铝阳极氧化膜在NaCl溶液中的电化学性能

采用交流阻抗法研究了工业纯铝L3阳极氧化膜在中性NaCl溶液中交流阻抗谱的变化规律, 比较了未封闭处理与沸水封闭处理后氧化膜的交流阻抗谱的差异, 并结合等效电路分析了氧化膜多孔层与阻挡层电化学参数的变化.结果表明, 未封闭的阳极氧化膜在NaCl溶液中浸泡初期存在一个自封闭过程, 封闭处理明显提高氧化膜多孔层的初始Rp值并降低初始CPEp值; 溶液中侵蚀性离子浓度越高, 封闭处理提高铝阳极氧化膜的耐蚀性能作用越明显.     

脉冲电化学光整加工的流场及间隙特性

通过系统的试验研究，分析了工作液流场分布、流量、加工间隙等工艺参数对加工质量的影响。研究结果表明：合理控制加工间隙和工作液流场分布，对保证加工表面的质量极为重要；在优选的工艺参数下，可快速获得优质表面。     

镁合金的活性电弧焊接

在不同的电流条件下,研究了9种常见氧化物、氟化物、氯化物活性剂在镁合金交流氩弧焊及变极性等离子焊弧中的行为.结果表明:活性剂TiO2、Cr2O3、AlF3、NiCl2、CdCl2、ZnCl2、MgCl2使镁合金交流氩弧焊焊缝熔深增加;MgF2、SiO2使镁合金交流氩弧焊焊缝熔深减小;TiO2、SiO2、Cr2O3、AlF3、NiCl2、CdCl2使镁合金变极性等离子弧焊焊缝熔深增加;MgF2、ZnCl2、MgCl2使镁合金变极性等离子弧焊焊缝熔深减小;活性剂对镁合金交流氩弧焊焊缝熔深增加的作用大于对镁合金变极性等离子弧焊的;电弧收缩是活性剂使得镁合金电弧焊焊缝熔深增加的原因之一;活性剂的加入使得焊缝的晶粒比未涂敷活性剂时粗大.     

Preparation and electrocatalytic properties of tungsten carbide electrocatalysts

1　ＩＮＴＲＯＤＵＣＴＩＯＮ ｉｎ 1 5 0℃ .Ｍａａｓ[1 0 ] ａｌｓｏｍａｎｕｆａｃｔｕｒｅｄｔｈｅＨ2 Ｏ2 ｆｕｅｌｃｅｌｌｓｔａｃｋｓｗｉｔｈｔｈｅｏｕｔｐｕｔｐｏｗｅｒｕｐｔｏ 1ｋＷ ,ａｎｄｔｈｅｐｒｏｐｅｒｔｉｅｓｏｆｔｈｅａｓ ｐｒｅｐａｒｅｄｆｕｅｌ     

铸态Mm(NiCoMnAl)5.1Bx贮氢合金电化学性能研究

本文研究了B含量对铸态非化学计量比贮氢使合金Mm(NiCoMnAl)5.1Bx的相结构及其电化学性能的影响。结果表明，加B合金中除了CaCu5相以外还含有一定量的第二相MmCo4B，且随着B元素含量的增加而增加；B的加入有利于提高合金的活化性能和高倍率放电性能，合金的循环寿命亦有所提高，但不利于合金的放电容量和放电电压性能。     

碳钢在流动3%氯化钠溶液中的腐蚀机理的探讨

本文利用自行设计的模拟流动状态的装置,研究了碳钢在流动3%NaCl溶液中的腐蚀规律及施加阴极电流后对腐蚀的影响。结果表明:随着相对流速的增大,碳钢的腐蚀随之加剧,并发现存在一个临界相对流速值。当相对流速小于此值时,腐蚀主要受电化学因素影响。而相对流速大于此值时,流体力学因素开始明显起主导作用,并与电化学因素间的协同效应增强,导致腐蚀速度急剧上升。施加阴极电流后,不仅抑制了电化学因素引起的腐蚀,而且大幅度地削弱了电化学因素与流体力学因素间的协同效应,从而使腐蚀速度大大降低。     

Electrodeposition of dixanthogen（TETD） on pyrite surface

The electrochemical reaction of xanthate on the surface of pyrite was studied using cyclic voltammogrametry, chronopotentiometry and rotating-disc electrode measurements.Experimental results demonstrate that the first step in the reaction is electrochemical adsorption of xanthate ion,and then the adsorbed ion associates with a xanthate ion from the solution and forms a dixanthogen on the pyrite electrode surface.The diffusion coefficient of butyl xanthate on pyrite electrode surface can be determined to be about 1.09×10- 6cm2/s.Using the galvanostatic technique,the kinetic parameters of oxidation of the butyl xanthate ion on the pyrite surface are calculated as Ja=200μA/cm2 ,β=0.203 and J0=27.1μA/cm2.     

热处理对La0．7Mg0．3Ni2．8Co0．5贮氢合金电化学性能的影响

La0．7Mg0．3Ni2．8Co0．5贮氢电极合金经过适当热处理后(1123K)，最大放电容量、循环稳定性、高倍率放电性能(HRD)、交换电流密度(I0)以及极限电流密度(IL)都有明显改善，铸态合金电极的最大放电容量为392mAh／g，放电电流密度，Id=2000mA／g时，HRD2000=74．0％，I0=266．7mA／g，IL=3425．5mA／g；经1123K保温8h退火的合金电极的最大放电容量提高到414mAh／g，HRD2000=76．2％，I0=407．9mA／g，IL=3753．6mA／g。X射线衍射(XRD)分析表明，衍射峰宽度随着退火温度的升高而变窄，其原因是合金经退火处理相结构的变化和成分的均匀化。     

On the electrochemical nature of hot-corrosion attack in Ni-Cr alloys

Hot-corrosion attack on gas-turbine components has been a problem of practical importance for over two decades. The nature and the extent of corrosion are influenced by the type of contaminants, the alloy constituents, and temperature. The hot-corrosion process is quite complex. There is controversy regarding the role of alloying elements, and whether the process is chemical or electrochemical in nature. In this investigation, an attempt has been made to investigate the role of Al and Ti in influencing the hot-corrosion attack of Ni-20 wt. % Cr alloys in molten Na₂SO₄-NaCl mixtures. It was found that Ni-Cr-Al alloys undergo a localized, heavy-blister attack under certain experimental conditions which is electrochemical in nature. An electrochemical model has been proposed which can satisfatorily explain the nature and kinetics of the localized blister corrosion.     

Effects of pH value of reaction solution on structure and electrochemical performance of calcium-containing active material of secondary zinc electrodes

The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD).Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH: 11. 15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime.