硫化钠在黑白钨加温精选中的应用研究

介绍了柿竹园黑白钨混合粗精矿加温精选中 ,添加硫化钠与水玻璃混合剂比单一添加水玻璃能更有效地使白钨矿与萤石等含钙矿物及脉石矿物分离。论述了硫化钠在加温精选中的作用效果并探讨了其作用机理     

砂岩油藏注水井深部酸化技术

吐哈油田长期注水开发后,注入水外源性伤害和地层内源性伤害不断在地层深部累积,采用常规酸化措施效果不理想。为此,通过长岩心污染模拟实验,研究了深部污染的污染特征及酸化解堵机理,通过解堵液缓速和工艺过程的综合应用实现深部解堵。应用AcidGuide专家系统对单井进行全面的污染诊断分析,并进行了参数优化设计,形成了适应吐哈油田深部酸化解堵的技术体系,现场应用取得良好效果,为类似低渗透油藏水井增注措施提供参考。     

Hysys软件在分析精丙烯硫化物来源中的应用

气体分馏装置原料液化石油气 (LPG)中有机硫化物形态复杂 ,考察分析工业装置精丙烯硫化物含量变化难度大。利用Hysys模拟 ,分析判断LPG中小分子有机硫化物在气体分馏产品的分布并提出了控制措施。考虑操作条件对精丙烯硫含量的影响 ,并对工业装置精丙烯总硫超标原因进行了分析。     

Procedure for Measuring Low Concentrations of H2 and H2S Above a Water Surface

A simple measuring procedure for low concentrations of H₂ and H₂S (at the level of ppm fractions) above the surface of water by using sensitive gas analyzers is suggested. The procedure is easily accomplished in conditions outside the laboratory (under field conditions).     

Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

Inhibition of sulfide on the simultaneous removal of nitrate and p‐cresol by a denitrifying sludge

BACKGROUND: Many industrial discharges, such as those generated from petrochemical refineries, contain large amounts of sulfurous, nitrogenous and organic contaminants. Denitrification has emerged as a suitable technology for the simultaneous removal of these pollutants in a single reactor unit; however, more evidence is demanded to clarify the limitations of denitrification on the simultaneous removal of sulfide and phenolic contaminants and to optimize the biological process. The aim of this study was to evaluate the capacity of a denitrifying sludge to simultaneously convert sulfide and p‐cresol via denitrification. RESULTS: Sulfide was the preferred electron donor over p‐cresol, imposing a 5 h lag phase (required for complete sulfide removal) on organotrophic denitrification. Addition of sulfide (20 mg S^2? L^?1) to p‐cresol‐amended denitrifying cultures also decreased the reduction rate of nitrate and nitrite, as well as the production rate of nitrogen gas. Nitrite reduction rate was the most affected step by sulfide, decreasing from 35 to 21 mg N (g VSS d)^?1. A synergistic inhibitory effect of nitrate and sulfide was also observed on nitrite reduction. Despite the effects of sulfide on the respiratory rates monitored, complete removal of nitrate, sulfide and p‐cresol could be achieved after 48 h of incubation. CONCLUSION: Our results suggest that simultaneous removal of sulfide and p‐cresol could be achieved in denitrifying reactors, but a large hydraulic residence time may be required to sustain an efficient process due to inhibitory effects of sulfide. Copyright © 2008 Society of Chemical Industry     

Analytical characterization of cadmium cyanamide in CdS thin films and bulk precipitates produced from CBD process in pilot plant

CdS thin films and bulk precipitates were obtained by chemical bath deposition (CBD) in a well-closed reactor. X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, elemental analysis and leaching have been used to characterize solids and thin films. It has been shown that the proportion of cadmium cyanamide in solids may vary from about 50% to 2% according to physicochemical conditions in solution (time after CBD, ammonia concentration) and that CdO results from CdCN₂ after air annealing of thin films. This last step also increases the crystallinity of the films.     

撬装式油井热洗装置研制及应用效果评价

油井热洗是油田最常用的一种清蜡方法。靖安长6油藏是采油三厂的主力油藏,截至2004年底建成油井1064口,由于长6层原油含蜡量高,油井结蜡严重,通常采用常规热洗方法进行油井清蜡。存在以下两方面问题：一是常规油井热洗方法操作比较复杂,运行动力设施多,热洗费用较高；二是常规洗井油源均来自联合站或接转站,为不同层所采的混合原油,进入地层后,会对地层造成一定程度的伤害。为此,我们认真分析了现有油井热洗工艺的不足,查找了油井热洗费用高的影响因素,结合靖安油田长6油藏丰富的伴生气资源,自主研发了撬装式油井热洗装置,经过现场应用取得了较好的效果。     

Shear-induced crystallization of poly(phenylene sulfide)

The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow.     

Motion compensated film restoration

Motion picture films are susceptible to local degradations such as dust spots. Other deteriorations are global such as intensity and spatial jitter. It is obvious that motion needs to be compensated for before the detection/correction of such local and dynamic defects. Therefore, we propose a hierarchical motion estimation method ideally suited for high resolution film sequences. This recursive block-based motion estimator relies on an adaptive search strategy and Radon projections to improve processing speed. The localization of dust particles then becomes straightforward. Thus, it is achieved by simple inter-frame differences between the current image and motion compensated successive and preceding frames. However, the detection of spatial and intensity jitter requires a specific process taking advantage of the high temporal correlation in the image sequence. In this paper, we present our motion compensation-based algorithms for removing dust spots, spatial and intensity jitter in degraded motion pictures. Experimental results are presented showing the usefulness of our motion estimator for film restoration at reasonable computational costs. Received: 9 July 2000 / Accepted: 13 January 2002 Correspondence to:S. Boukir