Effect of oxygen flow rate on the structural and electrochemical properties of lithium nickel oxides synthesized by the sol–gel method

The structural and electrochemical properties of LiNiO₂ powders were investigated as a function of the oxygen flow rate employed in the preparation of lithium nickel oxide. It was found that oxygen played an important role in the synthesis of highly crystallized LiNiO₂(R3¯m). In the crystallization process of LiNiO₂, a deficiency of oxygen in the calcination reactor induced the formation of impurities and cubic rock-salt structure (Fm3m) in LiNiO₂ powders. For LiNiO₂ prepared at higher oxygen flow rates, the electrode delivered high discharge capacities with relatively good retention rates. But very low electrode capacity was obtained from LiNiO₂ prepared at lower oxygen flow rates.     

异丁烷与丁烯烷基化反应工艺

讨论了异丁烷与丁烯烷基化反应工艺在清洁燃料生产过程中的地位、作用和发展趋势;简介了目前石油炼制工业中使用的液体酸烷基化工艺;详细介绍了正在研究开发的固体酸烷基化技术;对在烷基化反应中应用的新型固体酸催化材料和新催化反应工艺的探索和进展进行了综述。     

离子静电水处理技术在循环冷却水中的应用

简要介绍了离子静电水处理技术杀菌、灭藻、防垢阻垢的机理，及在循环冷却水系统中的应用情况。     

Design and control of an olefin metathesis reactive distillation column

This paper considers the design and control of a reactive distillation column in which one reactant is consumed and two products are formed (A?B+C). The volatilities are α_B>α_A>α_C, i.e. the reactant is intermediate boiling between the two products. The metathesis of 2-pentene is considered as the demonstrative example. The column has a single feed of the intermediate boiling reactant. The distillate contains mostly light component and the bottoms mostly heavy.Three designs are considered: the base case (low-conversion/low-pressure), a low-conversion/high-pressure case and a high-conversion/high-pressure case. The base design is obtained from the literature, and the other two steady-state designs are optimized with respect to the total annual cost. All the designs are found to be openloop stable. Five control structures are studied for the base design. Then the best two structures are applied to the remaining two designs. This category of reactive distillation exhibits less challenging problems than other categories since it uses a single feed, which eliminates the need for the control structure to perfectly balance two fresh feeds.Simulation results demonstrate that effective dynamic control is provided by a control structure that uses two temperatures to maintain the purities of both product streams. No internal composition measurement is required. This structure is found to be robust and stable and rejects loads and tracks setpoints very well.     

Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

电流模式n阶传输函数的OA-OTA实现

提出了一种新的实现任意 n阶电流模式传输函数的网络结构。该电路仅含运算放大器 (OA)和运算跨导放大器 (OTA)有源器件 ,因而适于全集成。适当设置 OTA的跨导值能实现任意高阶传输函数 ,且传输函数的系数可独立调整。文中推导了滤波器的设计公式 ,并给出了截止频率为 1 0 0 k Hz的三阶巴特沃斯低通滤波器实例 ,PSPICE仿真结果表明所提电路及设计公式是正确的     

对完善公司物资供应管理体系的思考

针对经“债转股”和资产重组成立的北京东方石油化工有限公司物资供应管理特点和存在的问题，从供应管理模式、采购方式、采购过程监控、信息化管理、物资储备、人员结构等6个方面，分析了目前供应管理存在的问题和不足，并针对问题通过对物资供应管理体制的分析和思考，提出对策，为新的物资供应体制的建立提供参考。     

健康长江评价指标体系与标准研究

科学的指标体系和标准是评价河流健康状况的技术依据。根据科学性、代表性、创新性等原则，运用主成分分析法和聚类分析法．构建了健康长江评价指标体系，包括河岸稳定性、河床稳定性等19个定量指标和水系连通性、河岸栖息地状况和珍稀水生动物存活状况3个定性指标；给出了相应指标的量化评价方法，并通过国内外相关研究成果的综合分析．提出了健康长江的评价标准及分类标准，为维持河流健康理论发展提供了新方法。