Comparison of interfaces in Ti composites reinforced with uncoated and TiB2/C-coated SiC fibres

Interfaces play an important role in determining the mechanical properties of composite materials. The interfaces established between a titanium-alloy matrix (Ti-6Al-4V) and uncoated and TiB₂/C-coated SiC fibres are analysed by scanning electron microscopy, transmission electron microscopy and X-ray techniques. Emphasis is placed upon the interfacial morphology and microstructure, identification of reaction products, and the stability of the coating layer. Complex multi-reaction layers are observed frequently in the interfacial zones. Previous, often contradictory, reports about the interlayers are reviewed. Experimental observation demonstrates that the type and distribution of interlayers vary in a given system, due to prolonged treatment of the samples at temperature. The formation and distribution of the interlayers are discussed further, with respect to these and previous findings. Methods of reducing interfacial reactivity are discussed.     

给排水设备的电气控制安装与调试

针对2011年和2012年全国中职院校竞赛项目使用的《建筑设备给排水控制调试装置》设备,对其电气控制部分的安装调试过程进行分解。     

电导法测定乙酸解离常数实验数据处理软件设计

介绍了用电导法测定乙酸解离常数的实验原理和步骤,给出了用计算机对电导法测定乙酸解离常数的实验数据进行处理的软件设计方法,同时给出了用Visual FoxPro 6.0编写电导法测定乙酸解离常数的处理软件的基本结构和部分程序代码。     

压风机恒压供风系统设计

针对某矿压风机往井下输送高压空气时存在输气总管压力波动大且调节困难的问题,设计了一种基于变频调速和闭环负反馈控制的压风机恒压供风系统。该系统通过输气总管上的压力传感器采集实时压力信号,与输入压力信号比较后得到偏差信号,PLC对偏差信号进行分析和处理,并输出相应的变频器调节信号,使变频器改变压风机电动机的电源频率,从而达到调节输气总管压力的目的。实际应用表明,该系统运行稳定、可靠,实现了输气总管高压空气的恒压输送。     

Poly(oxyphosphazenes): A unifying look at structure and morphology

Variations in thermotropic behavior have been investigated for many crystalline polyphosphazenes. Experimental results obtained from DSC, solid-state MAS NMR, dilatometry, mechanical property (creep and dynamic) measurements, birefringence, X-ray (wide and small-angle), and electron diffraction have been made as a function of temperature in an attempt to elucidate the structure-morphology behavior in these polymers. Initially all polyphosphazenes described in this study crystallize from dilute or moderately concentrated solutions in the monoclinic form with relatively low crystallinity (50%). When heated, these specimens expand atT(1) and adopt a chain-extended 2D mesophase morphology in order to relieve congestion. Above this first-orderT(1) temperature a chain-extended –P=N– chain backbone morphology transforms into an isotropic phase at the melting temperatureT _m. When cooled, samples transform into the mesostate. However, crystallization from the mesophase belowT(1) takes place into a 3D orthorhombic state. These two modes of ordering/disordering are in accordance with (i) a hexatic chain packing [betweenT(1) andT _m] with variously mobile side groups that also exhibits smectic features when mesogenic side groups are present and (ii) a 3D orthorhombic structure of high crystallinity belowT(1). The initial monoclinic phase is accessible only via a solution crystallization route. Solid-state MAS NMR, crystallization kinetic measurements, and optical microscopy studies obtained from oriented and unoriented polymers have been especially germane in providing a unifying picture for mesophase formation and ordering in polyoxyphosphazenes. X-ray and electron diffraction evidence is complicated by critical overlapping peaks that are found under these same conditions. They demonstrate that (a) positional disorder exists along the chain direction and (b) the side chain above, as well as below, theT(1) transition is governed by the mobility, size, and type of side group in circumstances where phase transformations occur.     

A refined evaluation of the gas-phase water-dimerization equilibrium constant within non-rigid BJH- and MCY-type potentials

The flexible BJH- and flexible or semiflexible MCY-type water-water potentials (4 potential modifications in each nonrigid family, i.e., altogether 12 potentials) are used for evaluation of the gas-phase water-dimerization equilibrium constants. The potential-energy term is adjusted for best reproduction of the available experimental equilibrium constants. An independent test using the experimental steam second-virial coefficient isotopic difference shows that the adjustment also improves the computational evaluation of the difference. A set of dimerization equilibrium constants is suggested over a wide temperature interval (based on the BJH/G, MCY-B, or MCYB potential modifications). The best reproduction of the experimental equilibrium constants (in conjunction with good performance for the second-virial isotopic difference) is produced by the BJH/G potential. The results are applicable to various problems such as the formation of water clusters in large-scale natural and artificial water jets (e.g., hydrogen-oxygen rocket motors, orbital capsule water dumps, water ejection from a comet nucleus) or in atmospheric chemistry.     

一种新的修正恒模算法

阐述了恒模算法(CMA)、修正恒模算法(MCMA)和判决引导(DD)算法的基本原理。针对CMA和MCMA收敛速度慢,固定步长条件下收敛速度和剩余误差之间存在矛盾的缺陷,在分析CMA误差特性的基础上,利用DD算法误差函数的模值和判决器输出构造新的误差函数,提出了一种新的变步长MCMA。新算法在加快收敛速度的同时保持小的剩余误差。仿真结果表明,新算法比CMA和MCMA收敛速度快,均衡输出剩余码间干扰(ISI)小而且能克服相位偏移,具有很好的实用性。     

低碳钢显微结构的EBSD表征

近年来,新开发的电子背散射衍射技术将多晶材料的显微组织、微区成分与结晶学数据分析联系起来,能对晶界类型、取向、位向差和结构及其分布进行观察、统计测定和定量分析,从而建立了晶界结构、取向和织构等与多晶材料性能的定量和半定量关系,成为现代材料研究的重要实验技术。笔者结合低碳钢生产中的一些实际问题,扼要介绍了电子背散射衍射技术中的晶体取向图在多晶材料显微结构表征中的应用。     

Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge

For a quantitative evaluation of the protectiveness of a rust layer formed on a weathering steel bridge, the relationship between the corrosion rate of the bridge and the composition of the rust layers formed on the girders was first investigated. These corrosion rates were clearly classified by the protective ability index (PAI) of α/γ^∗ and (β + s)/γ^∗, where α, γ^∗, β and s are the mass ratio of crystalline α-FeOOH, the total of γ-FeOOH, β-FeOOH and the spinel-type iron oxide (mainly Fe₃O₄), β-FeOOH and spinel-type iron oxide, analyzed by XRD, respectively. The inequality of the former index α/γ^∗ > 1 expressed the protectiveness criterion of the rust layer, while that of the latter index, (β + s)/γ^∗< 0.5 or > 0.5, classified the corrosion rate of the non-protective rust layer. The PAI is useful for a quantitative evaluation of the protectiveness of a rust layer formed on a weathering steel bridge and is an important item for the corrosion assessment of the bridge.     

Structure, hyperfine interactions and magnetization studies of mechanically alloyed Fe50Ge50 and Fe62Ge38

X-ray diffraction, Mössbauer spectroscopy and magnetization measurements were used to study the structure and some magnetic properties of Fe₅₀Ge₅₀ and Fe₆₂Ge₃₈ prepared by mechanical alloying from the elemental powders. In both cases in the early stages of milling the intermediate paramagnetic FeGe₂ phase was formed. The mechanical alloying process of Fe₅₀Ge₅₀ resulted in the formation of the paramagnetic FeGe (B20) phase with an average crystallite size of about 15 nm. In the case of the Fe₆₂Ge₃₈, the ferromagnetic Fe₅Ge₃ (β) phase with a Curie temperature of about 430 K was obtained. The average crystallite size was about 9 nm. The average hyperfine magnetic field of about 16 T allowed it to determine that more than four germanium atoms exist in the nearest environment of the ⁵⁷Fe isotopes in the Fe₅Ge₃ phase.