Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

水文自动测报系统防雷的探讨

水文自动测报系统若配备有线／无线（GSM，GPRS）双通道，可提高系统的可靠性，保证系统的畅通。然而，有线组网方式最致命弱点是防雷能力差，针对防雷问题，在实践中探讨其有效途径，论述接地装置的设计、安装中应注意的几个问题，并介绍在实践中电话线防雷从一级防护发展到三级防护，提高防雷的效果，有待在实践中，再认识，再提高。     

高性能IGBT模块的设计考虑

本文对ＩＧＢＴ模块中功率芯片（ＩＧＢＴ和续流二极管）的优化设计进行了讨论。通过优化几个重要的工艺参数并改进器件的结构，ＩＧＢＴ不仅有足够的短路容量，而且正向压降与电流下降时间之间可实现最佳折衷。另外，续流二极管的反向恢复特性也有明显改善。通过采用衬底控制技术，ＩＧＢＴ模块的输出特性不受温度的影响，输出电流更稳，输出阻抗更高。本文详细介绍了整个设计考虑。     

Application of SiC-Si functionally gradient material to thermoelectric energy conversion device

Because of its high–temperature chemical stability, SiC ceramic is a promising material for high-temperature device applications such as thermoelectric energy converters. However, the electrical conductivity of SiC ceramic is too low for it to be used as a thermoelectric energy converter at the cold junction. Therefore, we propose a SiC-Si functionally gradient material (FGM) in order to improve the electrical conductivity of the SiC ceramic at the cold junction. An SiC rod was fired in a temperature gradient furnace. One end of the SiC rod was maintained at 2473 K and the other end was maintained at 1973 K for 30 min. After firing, the porous SiC edge fired at 1973 K was dipped into molten Si in order to infiltrate molten Si into the porous SiC. The microstructure of the FGM is classified into three regions: the SiC-Si composite material; the porous SiC ceramic; and the densified SiC ceramic. The electrical conductivity, the Seebeck coefficient and the thermal conductivity for each region of SiC-Si FGM was measured at 300 K; a figure of merit was calculated. The figure of merit of the SiC-Si FGM at the cold junction, at room temperature, was 10⁸ times higher than that of a nongradient SiC ceramic.     

地域通信网的干扰技术研究

本文在分析地域通信网结构及组成的基础上,研究了对地域通信网实施的节点破坏、末端信息封锁、局部阻塞瘫痪等对抗方法,并使用干扰地域通信网的程度、节点干扰率、末端节点封锁率和传递信息误差率等指标对干扰效果进行评估。     

新型无杆水力采油装置研制与应用

针对中原油田中后期开发存在的液面降低、泵挂加深使得抽油机载荷增加、冲程损失增大、杆管偏磨严重等问题,研制了新型无杆水力采油装置。该装置采用球阀换向,冲程长、冲次低。现场试验时SC38—74—4.8型无杆水力采油装置与常规管式抽油泵联用,下泵深度1650m,冲程4.8m,冲次2.7min-1,日注水量72m3,产出液60m3。结果表明,新型无杆水力采油装置延长了抽油泵的使用寿命,彻底根除了杆管偏磨,采用球阀换向,对动力液要求较低,日常维护简单。     

汽车摩擦片厚度测量装置驱动电路的研究

本文通过对摩擦片厚度在线测量装置系统构成的全面分析，对其驱动电路子系统进行了理论探索和技术研究，完成了相应的电路设计、误差分析及器件选择等工作，并进行了具体的实验验证，证明该驱动电路具有良好的性能，可圆满实现摩擦片厚度在线检测和实时分析的工作任务。     

电荷耦合图像传感器在细线直径测控系统中的应用

文中给出了一个以氟化氪固体激光器做光源，以电荷耦合图像传感器为光屏，应用夫朗禾费衍射原理，实现对细丝直径在线检测自动控制。该方案对相关企业质量控制的自动化是有意义的。     

虚拟仪器在教学中的应用

主要介绍了Multisim2001中虚拟仪器库中函数发生器、示波器的使用方法及功能；并在Multisim2001环境中仿真单管放大电路、桥式整流滤波电路。由调试结果，分析了其在教学中应用的可行性。     

一种高性能图形板的设计与实现

介绍了一种采用高性能嵌入式图形处理器、大容量双端口视频存储器、高性能查色表以及超大规模可编程逻辑器件设计的图形显示控制板的基本组成和工作原理。