An integrated biodesulfurization process,including inoculum preparation,desulfurization and sulfate removal in a single step,for removing sulfur from oils

BACKGROUND: A single‐stage reactor, in which the growth of bacterial culture, induction of desulfurizing enzymes, and desulfurization reaction are carried out in a single step, was adopted to investigate desulfurization of dibenzothiophene (DBT) at high cell densities. Rhodococcus erythropolis, IGTS8 was used as the biocatalyst. Optimal conditions for bacterial growth and DBT desulfurization were investigated. RESULTS: Optimization of fermentation conditions was necessary to obtain high cell densities including controlling accumulation of acetate. Under optimal operating conditions, the maximum optical density at 600 nm (OD₆₀₀) was measured to be 26.6 at 118 h of cultivation. When biodesulfurization of DBT in model oil with a high cell density culture of IGTS8 was investigated, accumulation of sulfate was found to limit the extent of desulfurization. A sulfate removal step was added to obtain a single‐stage integrated biodesulfurization process. Sulfate removal was achieved via an aqueous bleed stream and use of a separation unit to recycle the organic phase. CONCLUSION: A proof of principle of a complete system capable of biocatalyst growth, induction, desulfurization and by‐product separation was demonstrated. This system enables simplification of the biodesulfurization process and has potential to lower the operating cost of the bioprocess. Copyright © 2008 Society of Chemical Industry     

Design and Characterization of the CLIMPAQ,Chamber for Laboratory Investigations of Materials,Pollution and Air Quality*

A test chamber has been developed in order to provide a small and simple emission testing facility capable of testing construction products in a climate where the important climatic parameters such as temperature, ventilation rate and air velocity can be varied independently around typical indoor values. The test chamber CLIMPAQ is made of panes of window glass. Other main surface materials are stainless steel and eloxated aluminium. The chamber has a volume of 50.9 litres and is designed to meet the requirements for quantifying air pollution. In this investigation human subjects acted as air pollution judges, and chemical characterization of the air pollution was carried out. Carpet, linoleum, wall paint and seal- ant were tested simultaneously in the CLIMPAQ and in four other chambers ranging from a full-scale chamber of 28 m³ to a field and laboratory emission cell of 3.5· 10^?5m³. Product ranking is the same in all chambers for the sensory measurements. Emission rates based on sensory measurements differ for all products less than 100 % except for tests in a 3-litre chamber where emission rates were higher. Chemical measurements differ up to approximately 10 times for the same product in different chambers. Deviations appear to be the result of different environmental parameters in the various chambers. Low air concentrations or high specific ventilation rates seem to increase emissions, while differences in air velocities and sink properties may also be the cause of differences in emission rates.     

Personal Exposure in Displacement Ventilated Rooms

Personal exposure in a displacement ventilated room is examined. The stratified flow and the considerable concentration gradients necessitate an improvement of the widely used fully mixing compartmental approach. The exposure of a seated and a standing person in proportion to the stratification height is examined by means of full-scale measurements. A breathing thermal manikin is used to simulate a person. It is found that the flow in the boundary layer around a person is able to a great extent to entrain and transport air from below the breathing zone. In the case of non-passive, heated contaminant sources, this entrainment improves the indoor air quality. Measurements of exposure due to a passive contaminant source show a significant dependence on the flow field as well as on the contaminant source location. Poor system performance is found in the case of a passive contaminant released in the lower part of the room close to the occupant. A personal exposure model for displacement ventilated rooms is proposed. The model takes the influence of gradients and the human thermal boundary layer into account. Two new quantities describing the interaction between a person and the ventilation are defined.     

济钢第一炼钢厂降低钢铁料消耗实践

济钢第一炼钢厂通过优化入炉原料结构,改进冶炼工艺,实施少渣炼钢,有效减少了转炉吹损,降低了钢铁料消耗成本,2002年增加炼钢综合经济效益3100多万元。     

上向分层尾砂充填法在仓上金矿的新应用

本文介绍了垂直矿体走向布置的上向分层尾砂充填采矿法新方案的特点及其在仓上金矿中厚矿体的具体应用。     

Vibrational Mode in Two-Dimensional Dust Monolayer with Finite Size Dust Grains

Vibrational mode in a two-dimensional dust monolayer is investigated by considering the finite size of dust grains. Each dust grain is assumed to be a negative point charge and a dipole moment due to the inhomogeneous charge distribution on its surface. The dispersion relation of the vibrational mode is derived. Both the self-excited and externally excited cases are discussed. It is shown that the mode is sensitive to the direction of the dipole moment.     

堆底熔穿事故的场外后果及其对策

在压水堆核电站应急计划和应急响应中，堆底熔穿事故占有重要位置。本文用法国核电厂事故源项Ｓ３（对应于堆底熔穿事故）计算了在典型气象条件下的场外放射学的后果，根据一般防护决策原则和我国颁布的干预水平，提出了保护公众的应急防护措施的建议。     

锻钢退火炉消烟除尘技术改造

介绍了锡钢集团公司锻压分厂车底式热处理退火炉消烟除尘综合治理改造情况。包括烧嘴重新选型、配置，增设空气预热器及重油加热系统，并将下排烟改为地上排烟。改造的主要目的是消烟除尘，提高产品退火质量，提高炉子装备水平及节省燃油消耗。改造后运行结果基本达到了预定目标。     

《Flash动画制作》课程教学方法探讨与实践

根据《Flash动画制作》课程在教学实践中的特点,提出构建"理实同步,实例引导,任务驱动"的教学模式,在教学内容、教学方法等方面进行教学改革,并阐述了在Flash教学中的具体实施方法,提高了学生动手能力及综合素质。     

Prediction of venturi scrubber efficiency used in an updraft gasifier cleaning train

The performance of a venturi scrubber in the removal of tar from gas in updraft gasification has been studied. The gasifier has been operated with a husk feed rate of 1.6 × 10^?4 kg/s. The venturi scrubber has been operated at a superficial gas velocity of 56.4 m/s at the throat. A wide variety of scrubbing liquids having surface tensions ranging from 0.026 to 0.072 N/m have been used. The Q_g/Q_l, has been varied in the range of 1000–8000. The tar separation efficiency η has been found to vary from 51 to 98.5%. A mathematical model, assuming steady-state operation, has been developed considering very high pseudosolubility of tar in the scrubbing liquids. The predicted values of η have been compared with experimental results. The model satisfactorily explains the tar removal efficiency of the venturi for Q_g/Q_l values ranging from 4000 to 8000 for all scrubbing liquids. The following correlation has been developed for predicting venturi scrubber efficiency: .