注射成形Fe-50%Ni软磁合金的研究

Fe-50 %Ni合金是一种典型的高磁导率和低矫顽力的软磁材料,有着广阔的应用前景.本次实验采用注射成形方法制取Fe-50 %Ni,研究了在注射成形工艺中烧结工艺对最终产品性能及微观组织的影响,并分析了影响产品磁性能的一些主要因素.实验表明,烧结温度的提高和烧结时间的延长能够较好改善产品的力学性能;密度是影响产品磁性能的主要因素,杂质(主要指(C、O、N)的含量和晶粒尺寸对剩磁、磁导率和矫顽力也有较大的影响;通过注射成形方法制取的Fe-50 %Ni,其性能要优于采用传统粉末冶金方法制造的Fe-50 %Ni.     

Co- and Ni-exchanged ferrierite: The contribution of synchrotron X-ray diffraction data to siting of TMIs

High-silica zeolites exchanged with transition metal ions (TMIs) are the subject of great interest for their unusual catalytic activity and selectivity. Structural information like coordination and accessibility of TMIs in zeolites are important factors for understanding their catalytic activity. Siting of TMIs in zeolites is typically obtained by spectroscopic (EXAFS, EPR, UV–vis and IR) and computational methods, as in the case of Co-ferrierite. However, some controversy exists in the literature concerning the model for incorporation of bare Co ions in ferrierite. We show here that the results of our synchrotron X-ray powder diffraction studies on Co- and Ni-exchanged ferrierite (Si/Al = 8.5) are in a good agreement with the model of Co siting based on an indirect spectroscopic approach and help to validate this model. By direct structural evidences, a possible explanation for the larger catalytic activity of Co sites in the main channels of ferrierite can be inferred. A combination of data from in situ XRD continuous monitoring of the Co ion migration during calcination and crystal-chemical considerations allows to device a strategy for the design of optimised co-cations containing Co-ferrierite catalysts.     

PTT直接酯化反应动力学研究

研究了不同温度下PTT(聚对苯二甲酸丙二醇酯)直接酯化反应动力学。建立了零级和一级反应动力学模型。用实验数据进行的检验表明,一级动力学模型更为接近该反应过程。     

Formation and electronic structure of interface

In the present work the formation of the interface between polycrystalline silver and thin films of titanium oxide was studied with photoelectron spectroscopy (XPS, UPS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Titanium oxide was deposited stepwise on 100 nm thick silver films by reactive magnetron sputtering allowing to study the evolution of the interface formation process. The process involves two steps: formation of thin layer of silver oxide and subsequent growth of the TiO₂ film. For better understanding of the silver oxidation process, pure silver films were exposed to a low temperature Ar/O plasma for different time intervals providing a possibility to investigate early stages of the oxide film growth.     

微量元素对管道焊缝性能的改善

在焊条中添加微量元素Ce、Y、Ca、Ba和Zr，有利于改善石油天然气管道焊缝的金属性能，俄罗斯专家对此做了一系列实验和研究。结果表明添加微量元素有利于提高焊缝金属平面应变断裂韧性KIC，提高裂纹张开位移δc，减小裂纹扩展速率dα／dN改善焊缝金属的组织结构。通过大量的试验和研究，俄罗斯焊接学者确定了焊缝中微量元素的最佳含量，并建立了相关参数的数学模型。     

In‐Situ Observation of the Formation of MnS during Solidification of High Sulphur Steels

A Confocal Scanning Laser Microscope equipped with a gold image furnace was used to directly observe the precipitation of MnS during solidification of high sulphur steels under isothermal conditions in the temperature region 1440 to 1480°C on the free surface of the steel melt. For the case of Al‐killed steels, below 1480°C MnS particles were found to precipitate with Fe forming simultaneously around them. This MnS containing structure continued to grow rapidly (264 μm/s) as a surface film. The film gradually changed, as the level of S in the melt decreased, into a eutectic structure (with lamella spacing of 2 μm) as predicted by thermodynamics. In Si‐ killed steels there was significantly lower tendency to form MnS both in terms of time until precipitation occurred and growth rate.     

直流法测量钯氢化物电极电阻时的阻值偏移

讨论了直流法在线测量钯氢化物电极电阻时的电化学效应，计算了电解液的共导、测量电流与电解电流引起的浓差电池效应以及电极作为集流体引起的电阻贡献。结果表明：当电极具有高的长度与半径比值、粗糙的表面、高的溶液电导以及大的电解电流时容易引起显著的附加电阻。     

磷矿中七种金属元素的光谱法测定

研究了磷矿样品中7种金属元素锰、钴、镍，锌、铬、钼及铋的分析方法，选择了灵敏度高干扰少的谱线，绘制出工作曲线，对样品进行了科学处理，不必进行化学分离即可对七种元素同时测定，经合成样分析、回收实验及样品测定，证明此方法精确可靠，其回收率在98％-102％之间。     

钛精矿回转窑直接还原过程结圈可能性的探讨

通过煤种，入窑球冷态强度和还原过程强度，以及钛精矿与煤灰混合物的软化温度等分析探讨了钛精矿预热球团回转窑直接还原产生结圈的可能性，获得了可以避免结圈的结论。     

A direct stiffness analysis of a composite beam with partial interaction

The use of the conventional semi-analytical stiffness method in finite element analysis, in which interpolation polynomials are used to develop the stiffness relationships, leads to problems of curvature locking when beam-type elements are developed for composite members with partial interaction between the materials of which it is comprised. The curvature locking phenomenon that occurs for composite steel–concrete members is quite well reported, and the general approach to minimizing the undesirable ramifications of curvature locking has been to use higher-order polynomials with increasing numbers of internal nodes. This paper presents an alternate formulation based on a direct stiffness approach rather than starting from pre-defined interpolation polynomials, and which does not possess the undesirable locking characteristics. The formulation is based on a more general approach for a bi-material composite flexural member, whose constituent materials are joined by elastic shear connection so as to provide partial interaction. The stiffness relationships are derived, and these are applied to a simply supported and a continuous steel–concrete composite beam to demonstrate the efficacy of the method, and in particular its ability to model accurately both very flexible and very stiff shear connection that causes difficulties when implemented in competitive semi-analytical algorithms. Copyright © 2004 John Wiley & Sons, Ltd.