Study of Hydrodynamics,Mixing and Gas‐Liquid Mass Transfer in a Split‐Rectangular Airlift Reactor

Global hydrodynamic characteristics, liquid mixing and gas‐liquid mass transfer for a 63 L split‐rectangular airlift reactor were studied. Correlations for gas holdup and overall liquid circulation velocity were derived for the air‐water system as a function of the specific power input; these were compared to data and correlations for reactor volumes between 4.7 L and 4600 L. A partial recirculation of small bubbles in the riser was observed when U_gr > 0.03 m/s, which was attributed to the use of a single‐orifice nozzle as the gas phase distributor. The dimensionless mixing time and the overall axial dispersion coefficient were nearly constant for the range of gas flow rates studied. However, values of K_L/d_B were greater than those reported in previous studies and this is caused by the partial recirculation of the gas phase in the riser. While scale effects remain slight, the use of a gas distributor favouring this partial recirculation seems adequate for mass transfer in split‐rectangular airlift reactors.     

染料释放化合物及一当量成色剂浅谈

简述了染料释放化合物的发展过程 ,并由此引出一当量成色剂的概念 ,叙述了一当量成色剂应用和发展 ,对一当量成色剂应用前景做了预测。     

多孔介质内部热质传递的等效耦合扩散模型的推导及其应用

基于Whitaker的体积平均方程，在不附加任何新的假设的基础上，对多孔介质内部热质传递的等效耦合扩散模型进行推导，得出了多孔介质内部热质传递的等效耦合扩散模型。并应用该模型对瓷质砖体干燥过程进行了数值模拟，模拟结果与实验结果十分吻合。     

Ionic liquids as electrolytes

Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors.     

不同缝面形态下诱导缝开裂效果对比研究

一些采用径向扭缝的碾压混凝土拱坝工程中,出现了诱导缝周边坝体混凝土开裂而诱导缝本身未张开的现象,因此需定量分析不同空间形态缝面对诱导缝开裂的影响效果。根据碾压混凝土拱坝应力变化特点以及诱导缝开裂变化规律,本文拟定含不同缝面空间形态的有限大平板和圆筒拱坝算例,利用虚拟裂纹闭合法和Richard脆性断裂准则获取空间缝面等效应力强度因子,研究缝面应力强度因子随缝面夹角的变化规律;通过对归一化后的应力强度因子求倒数,获取不同缝面夹角条件下诱导缝等效强度的修正系数即缝面空间形态影响因子,以反映不同缝面空间形态下诱导缝开裂效果。研究表明,随着缝面夹角的不断增大,缝面越不容易张开,这就意味着缝面的等效强度在逐渐增大。因此,在实际碾压混凝土拱坝设计中,诱导缝应尽量采用竖向垂直缝布置;若要布置成径向扭缝,则缝面夹角最大不宜超过10°。     

Dual segment rectangular dielectric resonator antenna with metamaterial for improvement of bandwidth and gain

The simulation and experimental studies of an aperture‐coupled wideband dual segment rectangular dielectric resonator antenna with metamaterial for C‐band applications are presented in this paper. The antenna consists of Alumina (Al₂O₃) ceramic as upper segment and Teflon as lower segment. The combination of circular‐shaped coplanar split‐ring resonator and conducting strip has been used as metamaterial superstrate. With the use of metamaterial superstrate, the bandwidth of the antenna is increased by 48% through simulation and 22% experimentally. The broadside radiation pattern of the antenna is converted into directive radiation pattern with reduced beamwidth when metamaterial superstrate is used. The peak gain of the antenna is also enhanced by 33% through simulation and 31% experimentally with the use of metamaterial superstrate. © 2014 Wiley Periodicals, Inc. Int J RF and Microwave CAE 24:646–655, 2014.     

Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals

During storage and use, vegetable oil-derived industrial products such as biodiesel and biodegradable lubricants can be subjected to conditions that promote oxidation of their unsaturated components. The materials arising during oxidation and subsequent degradation can seriously impair the quality and performance of such products. Therefore, oxidative stability is a significant issue facing these vegetable oil-derived products, and enhanced understanding of the influence of various components of vegetable oils and storage parameters is necessary. In this work, the oil stability index (OSI) was used for assessing oxidation of monoalkyl esters of FA by varying several parameters. Neat fatty compounds and prepared mixtures thereof were studied for assessing the influence of compound structure and concentration. Small amounts of more highly unsaturated compounds had a disproportionately strong effect on oxidative stability. The recently developed concept of bis-allylic equivalents correlated more closely than the iodine value with the OSI times of mixtures of fatty esters. The OSI times of free acids were shorter than those of the corresponding alkyl esters. The presence of copper, iron, and nickel also reduced oxidative stability, but their effect was less than the presence of more highly unsaturated fatty compounds. Of these metals, copper had the strongest catalytic effect on OSI time. OSI may be an alternative to long-term storage tests for determining the influence of extraneous materials such as metals on oxidative stability.     

带长矩形接管受压圆简体的有限元分析与强度计算

本文运用有限元软件FEPG,建立了带长矩形接管受压圆筒体的三维参数化有限元模型,研究了矩形接管部位的应力分布特点,按照分析设计规范对带长矩形接管受压圆筒体进行了强度评定,并针对应力分布的不合理性提出了结构改进措施。     

瓷质砖湿坯对流干燥过程的传热传质研究

引用建立于Whitaker的体积平均方程和Darcy定律基础止的多孔介质内部热质传递的等效耦合扩散模型，寻出一组关于液体饱和度、温度和气相压力的新支配方程，应用该方程组对瓷质砖坯体干燥过程进行了数值分析和实验测定。在平均含湿饱和度的变化方面，数值解与实验结果十分吻合。还改变影响坯体干燥过程的一些因素进行计算机模拟计算，通过改变这些因素的大小来考察计算结果，以期获得某些定性或定量的结论，从而用以指导实际生产过程。     

Dynamic equivalent method of interconnected power systems with consideration of motor loads

The existing equivalent methods usually only deal with static load models and neglect the dynamic characteristics of loads such as induction motors.This paper presents a dynamic equivalent method which considers motor dynamics.At first,the clustering criterion of motor loads is given.The motors with similar dynamic characteristics are classified into one group.Then,reduction of motors in the same group is carried out.Finally,parameters of the equivalent motor are calculated and the equivalent system is thus...