新型引线热浸镀锡合金的研究

分析比较了进口锡与国产锡的成分和性能。设计出了新型的引线热浸镀锡合金，它具有较低的工作温度、优良的抗氧化性、流动性和可焊性。     

Nanoscale artifacts in RuO4-stained poly(styrene)

This research studies the effects of RuO₄ exposure on various samples of poly(styrene) (PS). Transmission electron energy-loss spectroscopy (EELS) shows a decrease in the 7 eV π-π∗ transition characteristic of aromatic rings in PS indicating that RuO₄ covalently alters aromatic character. Imaging and selected-area electron diffraction show that a layer of RuO₂ solid forms on the surface of bulk PS specimens exposed to RuO₄. High-resolution TEM imaging (HREM) shows that RuO₂ nanocrystals consistently condense on specimen surfaces, independent of the chemical nature of the specimen below. These nanocrystals modulate contrast at length scales on the order of 2-5 nm in TEM images and limit resolution at nanometer length scales.     

Electron microscopic observations and DNA chain fragmentation studies on apoptosis in bone tumor cells induced by ~(153)Sm-EDTMP

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In-situ birefringence microscopy of uniaxially stretched metal-polymer laminate

This paper concentrates on revealing the local deformation as a function of applied strain in a polymer coating supported by a plastically deforming and roughening metal substrate. To this end in-situ birefringence microscopy measurements have been executed. The measurements are performed in reflection and an alternative unwrapping scheme for the optical path difference is proposed. From the characterization of PET (polyethylene terephthalate) coated stainless steel it is concluded that strain localization appears below the macroscopic strain at yield and that the surface roughness of the substrate is the driving force of the localization.     

Fluctuation X-ray microscopy: a novel approach for the structural study of disordered materials

Measuring medium‐range order is a challenging and important problem in the structural study of disordered materials. We have developed a new technique, fluctuation x‐ray microscopy, that offers quantitative insight into medium‐range correlations in disordered materials at nanometre and larger length scales.In this technique, which requires a spatially coherent x‐ray beam, a series of speckle patterns are measured at a large number of locations in a sample using various illumination sizes. Examination of the speckle variance as a function of the illumination spot size allows the structural correlation length to be measured. To demonstrate this technique we have studied polystyrene latex spheres, which serve as a model for a dense random‐packed glass, and for the first time have measured the correlation length in a disordered system by fluctuation X‐ray microscopy. We discuss data analysis and procedures to correct for shot noise and detector noise. This approach could be used to explore medium‐range order and subtle spatial structural changes in a wide range of disordered materials, from soft matter to nanowire arrays, semiconductor quantum dot arrays and magnetic materials.     

Transmission electron and optical microscopy of the domain structure of Ni3B7O13Br ferroic boracite

The study investigated the domain structure of nickel bromine boracite single crystals, by means of polarised-light in conjunction with transmission electron microscopy. Single crystals of Ni₃B₇O₁₃Br were grown by chemical transport reactions in closed quartz ampoules, in the temperature range of 1130 K and were examined by polarising optical microscopy (PLM), and transmission electron microscopy (TEM). PLM was also used in order to study the behaviour of birefringence as a function of temperature. For TEM the single crystals were crushed and mounted on holey carbon films. Comparative electron microscope images were useful for revealing the domain structure of this fully ferroelectric/fully ferroelastic material previously observed between the crossed polars of an optical microscope. X-ray diffraction analysis of the crystal under study was performed at room temperature.     

How to make and defend a proposal in a deliberation dialogue

In this paper it is shown how tools developed in argumentation theory and artificial intelligence can be applied to the development of a new dialectical analysis of the speech act of making a proposal in a deliberation dialogue. These tools are developed, modified and used to formulate dialogue pre-conditions, defining conditions and post-conditions for the speech act of making a proposal in a deliberation dialogue. The defining conditions set out what is required for a move in a dialogue to count as the making of a proposal by one of the parties. What is required are the conditions that (1) the move fit the requirements of the argumentation scheme for practical reasoning, and (2) the premises are propositions describing common goals of both parties or propositions that they reasonably consider means to achieve these goals. The analysis goes beyond the standard speech act approach by specifying not only the normative requirements for making a well-formed proposal, but also the requirements for responding to it by questioning or criticizing it, and the requirements for defending it.     

Atomic force microscopic analysis of hydrogen peroxide bleached kraft northern black spruce fibres

Hydrogen peroxide is a potent, relatively inexpensive oxidant that chemically degrades chromophoric components in pulps and textiles. Oxidation of cellulose is a byproduct of this process step that decreases the tensile strength of individual fibres. The residence time of pulp in the bleaching reactor must be optimized to achieve the desired brightness and minimizing fibre degradation. To evaluate the impact of peroxide bleaching at the microfibrillar level, a single black spruce tree was chosen and kraft pulped. Peroxide bleaching was conducted via benchtop polyethylene bag bleaching in a temperature-controlled waterbath. Atomic force microscopy (AFM) topographical images acquired before and after the bleaching step show dramatic changes in fibre structure consistent with delignification and defects in the surface topography. This was further verified by X-ray work at Brookhaven National Laboratory, NY, U.S.A.     

Structure of carbon nanotubes probed by local and global probes

A review is proposed of different techniques available today for the characterization of the atomic structure of carbon nanotubes. This review covers the electron microscopies, various diffraction techniques, scanning probe microscopies, and optical spectroscopies, including Raman scattering. The advantages and limitations of the characterization techniques are discussed.     

SEM observation of the “orange peel effect” of materials

This study investigated the peculiar “orange peel” effect often observed in nanomaterials using high-resolution scanning electron microscopes. The study used different materials, including semiconductor thin films and ceramic nanoparticles. The investigation established that the “orange peel” is of an artifact caused by the metallic coating of the samples in sample preparation. This discovery is important in eliminating the misinterpretation of such effect on the true surface feature of materials, hence avoiding the confusion in the discussion of the properties of nanomaterials.