B位掺杂钙钛矿结构化合物LaSr2Mn2-xFexO7的电磁性能

研究了以Fe离子(Fe3 )掺杂取代部分锰(Mn)离子的层状钙钛矿结构化合物LaSr2Mn2-xFexO7(O≤x≤O.3)的电性和磁性.结果发现:Fe3 的掺杂抑制了LaSr2Mn2-xFexO7低温的反铁磁性交换作用,使Neel温度TN由x=0的138K降至x=0.3的l0lK.同时,LaSr2Mn2-xFex07的自旋玻璃态、电荷有序和金属一绝缘体转变温度都由于Fe3 取代Mn离子而受到抑制.产生上述现象的原因是因为Mn位被取代导致产生无序状态.由于Fe3 取代Mn粒子,致使双交换作用通道被打破,化合物的电阻率随x的增加而迅速增加.所有化合物的电阻率在低温阶段都可以用Mott的变程跳跃理论来拟合;在高温阶段可以用最近小声子极化理论来拟合.     

Suppression of the α → β-nickel hydroxide transformation in concentrated alkali: Role of dissolved cations

The presence of dissolved cations such as Al and Zn in alkaline electrolyte (6 M KOH) suppresses the -nickel hydroxide transformation. The uptake of Al (10 mol%) and Zn (30 mol%) exhibited by the active material likely stabilizes the -phase. Dissolved Al is deleterious to the performance of the nickel hydroxide electrode, whereas, dissolved Zn enhances the specific discharge capacity of nickel hydroxide by approximately 25% showing that the mode of metal uptake is different in the two cases.     

A novel shaft-less double suction mini pump

A novel double suction shaft-less mini pump was developed for heat control of small energy systems in this study.The mini pump impeller with an exit diameter of 40 mm was combined with the motor rotor supported by the hybrid dynamic bearing.The specific speed of the pump was 125 min-1 m3 min-1 m.The hydraulic performance of the pump was investigated experimen-tally under four rotational speeds.From the test results,it was recognized that the pump could provide a flow discharge of 5 L/min and head of 1.5 m,w...     

一种新的第三方双重图像水印算法

提出一种新的第三方双重图像水印算法。该算法依赖于可信任第三方提供的时间戳以及用户的私钥和授权码生成双重水印信息,然后将其嵌入在图像分块除直流分量外的DCT系数上。水印检测时可分别对水印作品时间戳和隶属关系的合法性进行检测。仿真实例和安全分析表明,该算法对嵌入参数敏感,对图像的常规操作具有较好的鲁棒性。在没有第三方的参与下,任何用户都不能构造和检测出合法的水印信息,这限制了恶意盗版者进行分析和攻击的一些前提条件,保证了水印系统的安全。     

基于红外原理的微型多气体检测系统的设计

为了解决目前煤矿瓦斯事故以及大量使用天然气的家庭安全、环境污染等问题,设计并开发了一种具有集成化、微型化的红外多气体检测系统,通过实验数据的测试对比和数据分析,这种系统达到了微功耗、微体积、宽量程、高分辨率等技术要求,且能集成多气体检测的微型检测系统.重点介绍了红外检测的光学原理,以及从单气体检测引入到集成多气体检测的设计思想和方法,并介绍了有关CAN总线的数据传输方式和无线数据通信方式在系统中的应用.     

Mechanical performance and texture characteristic of an IF steel containing Nb and Ti by double cold rolling

Single cold rolling and double cold rolling were applied to hot rolled strips with different reduction ratios. The evolutions of {100},{111} and Goss face texture during double rolling were investigated by comparing the orientation distribution function(ODF) of the double rolled sample with that of the single rolled one. The double cold rolling texture is characterized by a higher γ-texture and a lower α-texture,and the {111}<112> component is improved remarkably. Based on the TEM observation and mechanical...     

Preparation and electrochemical characterization of activated carbons by chemical-physical activation

A process was proposed based on the combination of chemical and physical activation for the production of activated carbons used as the electrode material for electric double layer capacitor (EDLC). By material characterization and electrochemical methods, the influences of the activitation process on the specific surface area, pore structure and electrochemical properties of the activated carbons were investigated. The results show that specific surface area, the mesopore volume, and the specific capacitance increase with the increase of the mass ratio of KOH to char (m(KOH)/m(char)) and the activation time, respectively. When m(KOH)/m(char) is 4.0, the specific surface area and the mesopore volume reach the maximum values, i.e. 1 960 m²/g and 0.308 4 cm³/g, and the specific capacitance is 120.7 F/g synchronously. Compared with the chemical activation, the activated carbons prepared by chemical-physical activation show a larger mesopore volume, a higher ratio of mesopore and a larger specific capacitance. Foundation item: Project(2007BAE12B01) supported by the National Key Technology Research and Development Program of China     

Influence of nitrogen hetero-substitution on the electrochemical performance of coal-based activated carbons measured in non-aqueous electrolyte

Nitrogen-containing carbons were prepared by modification of activated carbons. The modified carbons were used as electrode materials with improved electrochemical performance. Precursor anthracite was activated by KOH (KOH: anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons. The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively. Electrochemical experiments were performed in an organic electrolytic solution of 1 M (C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement. The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons: this ensured a sufficient utilization of the exposed surface for charge storage.     

基于CSY型传感器的悬臂力学试验确定材料弹性模量的方法

对在CSY型传感器综合实验仪上拓展悬臂梁力学实验进行了研究,研究了在该实验仪上实现材料弹性模量的测定.通过材料力学的理论推导出悬臂梁弹性模量与其受力和挠度比值的关系,通过应变式传感器的实验确定出悬臂梁受力与其挠度的比值关系,进一步可推导出悬臂梁材料的弹性模量,并验证了该方法的可行性及有效性.该方法集合了电阻应变效应、全桥差动电路等传感器电测技术以及材料弹性力学、悬臂梁结构力学的基础知识,具有综合应用性.同时,对高校实验室如何有效利用设备资源、开发拓展型实验有一定的示范作用.     

Experimental Study on the Expansion Uniformity of Armature

A measurement system has been developed based on high-precision printed probes in printed circuit board (PCB) and steep rising-time probe adapters,which can be applied to study the expansion uniformity of armature in a helical magnetic flux compression generator (HFCG).The influences of wall thickness and initiation position on the expansion uniformity of armature in HFCG were experimentally investigated.The results show that the armature with thinner wall thickness will easily rupture due to the high pressure of detonation products inside,the armature with larger wall thickness will easily crack due to the tensile stress on the outer surface of the wall,the influence of the end effect on the expansion uniformity can be ignored if the distance between the first group of probe and the initiation point is more than 3 times the armature diameter.