Author Keywords: trimethylaluminium hydrolysate; stereoregular; poly(propylene oxide); fractionation; end-group analysis; cyclic oligomers 相似文献
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151.
The effect of thermal shock on the spalling of oxides from the surfaces of several commercial alloys was determined. The average cooling rate was varied from approximately 240°C/sec to less than 1.0°C/sec during cyclic oxidation tests in air. The tests consisted of 100 cycles of 1 hr at the maximimum temperature (1100 or 1200°C). The alloys were HOS-875, TD-Ni, TD-NiCrAl, In-601, In-702, and B-1900 plus Hf. All of these alloys exhibited partial spalling within the oxide rather than total oxide loss down to bare metal. Thermal shock resulted in deformation of the metal, which in turn resulted, in most cases, in change of the oxide failure mode from compressive to tensile. Tensile failures were characterized by cracking of the oxide and little loss, while compressive failures were characterized by explosive loss of platelets of oxide. This behavior was confirmed by examination of mechanically stressed oxide scales. The thermally shocked oxides spalled less than the slow-cooled samples with the exception of TD-NiCrAl. This material failed in a brittle manner rather than by plastic deformation. The HOS-875 and the TD-Ni did not spall during either type of cooling. Thus, the effect of thermal shock on spalling is determined, in large part, by the mechanical properties of the metal. 相似文献
152.
介绍了浮动芯棒、限动芯棒和三辊式限动芯棒连轧管工艺的发展历程。分析了各种型式连轧管机的适用条件;并认为,各种机型装备的发展与市场需求紧密相关,单纯从技术上考虑,而追求同一机型不能带来良好的经济效益 相似文献
153.
Solid lubricants lead to substantial weight savings relative to the use of liquid lubricant, especially in the weight-conscious aerospace industry. A new PTFE-Al alloy composite(A) containing 60% area proportion of PTFE composite was developed. Another type of common metal-plastics multilayer composite, also called DU, was selected for a comparative investigation. Friction and wear tests were carried out in an oscillating sliding tribotester in air at an oscillating frequency of 0.13 Hz and contact mean pressures from 10 to 80 MPa. The composites slid against a 38CrMoAlA steel shaft. The results show that the composite A exhibits low coefficient of dry sliding friction less than 0.1 and long wear life of 2 000 m. This is because the composite A can provide a sufficient solid lubrication during the whole tests. SEM examination of the transfer films for the composite A confirms that uniform, thin and coherent transfer films are prerequisites for low friction and good wear resistance. 相似文献
154.
实用M2052合金阻尼行为表征 总被引:5,自引:0,他引:5
名义组分为Mn-20Cu-5Ni-2Fe(原子分数,%)的M2052合金,具有很高的强度和阻尼性能.对该合金在不同条件下的阻尼性能采用多种方法进行了表征.该合金的高阻尼态出现在一个临界温度以下,该温度可以通过改变组分和热处理来调整.合金的室温阻尼性能强烈地依赖于频率、应变振幅以及静载荷的大小. 相似文献
155.
本文分析了机床拖动的特点,变频调速对电动机及变频器的要求,分析了变频器应用中的干扰问题及采取的抑制措施。 相似文献
156.
V. Devadoss M. Noel K. Jayaraman C. Ahmed Basha 《Journal of Applied Electrochemistry》2003,33(3-4):319-323
The redox behaviour of Mn3+/Mn2+, Co3+/Co2+ and Ce4+/Ce3+ mediators commonly used in indirect oxidation of organic compounds were evaluated in methane sulfonic acid on a glassy carbon working electrode employing cyclic voltammetry. Manganic methanesulfonate exhibits higher instability in dilute methanesulfonic acid. The solid MnO2 formed during disproportionation on the glassy carbon electrode further affects the reproducibility. Cobaltic methanesulfonate formation occurs only at oxygen evolution region rendering the overall oxidation process less efficient. Ceric methane sulfonate formation is highly efficient over a wide acid concentration range. Ceric methanesulfonate can also be employed over a wide temperature range to oxidize different aromatic compounds. 相似文献
157.
Partially stereoregular poly(propylene oxide) samples were synthesized via reactions catalysed by a preformed analytically defined trimethylaluminium hydrolysate. These samples were fractionated into two contrastingly different fractions.
1. (i) D-polymers: This fraction constituted the major part (up to 90%). It mainly contained cyclic low molecular weight oligomers (MW < 1000). The linear chains found in D-polymers had hydroxyl end groups. No double bonds could be detected spectroscopically.
2. (ii) K-polymers: This fraction was high molecular weight stereoregular polymer. Stepwise thermal precipitation from dilute isooctane solution of K-polymers yielded a succession of fractions which differed in melting point. It appears that the phase equilibria during the thermal precipitations were not controlled by the molecular weights of species.
158.
The pitting behaviour of type 321 stainless steel in sulfide-containing chloride aqueous environments was studied using cyclic potentiodynamic polarization. A well-established correlation between H2S and Na2S2O3 in the study of corrosion was applied, that is, H2S was simulated by Na2S2O3. The major factors affecting the pitting corrosion of type 321 stainless steel are the Cl- concentration, solution pH and temperature. The results clearly indicate that both Epit and E
pp decrease with increasing Cl- concentration and temperature, while I
pass is more sensitive to temperature variation. E
pit decreased with decreasing pH in the range 2 < pH < 7.5. The surface morphology and chemistry of the corroded type 321 stainless steel resulting from anodic polarization in 0.01 M S2O
3
2-
-containing Cl- solution were analysed by XRD, SEM and EPMA. A higher concentration of sulfur was found in the pits, and the dark surface film was mainly composed of FeS and -Fe2O3. The results describe the pitting behaviour of type 321 stainless steel in sulfide-containing Cl- aqueous environments. 相似文献
159.
160.
三盐基硫酸铅的生产工艺条件研究 总被引:2,自引:0,他引:2
介绍了氧化铅法中硝酸铅法生产三盐基硫酸铅两种生产工艺 ,对氧化铅法中硫酸的加入量、酸度、温度、时间等生产条件进行了研究 ,确定了最佳生产工艺条件 ,并对两种方法进行了简单对比 相似文献