Heterostructured dysprosium vanadate – ZnO for photo-electrocatalytic and self-cleaning applications

In this article, we report fabrication of 5 wt% of Dy as DyVO₄ supported ZnO by template-free hydrothermal-thermal decomposition method and its photocatalytic activity towards degradation of azo dyes Rhodamine-B (Rh-B) and Trypan Blue (TB) in solar light, Electrocatalytic activity in methanol oxidation and Self-cleaning properties. The as prepared DyVO₄-ZnO was characterized by surface analytical and spectroscopic techniques. The results suggested that Dysprosium vanadate doping on ZnO has increased its photocatalytic efficiency with high reusability. DyVO₄-ZnO exhibits higher electrocatalytic activity than prepared ZnO for methanol electrooxidation in alkaline medium, revealing its promising potential as the anode in direct methanol fuel cells. Hydrophobicity of ZnO increases by doping of DyVO_4.     

Engineering an Earth‐Abundant Element‐Based Bifunctional Electrocatalyst for Highly Efficient and Durable Overall Water Splitting

The simultaneous and efficient evolution of hydrogen and oxygen with earth‐abundant, highly active, and robust bifunctional electrocatalysts is a significant concern in water splitting. Herein, non‐noble metal‐based Ni–Co–S bifunctional catalysts with tunable stoichiometry and morphology are realized. The engineering of electronic structure and subsequent morphological design synergistically contributes to significantly elevated electrocatalytic performance. Stable overpotentials (η₁₀) of 243 mV (vs reversible hydrogen electrode) for oxygen evolution reaction (OER) and 80 mV for hydrogen evolution reaction (HER), as well as Tafel slopes of 54.9 mV dec^?1 for OER and 58.5 mV dec^?1 for HER, are demonstrated. In addition, density functional theory calculations are performed to determine the optimal electronic structure via the electron density differences to verify the enhanced OER activity is related to the Co top site on the (110) surface. Moreover, the tandem bifunctional NiCo₂S₄ exhibit a required voltage of 1.58 V (J = 10 mA cm^?2) for simultaneous OER and HER, and no obvious performance decay is observed after 72 h. When integrated with a GaAs solar cell, the resulting photoassisted water splitting electrolyzer shows a certified solar‐to‐hydrogen efficiency of up to 18.01%, further demonstrating the feasibility of engineering protocols and the promising potential of bifunctional NiCo₂S₄ for large‐scale overall water splitting.     

Ce对Sn-Ag-Cu系焊料合金的组织与性能影响

通过添加稀土Ce研究了Sn-3.0Ag-2.8Cu系焊料合金的显微组织和性能。用光学显微镜、SEM、EDX对其显微组织进行分析,并且对其导电性,润湿性,硬度等重要性能进行测试。结果表明,添加稀土w(Ce)为1%焊料合金的导电性明显提高;而润湿角明显减小,润湿性增强;同时焊料合金的硬度也有所增加。     

稀土掺杂对99氧化铍陶瓷性能的影响

对99BeO分别掺入16种稀土氧化物,系统地研究不同稀土氧化物掺杂对99BeO陶瓷热导率和密度的影响,研究发现：掺入0．1％和0．5％的Tb4O7能够提升BeO陶瓷的热导率,分别达到288w／（m·K）和295W／（m·K）。掺入CeO2,Nd2O3能够提升99BeO陶瓷的密度,在1630℃时烧结时达到2．939和2．927g／cm^3。     

考虑分级开挖的深基坑支护计算

 提出了考虑深基坑变形的一种新的支护结构计算方法——弯杆计算法，在弯杆法的有限元计算中， 通过变换座标的方式考虑上一级开挖的变形，从而达到考虑分级开挖的工况。实例验算表明，该程序能够计算出支护结构变形的变化趋势，并给出了简要的自编计算程序框图。     

阿哈水库粘土斜墙土坝渗压计的安装埋设

根据大坝安全监测和运行管理的需要，对阿哈水库粘土斜墙上坝补设了10个渗压观测点，渗压观测选用差动电阻式渗压计，渗压计埋设采用钻孔埋设法。此工程已于1996年12月实施完毕，并获得成功。     

半导体激光阵列“Smile”效应下快轴准直镜的装调

针对3种典型"Smile"形态的半导体激光阵列(LDA)如何装调快轴准直镜的问题,开展"Smile"条件下快轴准直实验定量研究。利用光纤近场扫描法和最小二乘法获得LDA的"Smile"值,采用Zemax非序列模式,模拟"Smile"下LDA的快轴准直。结果表明,LDA的"Smile"大小及形态分布影响准直镜装调位置,透镜光轴需要与LDA匹配,否则会造成光束质量的劣化。这为实际掌握LDA的快轴准直安装提供一种思路,为进一步集成高功率高光束质量的大功率半导体激光器提供了理论和实验基础。     

Yb3+/Er3+共掺ZnF2粉末上转换发光特性研究

为了研究ZnF₂作为基质材料、稀土离子Yb3+和Er3+共掺摩尔分数不同时的发光性能,采用高温固相法,在820℃时制备稀土掺杂ZnF₂样品,并对各个样品进行上转换发射光谱测试。将激发功率与上转换发射功率进行曲线拟合,确定Yb3+和Er3+光子吸收过程。结果表明,在980nm半导体激光器激发下,样品在可见光区域内存在533nm,555nm和655nm 3个上转换发射峰,发射的红光强度大于绿光强度,吸收光子数目依次为1.73,1.75,1.88,确定3个发射峰均对应于双光子吸收。此研究说明稀土离子掺杂ZnF₂材料将在上转换红色荧光粉领域有重要的应用前景。     

锡铅稀土钎料合金高温蠕变性能试验研究

文中对比分析了Ｓｎ６０Ｐｂ４０和Ｓｎ－Ｐｂ－０．０５Ｒｅ两种钎料合金在多轴应力状态下的蠕变断裂规律,初步探讨了主控两种钎料复合金为断裂的力学因素,并从金属学角度初步探讨了两种钎料合金的蠕变断裂方式,着重分析了混合稀土对锡铅秆料合金蠕变性能的影响。