Modeling of the bulk free radical polymerization up to high conversion—three stage polymerization model. II. Number-average molecular weight and apparent initiator efficiency

The equations for predicting the number-average molecular weight are derived on the basis of the three stage polymerization model (TSPM) in this paper. By applying the equations, a plotting approach is proposed to determine the apparent initiator efficiency defined as f[(α_td+1)/2] and the constant of chain transfer to monomer, where f is the initiator efficiency and α_td denotes the fraction of the termination rate constants by disproportionation. Using the approach to plot the experimental data in the literature, it is found that the chain transfer to monomer can be neglected for both methylmethacrylate (MMA) and styrene (St) polymerizations, but it can exert a significant effect on ethylmethacrylate (EMA) polymerization. In addition, the apparent initiator efficiency is found to be independent of reaction temperature and initiator concentration at each stage. The values of f[(α_td+1)/2] at gel effect stage are slightly reduced as compared with that at low conversion stage for MMA and EMA polymerizations. However, it decreases significantly at gel effect stage for St polymerization. Using the equations derived and the apparent initiator efficiencies obtained from TSPM plots, the number-average molecular weights at different conversions can be predicted. Comparisons show that the agreement between predictions and experimental data is satisfactory.     

Structure and properties of injection‐molded polypropylenes with different molecular weight distribution and tacticity characteristics

Two series of polypropylenes with different molecular weight distribution and tacticity characteristics were injection molded into flexural test specimens by varying cylinder temperature and the effects of the molecular weight distribution and tacticity on the structure and properties of the moldings were studied. Measured propertied were flexural modulus, flexural strength, heat distortion temperature, Izod impact strength, and mold shrinkage and structures studied were crystallinity, the thickness of skin layer, a*‐axis‐oriented component fraction and crystalline orientation functions. The relations between the structures and properties were also studied. It was found that the molecular weight distribution and tacticity characteristics affect the properties mainly through the molecular orientation and crystallinity, respectively. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2142–2156, 2002     

Thermally induced microstructural changes in cotton fibers: A free‐volume study

I measured positron lifetime in natural polymer–cotton fibers as a function of isochronal annealing temperature in the range 27–290°C. The variations in the positron results indicated structural changes occurring in the cotton fibers and determined the glass‐transition temperature as 80°C. Activation energies were measured separately for the crystalline and amorphous regions, indicating the versatility of the technique. These values were close to the O? H bond dissociation energy, suggesting O? H bond dissociation, the most probable process occurring under thermal treatment. As an extension of the positron results, the molecular weight of the cotton fibers was determined to be 1,200,000 based on free volume, which was within the range suggested for cotton. There seemed to be an indication that crosslinking changed the spiral structure of cotton fibers to the network type. However, this needs to be validated by other measurements. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3336–3345, 2002     

Analysis and Optimization Laminar Viscous Flow Through a Channel

Optimizing of laminar viscous flow through a pipe by two dimensionless values is investigated analytically. Dimensionless entropy generation and pumping power to heat transfer rate ratio are used as basis for constant viscous and the temperature dependence on the viscosity. For this matter we calculate entropy generation and pumping power for a fully developed in a pipe subjected to constant wall temperature for either constant viscosity and the variable viscosity. The variation entropy generation increase along the pipe length for viscous fluid is drawn, either the variation summation dimensionless entropy generation and the pumping power to heat transfer rate ratio are varying the fluid inlet temperature for fixed pipe length and are varying pipe length for fixed fluid inlet temperature are drawn. For low heat transfer conditions the entropy generation due to viscosity friction becomes dominant and the dependence of viscosity with the temperature becomes essentially important to be considered.     

复参数最大熵图像重建的剑桥算法

本文将正实参数的最大熵图像重建的剑桥算法推广到复参数，此算法能较好的地恢复复参数“图像”。文中还给出了此算法在逆散射成像中应用的计算机模拟实验结果。     

利用最小熵法预测高频拓宽频带

本根据最小熵观点给出了预测高频成分拓宽频带的方法，实际效果表明，该方法是一种拓宽频带的有效方法。     

关于Vague集的模糊熵及其构造

本文分析了Vague集的性质,给出了将Vague集变换为Fuzzy集的转换函数,并讨论了其性质。分析了关于Vague集的模糊熵的直观特性,在此基础上我们给出了Vague集的模糊熵的定义。最后给出了一个关于Vague集的模糊熵的构造方法。     

Effects of high molecular weight component on crystallization of polyethylene under shear flow

Crystallization of polyethylene (PE) blends of low and high molecular weight components under shear flow was studied using time-resolved depolarized light scattering (DPLS), focusing on effects of the high molecular weight component on the shish-kebab structure formation. Anisotropic two-dimensional scattering pattern due to shish-like structure formation was observed above a certain concentration of the high molecular weight PE. The threshold was about 2.5-3 times larger than the chain overlap concentration, suggesting an important role of entanglements of the high molecular weight component. On the basis of these results a gel-spinning-like mechanism for the shish-like structure formation has been proposed. The DPLS results also implied that the shish-like structure was mainly formed from the high molecular weight PE. This was confirmed by small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS) measurements on an elongated PE blend of low molecular weight deuterated PE and high molecular weight hydrogenated PE (3 wt%).     

悬索缆道(带铅鱼)在义棠水文站的应用

文中以山西省首家悬索自动化测流缆道在义棠水文站淤泥质河床的应用为例，叙述了该站缆道的设计、安装、试验研究的基本情况、设计指标、缆道总体布设、信号传输线路的设计及工作原理等。“失重”开关与河底开关的双重保险功能是解决我国北方地区淤泥质河床信号的产生与传输的关键。文中对此做了具体叙述，旨在为类似的缆道工程设计采用时参考。