饲料用脱氟磷酸钙的生产

本文介绍了饲料用脱氟磷酸钙生产现状，建议采用钠盐－磷酸法工艺。     

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本文提出了油井稳定生产状态下的脉冲试井数学模型,利用时间和空间叠加原理求得其解析解。并用非线性回归分析方法来进行脉冲试井分析。     

ERD facility for analysis of hydrogen and deuterium in solids

Hydrogen is the lightest element in nature, and so, its detection and quantitative analysis is difficult by the conventional methods utilized for other elements. In the recent years the technique of elastic recoil detection analysis (ERD) using 1–2 MeV He⁺ beam has been developed to quantitatively and simultaneously analyze hydrogen and its isotopes in solids. Such a facility has been set up using the 2 MeV Van-de-Graaff accelerator at IIT Kanpur. It facilitates H and D analysis in a material up to a depth of ∼ 1μm with a detection sensitivity of 0·1 at.% and depth resolution of about 300 ?. The application potential of this setup is illustrated by presenting the results of measurements performed on Al:H:D systems prepared by plasma source ion implantation and highT _c YBCO pellets exposed to humid atmosphere.     

Plasma immersion ion implantation for SOI synthesis: SIMOX and ion-cut

We have demonstrated feasibility to form silicon-on-insulator (SOI) substrates using plasma immersion ion implantation (PIII) for both separation by implantation of oxygen and ion-cut. This high throughput technique can substantially lower the high cost of SOI substrates due to the simpler implanter design as well as ease of maintenance. For separation by plasma implantation of oxygen wafers, secondary ion mass spectrometry analysis and cross-sectional transmission electron micrographs show continuous buried oxide formation under a single-crystal silicon overlayer with sharp Si/SiO₂ interfaces after oxygen plasma implantation and high-temperature (1300°C) annealing. Ion-cut SOI wafer fabrication technique is implemented for the first time using PIII. The hydrogen plasma can be optimized so that only one ion species is dominant in concentration and there are minimal effects by other residual ions on the ion-cut process. The physical mechanism of hydrogen induced silicon surface layer cleavage has been investigated. An ideal gas law model of the microcavity internal pressure combined with a two-dimensional finite element fracture mechanics model is used to approximate the fracture driving force which is sufficient to overcome the silicon fracture resistance.     

对数型产量衰减曲线方程的建立与应用

在产量衰减曲线方程的基础上，通过数学推导，得到了一种对数型产量减曲线方程。方程既可以用来预测油气田整个开发阶段的指标，又可以比较准确的测算油气田的可采集量。对国内外一些油田的实际应用表明，对数型产量衰减曲线方程是十分实用和有效的。     

Selective partial oxidation of light paraffins with hydrogen peroxide on thin-layer supported Nafion-H catalysts

Thin-layer carbon supported Nafion-H catalysts were found to be active and highly selective (S>98%) for the partial oxidation of C₁-C₃ alkanes, in a three phase catalytic membrane reactor (3PCMR), under mild conditions and in the presence of H₂O₂. The influences of the catalyst teflon loading and H₂O₂ concentration on the reaction rate have been evaluated. A reaction pathway, based on the electrophilic hydroxylation of the C-H bond of alkanes with protonated hydrogen peroxide (H₃O ₂ ⁺ ), is discussed.     

中国丙烯腈生产技术国产化发展过程

论述了30年来中国丙烯腈生产技术的发展概况和目前达到的技术水平。中国于1960年开始氨氧化法制丙烯腈技术的开发,大致可分为三个时期:1960—1969年实验室基础研究和中间试验,进行了固定床和流化床及相适应的催化剂以及丙烯腈回收精制工艺的研究。1970—1980年建成了一批生产装置并进一步改善了生产工艺和催化剂。1981年到目前是以国际先进水平为目标,开发了高性能催化剂、流化床反应器和新的丙烯腈回收精制工艺。目前已开发成功的MB-86型催化剂、内构件流化床、复合萃取分离新工艺等具有国际80年代末期水平。丙烯单耗为1.02—1.05t丙烯/t丙烯腈,同时可分离出纤维级丙烯腈,高纯度氢氰酸和浓度达80%的乙腈。也完成了乙腈精制、硫铵回收等副产物回收技术。在此基础上已经开始设计两个万吨级丙烯腈工厂。     

国内外改质沥青生产的现状及其发展

煤焦油沥青是炼铝及碳素工业的重要原料之一，它地质量如何直接影响到制品的技术经济指标。近年来，随着科学技术的发展，煤焦油沥青重整改质技术引起重视。目前已有许多国家已生产出改质沥青来满足制取电炉炼钢超高功率电极以及制品铝电解板的要求证同国内对此也开始进行研制工作。介绍了国内外改质沥青生产的现状及发展，并提出了参考建议。     

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本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。     

废电解液除杂制取硫酸铜和粗镍

介绍了废电解液除杂制取硫酸铜和粗镍的主要工艺条件及试验结果。在废电解液中加入CH80调节pH值到一定范围后,再加入CH64将电解液中Fe2+等杂质除去,铁的去除率可达到94%～98%。然后向滤液中加入CH80调节pH值沉淀铜。过滤后的滤饼用H2SO4溶解后再结晶,可得到CuSO4·5H2O晶体。滤液中加入Na2CO3沉淀镍,过滤后的滤饼即为粗镍(NiCO3)。铜和镍的回收率分别达96%和90%。该流程简单,投资少,效益高,环境保护好,在工业上有较广的应用前景。