环保型木器涂料

介绍水性和紫外光固化两类环保型木器涂料及其研究进展。水性木器涂料主要为丙烯酸酯与聚氨酯两大类，其研究进展集中表现为乳液改性，包括自交联、共混共聚、微乳液等；紫外光固化木器涂料包括其光固化树脂、活性稀释剂和光引发剂的功能及进展；指出研究新型乳液以提高水性木器涂料涂膜的表面性能，开发新型原材料以降低紫外光固化木器涂料的成本、扩大适应范围将成为今后环保型木器涂料的研究重点。     

木材用交联型醋丙胶粘剂的研制

研制一种由醋酸乙烯、丙烯酸丁酯、特种单体共聚而成的水性交联型环保胶粘剂以替代目前广泛使用的氨基树脂,适应绿色环保要求。     

水库水温分层对浮式取水口前流速分布的影响

由于目前缺乏对浮式取水口前流场变化规律的研究,以分析水库水温分层对取水口前各断面流速分布影响为目标,依据某水库水温资料,采用k-ε紊流模型对浮式取水口前流场进行三维数值模拟,针对水库水温均一和水温分层的两种情况,研究取水口前流速分布,分析水库水温分层对取水口前各断面流速分布的影响。研究结果表明,在浮式取水口附近,水温均一和水温分层的流速分布存在着差异,这种差距随着取水流量和淹没深度的增大而减小。研究成果可为浮式管型取水设施的应用和运行提供技术支持,为取水水温预测提供理论依据。     

黄河海勃湾水利枢纽对西鄂尔多斯国家级自然保护区胡杨岛的影响分析

海勃湾水利枢纽的建设、运行将对西鄂尔多斯胡杨岛旅游区产生不可逆的影响。经调查分析,胡杨岛胡杨种群分布面积为2.31 hm~2,总株数约为1 800株;胡杨种群表现出增长型特征;胡杨林总生物量为95.43 t。海勃湾水利工程运行后胡杨岛的淹没历时延长,淹没水深、淹没面积显著增加,岛北部低矮位置甚至全年淹没。胡杨部分种子可能落入水中被水流携带,丧失了种子繁殖的条件。根蘖产生的不定芽在4—6月生长期也会浸在水下,不能完成无性繁殖。胡杨幼苗树不高于2.5 m,淹没后无法生存。水库淹没将岛上以陆生生态为主的生态系统演变成以水生生态为主的生态系统,原有的旅游功能将发生变化或丧失,须采取生态补偿措施,减免工程造成的生态影响。     

化学工业推行清洁生产势在必行

本文介绍了清洁生产的内容,阐述了化学工业推行清洁生产的必要性、主要障碍和促进化工清洁生产的重要因素,并以实例说明清洁生产给企业带来的效益。     

Experimental Investigation of Epoxy Bonded Polymethylmethacrylate Joints

This paper presents an experimental investigation into various aspects of epoxy-bonded polymethylmethacrylate (PMMA) and PMMA-to-aluminium joints. The effects of adhesive thickness, overlap area, surface roughness, and environmental exposure on the joint strength were studied. Results indicated that the joint strength was not directly proportional to the overlap area, while sanding had a positive effect on the joint strength. A negative effect was observed when adhesive thickness was increased. The fatigue behaviour of adhesively-bonded joints under dynamic loading was found to be independent of frequency, for the range of values tested; however, it was dependent on the test temperature with greater reduction in fatigue life observed in PMMA-to-aluminium joints at higher temperature. Empirical equations from which the fatigue life of joints can be predicted were obtained by regression analysis. Intermittent fatigue testing of the joints was also performed. The epoxy adhesive tested proved to be a satisfactory choice for outdoor exposure. The rate of degradation of the adhesive was slow with the adherend itself degrading at a faster rate than the adhesive or the bondline.     

近海复杂环境因素对闸墩混凝土裂缝的影响

近海大体积混凝土结构所处的外界环境以及地质条件比较复杂,对于带裂缝水闸结构来说,因所处的地理位置、气候变化以及潮汐升降水位等因素的缘故,水闸闸墩裂缝处于张合状态,这降低了水闸结构的稳定性,甚至会影响水闸结构的寿命。沿海环境温度变化对混凝土裂缝宽度变化的实际监测分析,对于混凝土结构安全耐久性评价具有一定价值,依托典型软土地基永定新河防潮闸工程,利用测缝计对闸墩裂缝宽度变化进行健康监测。主要研究运行期环境因素(以空气温度、水温以及潮汐水位为主)对闸墩裂缝的影响,采用健康安全监测软件,通过对数据的挖掘处理,得出环境温度和水位是影响闸墩水下裂缝宽度变化的敏感性因素的结论,为以后水闸闸墩裂缝的安全维护和裂缝的预防提供思路。     

Trends in low flows of German rivers since 1950: Comparability of different low‐flow indicators and their spatial patterns

Climate change, land‐use shifts, reservoir storage, and water withdrawals impact low flows in rivers, creating challenges for ecological integrity and human uses. A systematic investigation of river discharges was carried out for 79 stream gauges in Germany. Available time series between 1950 and 2013 were analysed for trends in annual minimum low flows, discharge deficits, and low‐flow durations. The application of different low‐flow indicators led to similar spatial patterns, although each metric is used for different purposes in water management applications. Statistical tests identified significant discharge trends at more than half of the stations investigated. Low‐flow trends since 1950 tended to be catchment specific, suggesting that climate change has not been the dominant driver. Most of the gauges investigated showed statistically significant increases in low flows. This can be mainly attributed to reservoir management. For rivers showing snow‐ and icemelt‐dominated flow regimes, such trends are probably overlain by climate‐driven changes (increasing amounts of rainfall, earlier snowmelt in spring). In contrast, stations showing statistically significant decreases in low flows were correlated with areas of decreasing mining activity. Hydrologic impacts of climate change are widespread and significant, but the results here suggest that human river management remains the dominant hydrologic driver on many rivers.     

Assessment of the environmental quality of two urbanized lotic systems using multiple indicators

Urbanization impacts ecosystems through loss and fragmentation of habitat, loss of diversity, increase in runoff, and contaminant discharges, and the invasion of exotic species. Potrero de los Funes Village (San Luis, Argentina) is experiencing not only a population increase during summer months due to tourism but also an accelerated growth of its permanent population. In order to evaluate the potential effects of urbanization, the environmental quality of Potrero de los Funes River and Las Chacras Stream was assessed, using physical–chemical and biological indicators. Macroinvertebrates, through the application of the Biotic Index for San Luis Sierras (BISLS), anuran amphibian richness and relative abundance, and riparian vegetation were used as bioindicators. While the Simplified Index of Water Quality (SIWQ) was used to characterize the physical–chemical quality of water at each site. SIWQ and BISLS scores were significantly different between sites (F_7,28 = 9.88, p < .001 and F_7,28 = 24.18, p < .001, respectively). SIWQ was significantly correlated with BISLS (Spearman correlation coefficient = 0.8, p < .001). Four anuran species were registered along Potrero River, with no significant differences in the intensity of vocalizations between sites. No species were detected in Las Chacras Stream. Average total plant species richness, exotic plants richness, and vegetation cover were higher at the most impaired system, Las Chacras Stream. The principal component analysis showed that the first two principal components (PCs) explained 76.3% of the total variance. PC1, with strong loadings of SIWQ, BISLS, and amphibian richness, was principally driven by chemical water quality and biological conditions. PC2 was mainly determined by plant richness. The chemical and biological water quality of Potrero and Las Chacras is somewhat impaired, being the upper Las Chacras Stream the most compromised area. This study provides information that will certainly be used to manage future impacts of urbanization on aquatic resources.     

含碳氨水集成分离新技术的应用

通过应用含碳氨水集成分离技术改造氨回收装置，提高了分离效率及处理通量，经济与环保效益显著，氨回收率达９９％，处理量提高６０％，塔阻力下降８０％，蒸汽耗量下降４２％，装置出口废液含氨量达国家一级排放标准。