水泥填料对心墙沥青混凝土长期水稳定性的影响

以优选的心墙沥青混凝土配合比为基础,分别采用质量分数为12%的石灰石粉、6%水泥+6%石灰石粉、12%水泥作为填料配制沥青混凝土试件,研究水泥填料对采用天然砾石骨料的心墙沥青混凝土长期水稳定性的影响。试验结果表明:采用12%石灰石粉为填料的沥青混凝土水稳定系数随浸水时间的延长而不断减小,且在浸水75 h后水稳定系数降至0.88,已不满足心墙沥青混凝土水稳定系数大于或等于0.90的要求;采用12%水泥、6%水泥+6%石灰石粉为填料的沥青混凝土水稳定系数随浸水时间的延长先增大后减小,且在浸水375 h后达到最大,分别为1.02和0.98,在浸水1 500 h后水稳定系数仍然能够满足规范要求;用水泥替代部分石灰石粉作填料也可有效改善心墙沥青混凝土的长期水稳定性。     

重力坝深层抗滑稳定设计初探

针对某水库重力坝坝基地层倾角平缓(8°~15°),基岩为薄层状结构,坝基深层抗滑设计是工程关键技术,在利用抗剪断强度理论进行坝基抗滑稳定计算的基础上,通过分析比较常见的坝基基础处理措施,最终确定重力坝坝基采用坝趾处设置混凝土深齿墙措施,可同时提高坝基浅层及深层抗滑稳定安全系数。     

阿尔塔什水利枢纽工程深厚砂砾石覆盖层混凝土防渗墙施工技术研究

阿尔塔什水利枢纽工程是我国在建面板堆石坝工程之一,其深厚的砂砾石覆盖层和庞大的坝体,在施工和运行过程中均会对防渗墙的应力应变产生较大的影响,处理不好直接会影响到大坝整体防渗效果和工程安全。如何在保证施工质量的前提下,优化施工方案,改善防渗墙应力状况,是施工技术研究重点。通过对防渗墙的受力特性、深厚覆盖层的工程特性分析和研究,从防渗墙成墙槽段划分、墙段连接技术、强漏失地层成槽技术和固壁泥浆配比等关键技术上进行优化和改进,有效的消减了防渗墙在坝体填筑和蓄水过程中的应力应变集中,保证防渗墙的成墙质量和运行效果。     

Interfacial in situ polymerization of single wall carbon nanotube/nylon 6,6 nanocomposites

An interfacial polymerization method for nylon 6,6 was adapted to produce nanocomposites with single wall carbon nanotubes (SWNT) via in situ polymerization. SWNT were incorporated in purified, functionalized or surfactant stabilized forms. The functionalization of SWNT was characterized by FTIR, Raman spectroscopy and TGA and the SWNT dispersion was characterized by optical microscopy before and after the in situ polymerization. SWNT functionalization and surfactant stabilization improved the nanotube dispersion in solvents but only functionalized SWNT showed a good dispersion in composites, whereas purified and surfactant stabilized SWNT resulted in poor dispersion and nanotube agglomeration. Weak shear flow induced SWNT flocculation in these nanocomposites. The electrical and mechanical properties of the SWNT/nylon nanocomposites are briefly discussed in terms of SWNT loading, dispersion, length and type of functionalization.     

纳米SiO_2改性外墙涂料的研究

介绍了纳米材料改性高性能建筑外墙涂料的配方及研制,着重讨论了纳米SiO2添加量对涂料性能的影响:掺入4%的纳米SiO2能明显改善涂膜的附着力、光泽度、耐水、耐碱、耐洗刷性和涂料的抗沾污性、触变性能、稳定性。     

泄水建筑物下游冲刷坑二维数值模拟

对巨亭水电站泄水建筑物下游局部冲刷过程进行了二维数值模拟。采用RNG k-ε湍流模型封闭N-S方程、有限体积法在计算网格上离散求解、VOF方法追踪自由水面;采用C语言编写用户自定义函数,以泥沙起动切应力作为床面泥沙起动判别标准,通过分析比较水流剪切力与泥沙起动切应力大小,用以控制冲刷坑底部边界变化;采用局部重构模型和弹簧光顺模型更新计算区域和网格质量,藉以模拟和追踪局部冲刷坑边界变化。研究表明,模拟结果与实测资料符合良好。在冲刷坑的冲刷过程中,床面剪切应力随着冲刷的进程急剧减小,湍动能随着冲刷的进程减小缓慢;床面剪切应力和湍动能沿程变化均较为剧烈,床面剪切应力沿程先增大后减小,床面湍动能则沿程减小。冲刷坑的纵向平衡形态或床面泥沙起动主要决定于床面剪切应力,床面湍动能对泥沙起动也具有重要影响。     

高流态大掺量粉煤灰混凝土的研制及应用

通过混凝土配合比的正交试验及有关因素影响效果的分析,确定了高流态大掺量粉煤灰混凝土配合比的最优方案,进而成功用于最深的混凝土防渗墙工程中,为高流态大掺量粉煤灰混凝土的广泛应用提供了参考。     

论大钢模体系在剪力墙结构施工中的应用

简要叙述了大钢模施工的应用前景,着重分析了大钢模施工的优、缺点,大力推广大钢模施工技术的应用。     

间歇窑窑墙温度场图形仿真研究

本文利用有限差分法求解间歇窑窑墙中的温度分布，并用Ｃ语言设计了窑墙温度场图形仿真软件。输入窑墙厚度和材料的物性参数等，系统可进行窑墙温度场分布的实时仿真及窑炉结构与操作的优化     

Catalytic wall reactor: Catalytic coatings of stainless steel by VOx/TiO2 and Co/SiO2 catalysts

Catalytic wall (structured) reactors and structured supports are suitable to study the catalytic properties of nanosized materials. The coating of metallic (aluminum and stainless steel) plates by thin layers of active phase is presented in two cases, VO_x/TiO₂ and Co/SiO₂, catalysts used in the oxidative dehydrogenation (ODH) of propane and in Fischer–Tropsch synthesis (FTS) of clean fuels, respectively. The preparation of coated plates and their characterisation by various methods of physicochemical analysis are described. Both chemical and physical methods were used for coating. VO_x/TiO₂ layers were obtained by grafting of Ti (on Al or stainless-steel plates) and V (on TiO₂) alkoxides and use of sol–gel media or suspension. A silica primer was deposited (on stainless-steel plate) by plasma-assisted chemical vapour deposition (PACVD) onto which Co oxide and silica were coprecipitated from sol–gel. The catalytic experiments in the respective reactions were carried out in special plate reactors and compared with those of catalytic powders. The study shows that the coating of a metallic substrate by a catalyst is not straightforward and requires specific studies dealing with both chemistry (chemical affinity between substrate and catalytic layers) and catalytic engineering (catalytic performance in taylor-made reactors).