阳离子交换树脂铁中毒的复苏研究

软化器中使用的阳离子交换树脂容易受到铁离子的污染。采用均匀设计的方法,利用回归分析和最优化技术,研究了复苏剂中各组分对阳离子复苏效果的影响,得出了最佳复苏配方,开发出了一种新的复苏方法。这种方法具有腐蚀性低和复苏效果良好的特点,为生产现场树脂的复苏提供了有益的借鉴。     

J-199热熔胶膜的研制

讨论了不同VA含量不同熔体指数的EVA和各种增粘剂对热熔胶膜耐热性、软化点、剪切强度、拉伸强度、剥离强度等性能的影响。通过采用不同材料试验和配方的筛选，研制出一种90℃剪切强度0．07MPa、拉伸强度0．47MPa、耐热性好、粘接强度高的热熔胶膜，从而拓宽了热熔胶的使用范围。     

某炼油厂一级浮床除盐系统阳床工艺特性及调整试验

论述了某厂一级除盐系统阳床工艺特性及调整试验过程，对存在问题进行分析并改进，得到了实际运行最佳方式和参数，取得良好效果。     

Phenol novolac/poly(4- hydroxyphenylmaleimide) blend hardeners for DGEBA-type epoxy resin

Phenol novolac/poly (4-hydroxyphenylmaleimide) (PHPMI) blends were used as an epoxy resin hardener. The curing behavior of the above system and the thermal and mechanical properties of the cured epoxy resin were studied. It was not necessary to use a curing accelerator for this system, because PHPMI caused acceleration of the curing reaction. The curing mechanism of this system was investigated by using model compounds. Test pieces from the neat resins and the glass fiber reinforced resins were evaluated in terms of thermal and mechanical properties, respectively. It was found that heat resistance and mechanical properties were improved by increasing the amount of PHPMI in the hardener.     

树脂悬浮光度法测定微量银

在ｐＨ６．９的缓冲溶液中，银与硫代米Ｃｈｉ酮（ＴＭＫ）形成的螯合物在树脂甘油相中悬浮富集，用光度法测定银在波长４６１ｎｍ处有最大吸收，银在０～６μｇ／１０ｍＬ范围内遵守比尔定律，可用于样品中微量银的测定。     

Influence of two-step process and of different stoichiometric ratios on morphologies generated in castor oil epoxy resins

Phase separation during polymerization was studied in a model system consisting of a diepoxide based on diglycidyl ether of bisphenol A (DGEBA), variable amounts of ethylenediamine (EDA) and the mass of castor oil (CO) necessary to obtain a mass fraction equal to 0-15 in a final system where the stoichiometric ratio of amine to epoxy equivalents, r, was equal to 1. A two-step polymerization process was performed by curing first a system with r = 0-5, during variable times before phase separation, and then carrying the system to r = 1. Thermodynamic analysis of samples with different r values led to a linear relationship between the Flory-Huggins interaction parameter and r. The concentration (P) and average size (D?) of dispersed-phase particles followed opposite trends, i.e. P increased while D? decreased, when either r was increased or the time of curing in the first step of a two-step process was decreased. This was explained by assuming that the competition between nucleation and growth was determined by the viscosity at the cloud point, η_cp. Low values of η_cp favoured growth over nucleation and led to fewer but larger particles.     

载金树脂硫脲硫酸解吸规律的研究

本文对硫酸和氰化钠分步解吸载金树脂上的贱金属离子，以及用硫脲硫酸溶液解吸载金树脂上的金、银络离子的解吸过程进行了研究，并通过现场采集的数据绘制了解吸曲线。     

PTA酸化沉淀池的腐蚀及其研究

阐述了ＰＴＡ酸化沉淀池的腐蚀状况、防腐材料的选材试验及防腐措施的研究及其使用效果；分析了Ｍ树脂玻璃钢的应用技术；提出了ＰＴＡ酸化沉淀池采用复合玻璃钢的防腐措施。     

桐油改性酚醛树脂的结构及固化过程的研究

通过桐油与苯酚在酸性催化剂存在下反应，然后再在碱性催化剂存在与甲醛反应制得了一种热固性桐油改性酚醛树脂。利用红外光谱，差示扫描量热法分析技术对改性树脂的结构及固化反应过程进行了研究。