剪切场下聚合物结晶形态学研究进展

聚合物熔体被引入剪切场后，会发生与静态下不同的结晶现象。微观上可以得到伸直链晶体、片晶及串晶；宏观上除了静态下典型的球晶外，还能观察到球晶的变形和柱晶等。另外，剪切还可以使晶体发生晶型转变。本文对聚合物熔体在剪切场下结晶形态学的研究进展进行了介绍。     

不同穗型水稻产量与群体生理性状的关系

根据穗倾角穴穗颈节至穗尖的连线与茎秆延长线的夹角雪的大小,将参试的12个品种划分为直立穗型、半弯曲穗型、弯曲穗型3种类型,研究了不同穗型的群体形态生理性状与产量形成的关系。结果表明,弯曲穗型品种抽穗期干物重较高,直立穗型品种抽穗后和成熟期干物重较高,抽穗后干物重占成熟期干物重的百分比也较高,半弯曲穗型上述方面介于二者之间。直立穗型、半弯曲穗型和弯曲穗型的颖花/叶值相近,说明三者单位叶面积所负担的颖花数差异不大。就粒重/叶而言,直立穗型>半弯曲穗型>弯曲穗型。直立穗和半弯曲穗型品种抽穗后单个颖花拥有的干物质越多,成粒率越高。比叶重大的品种,抽穗后群体叶面积衰减缓慢,具有一定的群体叶面积,对干物质生产和产量的形成是十分有利的。     

Microscopy under pressure--an optical chamber system for fluorescence microscopic analysis of living cells under high hydrostatic pressure

High hydrostatic pressure (HHP) becomes more and more interesting for life science research, since it can be employed to inactivate various cells. To directly monitor "cells under pressure," the development of an optical high-pressure chamber is required. Therefore, an optical pressure chamber that can be used for up to 300 MPa was constructed. This chamber has already been described as a tool for in situ observation of dynamic changes of microscopic structures in bright field as well as phase contrast. In combination with an inverted microscope, we obtained brilliant microscopic color pictures with an optical resolution more than 0.56 microm. Here, we demonstrate the capabilities of the HHP cell, in combination with epifluorescence microscopy. Using a nonadherent human B-cell line (Raji, ATCC CCL 86), stained with the fluorescent dyes propidium iodide, Hoechst 33342, or dihexyloxacarbocyanine iodide, we were able to show that the system is suitable to perform fluorescence microscopic analyses, with pressures up to 300 MPa, with viable mammalian cells.     

热塑型聚氨酯结构形态的研究

本文研究了两个系列的热塑型聚氨酯—聚醚酯氨(ET)和聚酯氨酯(ES)的结构形态与相分离程度,提出了一种确定硬段含量(W_h)的IR方法。与NMR法、投料比法比较,三者得到非常吻合的结果。此外本文还研究了W_h、M_(n·■)、拉伸及热历史对相分离程度的影响。     

金红石型纳米TiO2在聚丙烯塑料中的抗老化应用研究

以金红石纳米TiO2为抗老化添加剂改性了PP材料,采用TEM、XRD、UV-VIS等测试手段分析了纳米TiO2的性能特征,用氙灯耐气候试验机人工加速了PP材料的老化降解,对比分析了纯PP和改性PP老化期间力学性能的变化规律,用SEM分析了PP材料的断口表面形貌及纳米TiO2的分散情况。研究结果表明,纳米TiO2及其复合材料对PP材料有增韧增强作用,并能赋予改性材料优异的耐候性能,延长PP制品的使用寿命。     

化学气相沉积ZrO_2涂层的表面微观形貌演变

采用ZrCl4-CO2-H2-Ar体系,在不同温度或氢气流量条件下采用常压化学气相沉积法(APCVD)通过不同沉积流程在C/C样品表面制备ZrO2涂层。用X射线衍射分析仪(XRD)和扫描电镜(SEM)分析涂层的物相组成和形貌特征。结果表明:随沉积温度升高,ZrO2涂层表面形貌由小颗粒堆积态向大尺寸多晶转变;氢气流量为0时,只在局部区域出现了少量ZrO2,当氢气流量为400mL/min时,ZrO2涂层晶粒尺寸较大且晶体学平面特征最明显;在氢气流量为800mL/min时沉积出现了副产物ZrC与C;在氢气流量为1600mL/min时,出现沉积副产物ZrC;连续沉积时,得到的ZrO2涂层为山峰状形貌。     

气体流量对多壁纳米碳管形貌和产率的影响

以CH4为碳源气，以H2为还原气，以纳米NiO-SiO2气凝胶为催化剂，探讨了气相化学沉积法制备多壁纳米碳管工艺过程中，气体流量对产物形貌和产率的影响。实验结果表明，CH4和H2流量保持为2：1，气体总量一定时可以经济地制备出长径比大，形态较好的纳米碳管，且产率较高。     

WC粉末粒度与形貌对硬质合金中WC晶粒度、晶粒形貌与合金性能的影响

探讨了粗颗粒与特粗颗粒两种粒度级别以及平面化表面与球化表面两种形貌特征的WC原料对WC-Co硬质合金中WC晶粒度、晶粒形貌以及合金性能的影响。结果表明,分别采用费氏粒度为11.4￣13.4μm,与22.0￣28.3μm两种粒度级别的WC粉末为原料制备合金,尽管两种合金硬度之间存在明显差别,但是两种合金的晶粒度相差很小,在4.0￣4.3μm之间,同属一种粒度级别。WC原料的原始形貌对合金中WC晶粒形貌与合金性能影响很小,碱金属掺杂原料制备的合金中WC晶粒结晶完整性相对较差。因此,高纯原料是制备高性能硬质合金的基础。     

Shape Connectivity: Multiscale Analysis and Application to Generalized Granulometries

This paper develops a multiscale connectivity theory for shapes based on the axiomatic definition of new generalized connectivity measures, which are obtained using morphology-based nonlinear scale-space operators. The concept of connectivity-tree for hierarchical image representation is introduced and used to define generalized connected morphological operators. This theoretical framework is then applied to establish a class of generalized granulometries, implemented at a particular problem concerning soilsection image analysis and evaluation of morphological properties such as size distributions. Comparative results demonstrate the power and versatility of the proposed methodology with respect to the application of typical connected operators (such as reconstruction openings). This multiscale connectivity analysis framework aims at a more reliable evaluation of shape/size information within complex images, with particular applications to generalized granulometries, connected operators, and segmentation.     

基于多结构元的形态图像边缘检测算法

基于修正的边缘检测算子和形态滤波思想,提出一种新的多结构元素形态学灰度图像边缘检测算法。在该算法中,自适应确定权重,并将各个结构元素下的检测信息进行加权求和,得到噪声存在条件下较为理想的图像边缘。仿真结果表明所给算法效果优于经典的边缘检测方法。