海洋钻井液有机物添加剂生物降解性评价

随着海洋石油的勘探开发，钻井液有机添加剂不可避免地进入海洋．因此在海洋勘探开发过程中应选择环保性能好，即生物降解性能好的有机物添加剂。用累计耗氧量法测定了海洋钻井液有机添加剂的生物降解性，研究评价了有机添加剂的生物降解规律和机理，探讨了有机物生物降解性同其化学结构的内在联系，为海洋勘探开发过程中选择环保性能好的有机物添加剂提供理论依据。总结实验结果发现：淀粉类(如DFD-140和FI-E1等)最容易生物降解；其次是纤维素类(如MV-CMC等)和烯类单体聚合物(如PAM和PHP)；而沥青类、两性离子类则难以生物降解，有的甚至对生物降解起抑制作用。     

剖析全板电镀镍金发白现象

简要介绍了全板电镀镍金加工过程中镀金面发白现象及改善措施。特别是针对高位发白(或粗糙)的产生原因和处理过程进行较为详细的描述,并对工艺在此处理过程中存在问题进行了简要剖析。     

The Fabrication and Characterization of Single‐Component Polymeric White‐Light‐Emitting Diodes

By using Ni⁰‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m^–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33).     

A Light‐Blue Phosphorescent Dendrimer for Efficient Solution‐Processed Light‐Emitting Diodes

We describe the preparation of a dendrimer that is solution‐processible and contains 2‐ethylhexyloxy surface groups, biphenyl‐based dendrons, and a fac‐tris[2‐(2,4‐difluorophenyl)pyridyl]iridium(III ) core. The homoleptic complex is highly luminescent and the color of emission is similar to the heteroleptic iridium(III ) complex, bis[2‐(2,4‐difluorophenyl)pyridyl]picolinate iridium(III ) (FIrpic). To avoid the change in emission color that would arise from attaching a conjugated dendron to the ligand, the conjugation between the dendron and the ligand is decoupled by separating them with an ethane linkage. Bilayer devices containing a light‐emitting layer comprised of a 30 wt.‐% blend of the dendrimer in 1,3‐bis(N‐carbazolyl)benzene (mCP) and a 1,3,5‐tris(2‐N‐phenylbenzimidazolyl)benzene electron‐transport layer have external quantum and power efficiencies, respectively, of 10.4 % and 11 lm W^–1 at 100 cd m^–2 and 6.4 V. These efficiencies are higher than those reported for more complex device structures prepared via evaporation that contain FIrpic blended with mCP as the emitting layer, showing the advantage of using a dendritic structure to control processing and intermolecular interactions. The external quantum efficiency of 10.4 % corresponds to the maximum achievable efficiency based on the photoluminescence quantum yield of the emissive film and the standard out‐coupling of light from the device.     

Emission Of Volatile And Semivolatile Organic Compounds From Waterborne Paints – The Effect Of The Film Thickness

A waterborne paint was applied to tin plated steel sheets with three different film thicknesses. The emission of volatile and semivolaile organic compounds ((S) VOCs) from the samples was measured in small climatic chambers under standard conditions over a two-week period. The purpose of the study was to evaluate the effect of the film thickness on the emission rate decay. First order decay models, including sink effects for the high boiling (S) VOCs, were fitted to the concentration versus time data. The results showed that the first order rate constants decrease with increasing film thickness. In uddition, the results indicated that the emissions of the (S)VOCs in the waterborne paint film seemed to be controlled by evaporation. The thicknesses of paint films used in climatic chamber tests to estimate emission rates for product compurison or emission prediction must be known in order to prevent erroneous conclusions     

上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.     

有机纤维材料用软膜乳液阻燃剂的制备

采用甲醛、尿素、三聚氰胺、脒基脲磷酸盐为原料,以硼砂、硼酸、氨水为pH调节剂合成了保护胶;在保护胶存在下,以预乳化的丙烯酸酯混合单体于82-88℃共聚合成乳液,将其涂布于有机纤维材料,干燥后得软膜透明阻燃涂层。用其处理的涤棉布阻燃性能为:损毁长度68mm、续燃时间1s、阴燃时间3s、氧指数62、吸附干量287g/kg,处理的纸板的阻燃性能为:平均炭化长度77mm、平均续焰时间2s、平均续灼燃时间32s、吸附干量283g/kg。     

铂与氢、水和苯分子相互作用的量子化学研究

采用量子化学程序Gaussian98(A.9)从头算的B3LYP方法，全优化计算铂对氢、水和苯的化学吸附作用，得到了3种相关络合物PtX、PtXX和Ptxxx(X=H，H2O或C6H6)的平衡几何构型和电子结构信息，并探讨了这些络合物的成键性质，以及苯环与铂原子之间的分子轨道作用性质。结果表明，苯环与铂原子之间有很强的成键作用，并随着游离氢原子和水分子的参与，作用强度有很大变化。苯分子吸附在金属铂上，它的芳香性得到不同程度的降低，苯环被活化，苯环与铂原子之间形成η^2型π键络合物；水参与作用后，苯环与铂原子之间形成σ络合物；氢和水同时参与作用后，苯环与铂原子之间仅有很弱的π轨道作用。     

EO/EG装置生产过程中有机酸的生成原因分析

分析了环氧乙烷，乙二醇装置工艺系统中有机酸生成的原因．指出在银催化剂作用下，乙烯氧化过程有机酸生成主要成分是甲酸和乙酸，银催化剂不是影响氧化反应器出口醛含量的主要因素；杂质、温度等对反应器出口气中的醛含量有重要影响，也直接影响到装置前系统的有机酸含量；乙二醇后系统中有机酸的增加仅取决于两级吸收及解析工艺的稳定操作。