16Mn钢疲劳短裂纹扩展

用带有盲孔的16Mn钢小圆棒试样进行等幅加载的疲劳试验,研究盲孔边短裂纹的扩展。建立了短裂纹平均扩展速率、裂纹长和名义应力幅的表达式,分析考察了短裂纹扩展的统计规律,讨论了裂纹表面尺寸分布随疲劳循环数的演化情况。     

V形件弯曲凹模最小深度的确定

该文指出了目前广泛使用的经验查表法确定V形件弯曲凹模深度的不合理性，分析了凹模斜壁的作用及其与圆角半径的相互关系，提出了凹模最小的深度的概念和计算公式。     

U形件弯曲影响回弹因素模拟分析

板材在弯曲过程中存在的最突出的问题是弯曲回弹难以精确控制.弯曲卸载后产生的回弹,使弯曲件的形状和尺寸与模具工作部分的形状和尺寸不符.弯曲件的最后形状与整个变形过程有关,模具几何参数、材料性能参数等都会对回弹产生很大影响.在板材弯曲成形智能化控制系统中,准确确定实时识别和预测模型的输入、输出参数是弯曲智能化控制的成功与否以及回弹控制精度高低的关键.本文采用Ls-dyna软件,对U形件弯曲影响回弹的因素进行了分析,得出了影响回弹规律的主要因素.为U形件弯曲智能化控制神经网络参数识别及预测模型输入、输出参数的选择提供依据.     

Q235B H型钢冷弯开裂原因分析

利用宏观检验、化学成分分析、力学性能测试及金相检测等方法对Q235B H型钢冷弯开裂试样进行分析。结果表明:在冷弯试验过程中,粗大的条状塑性夹杂物和点链状脆性夹杂物与基体的结合性较差,冷弯过程中夹杂物脱落或周围应力集中形成空隙或显微裂纹,随着受力状态的加强导致裂纹扩张形成冷弯开裂的裂纹源,在开裂过程中带状组织和加工痕迹加剧了裂纹的扩大。     

基于关联设计的弯曲级进模结构CAD方法研究

介绍了基于关联设计的弯曲级进模结构设计方法,描述了级进模装配约束关系的模型、弯曲工序对象和弯曲模组件对象,提出距离约束、几何约束、尺寸约束、依附约束4种约束方法。详细阐述了级进模弯曲设计中的装配树组织结构、关联设计、约束求解、参数化关键技术,及在此基础上实现的弯曲级进模块的设计流程和实现方法。     

Electrochemical behaviour of Mn3+/Mn2+, Co3+/Co2+ and Ce4+/Ce4+ redox mediators in methanesulfonic acid

The redox behaviour of Mn³⁺/Mn²⁺, Co³⁺/Co²⁺ and Ce⁴⁺/Ce³⁺ mediators commonly used in indirect oxidation of organic compounds were evaluated in methane sulfonic acid on a glassy carbon working electrode employing cyclic voltammetry. Manganic methanesulfonate exhibits higher instability in dilute methanesulfonic acid. The solid MnO₂ formed during disproportionation on the glassy carbon electrode further affects the reproducibility. Cobaltic methanesulfonate formation occurs only at oxygen evolution region rendering the overall oxidation process less efficient. Ceric methane sulfonate formation is highly efficient over a wide acid concentration range. Ceric methanesulfonate can also be employed over a wide temperature range to oxidize different aromatic compounds.     

Fractionation of partially stereoregular poly(propylene oxide)

Partially stereoregular poly(propylene oxide) samples were synthesized via reactions catalysed by a preformed analytically defined trimethylaluminium hydrolysate. These samples were fractionated into two contrastingly different fractions.

1. (i) D-polymers: This fraction constituted the major part (up to 90%). It mainly contained cyclic low molecular weight oligomers (MW < 1000). The linear chains found in D-polymers had hydroxyl end groups. No double bonds could be detected spectroscopically.

2. (ii) K-polymers: This fraction was high molecular weight stereoregular polymer. Stepwise thermal precipitation from dilute isooctane solution of K-polymers yielded a succession of fractions which differed in melting point. It appears that the phase equilibria during the thermal precipitations were not controlled by the molecular weights of species.

Electrochemical pitting behaviour of type 321 stainless steel in sulfide-containing chloride solutions

The pitting behaviour of type 321 stainless steel in sulfide-containing chloride aqueous environments was studied using cyclic potentiodynamic polarization. A well-established correlation between H₂S and Na₂S₂O₃ in the study of corrosion was applied, that is, H₂S was simulated by Na₂S₂O₃. The major factors affecting the pitting corrosion of type 321 stainless steel are the Cl^- concentration, solution pH and temperature. The results clearly indicate that both E_pit and E _pp decrease with increasing Cl^- concentration and temperature, while I _pass is more sensitive to temperature variation. E _pit decreased with decreasing pH in the range 2 < pH < 7.5. The surface morphology and chemistry of the corroded type 321 stainless steel resulting from anodic polarization in 0.01 M S₂O ₃ ^2- -containing Cl^- solution were analysed by XRD, SEM and EPMA. A higher concentration of sulfur was found in the pits, and the dark surface film was mainly composed of FeS and -Fe₂O₃. The results describe the pitting behaviour of type 321 stainless steel in sulfide-containing Cl^- aqueous environments.     

A/O结合循环式活性污泥法处理海产品加工废水

针对海产品加工废水氨氮含量较高的特点。舟山兴业有限公司的污水处理工程采用两段A/O结合循环式活性污泥法工艺，工程验收合格后运行一年多来，排放废水的各项污染指标均达到国家《污水综合排放标准》（GB8978-1996）的二级标准，处理系统具有很好的抗冲击能力和脱氮效果。     

用弯曲模型推导二组元复合材料杨氏模量新公式

用弯曲模型推导了适用于悬丝耦合弯曲共振法检测金属第二组元的杨氏模量的理论公式。通过实验数据计算。结果表明在两组元h2/h1≈1时与文献[2]的计算结果几乎接近，为用悬丝耦合弯曲共振法检测各种减振材料，陶瓷材料杨氏模量提供了理论公式；同时用改进后的弯曲模型推导出了适用于纤维复合材料横向杨氏模量的预测公式。