特点,在着重分析矩匹配方法的基础上,提出分段线性动态矩匹配条带去除方法。方法设定阈值分割高中低值域统计区间,对探测器响应函数进行分段线性拟合,并对探测器每一分图像动态采用其领域内均值和标准差作为参考值进行条带纠正。应用TM数据第4波段及环境一号卫星高光谱数据进行去条带实验,并定性和定量地比较了该方法与动态矩匹配、傅里叶变换、自动均衡化曲线方法的去条带效果。结果表明该方法能够在保留图像基本信息的前提下,获得最佳的去条带效果,尤其能够提高非均匀地物分布区域内水体的条带去除效果。     

管线用钢氢致裂纹(HIC)影响因素分析

研究了管线用钢的化学成分和金相组织对钢的氢致裂纹(HIC)性能的影响。研究认为,带状组织和马氏体含量对HIC性能有很大影响,S含量及Cep对HIC有不同程度影响。含有少量Cu、Ni的钢更适合在酸性环境下使用。     

中厚板轧机牌坊窗口变形问题的分析

对多年来二重在中厚板轧机制造装配过程中收集的数据进行统计分析，并结合牌坊受力、支持力对牌坊立柱作用产生的弯矩及弯矩使立柱产生挠度等进行论证，剖析轧机牌坊立装后产生“缩腰’’的原因，给设计工作提出了相关的建议。