Cooperative adsorption behavior of fatty acid methyl esters from hexadecane <Emphasis Type="Italic">via</Emphasis> coefficient of friction measurements

The frictional behaviors of methyl oleate (MO), methyl palmitate (MP), methyl laurate (ML), and methyl stearate (MSt) as additives in hexadecane have been examined in a boundary lubrication test regime using steel contacts. It was found that the transient attributes of coefficient of friction (COF)-time spectra are a sensitive measure of adsorption equilibria. Critical additive concentrations were defined and used to perform novel and simple Langmuir analyses that provide an order of adsoprtion energies: MSt>MP>MO≥ML. Application of Langmuir, Temkin, and Frumkin-Fowler-Guggenheim adsorption models via nonlinear fitting of a general cooperative model demonstrates the necessary inclusion of cooperative effects in the applied model. In agreement with the qualitative features of steady-state COF-concentration plots, MSt modeling requires minimal cooperative interaction terms. However, MO, MP, and ML data require large attractive interaction terms to be adequately fitted. Primary adsorption energies calculated via the cooperative model are necessarily decreased, whereas total adsorption energies correlate well with values obtained via critical concentration analyses. These results and comparisons with previous adsorption studies of MO and MSt suggest that primary (ester-surface) and secondary (alkyl-surface) adsorbate-adsorbent, adsorbate-adsorbare, and (free-additive) adsorpt-adsorpt interactions collectively determine both the calculated primary and the cooperative interaction energies.     

IPN压电阻尼材料的研究进展

阻尼材料广泛应用于交通工具、产业机械、建筑土木、家用电器、精密仪器和军事装备等领域。科学技术的不断发展,对阻尼材料的要求不断提高。本文主要综述了阻尼材料的发展状况,阐述了粘弹性阻尼、高阻尼合金、阻尼复合以及聚合物基压电智能阻尼材料的阻尼机理,并详细分析介绍了聚合物基IPN压电阻尼材料的设计原理及阻尼效果。     

降噪高分子材料及其应用

降噪材料按降噪机理可分为阻尼减振材料、吸声材料和隔声材料。降噪高分子材料可广泛应用于建筑、交通、化工和生活等各个领域。综述了降噪高分子材料的主要种类及其作用机理，并对高分子降噪材料的研究现状和应用情况作了简单的介绍。     

聚氨酯橡胶摩擦轮有限元及疲劳寿命分析

针对汽车滑板输送机聚氨酯橡胶摩擦轮的开裂问题,对摩擦轮与滑板之间的相互作用进行预压紧力和接触摩擦驱动有限元分析,获得摩擦轮的应力和变形分布等结果.在获得摩擦轮周向应力分布的基础上,根据疲劳裂纹扩展公式对聚氨酯橡胶部分进行疲劳寿命分析,验证是否满足设计要求.分析过程和结果能为聚氨酯橡胶摩擦轮的详细设计提供参考.     

Mechanical and dynamic mechanical properties of jute fibers–Novolac–epoxy composite laminates

A study was done of jute composite using a polymer matrix of epoxidized Novolac resin (ENR), diglycidyl ether of bisphenol A (DGEBA)–based epoxy, and their blends with different weight percentages of the resins. It was found that on blending ENR with DGEBA, the storage modulii at room temperature are enhanced by about 100% or more in the case of 30 and 40% ENR‐containing matrices, whereas the enhancement in the case of 20 and 12% ENR‐containing matrices is only 50% that of the pure matrix. It was also observed that the tan δ peak heights of the composites containing 30 and 40% ENR are closer to that of 20% ENR‐containing composite. The probable explanation drawn on the basis of experimental findings of DMA and mechanical analysis is that by blending ENR with DGEBA epoxy it is possible to manufacture jute composites with increased stiffness without sacrificing their ductility. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2800–2807, 2002     

重塑黄土与植物根系界面摩擦离散元分析

油松作为一种植根于黄土地区的常见植物,在提高黄土强度方面起重要作用。为了弄清油松根系在黄土地区的固土效应,本文采用离散单元法(Distinct Element Method)模拟根系拉拔试验,分析了法向压力、根系埋深、含水率对根-黄土界面摩擦力学特性的影响。结果表明:拉拔试验中,根-黄土界面峰值强度、残余强度随着法向力的增大而增大;峰值强度、残余强度随着根系埋深的增加而增大;随着含水率的降低,根-黄土界面峰值强度、残余强度呈增大的趋势。     

摩擦材料研究进展

对摩擦材料国内外发展现状进行了综述，简要叙述了摩擦材料的发展历史，以及各种摩擦材料的性能以及应用，阐述了它们的优缺点，说明了纤维在摩擦材料中的重要作用。同时指出陶瓷基复合摩擦材料是今后发展的趋势。     

基体和增强体对聚合物基摩擦材料性能影响研究

摩擦系数、磨损率和冲击强度是聚合物基摩擦材料的重要性能指标。本文试验研究基体含量对摩擦系数、磨损率的影响和增强体含量对冲击强度的影响,从理论方面分析增强体对摩擦磨损性能的影响。试验结果表明,在进行聚合物基摩擦材料的配方设计时,要根据所选用酚醛树脂和增强纤维的种类合理控制用量,可达到较好的摩擦磨损性能和冲击韧性。     

Friction and adsorption properties of normal and high-oleic soybean oils

The steel/steel boundary friction properties of soybean oil (SBO) and high-oleic soybean oil (HOSBO) are compared. HOSBO is significantly more saturated than SBO and more oxidatively stable. Changes in degree of unsaturation affect lateral interactions of adsorbate molecules, which in turn affects their adsorption and, hence, their boundary lubrication properties. To investigate this possibility, the free energies of adsorption (ΔG _ads) of SBO, HOSBO, and methyl laurate (ML) were determined from the analysis of friction-derived adsorption isotherms using the Langmuir and Temkin adsorption models. The results showed a stronger adsorption for the vegetable oils than for ML, an indication of multiple interactions between the ester groups of the triglycerides and the steel surface. The result also showed no difference in the ΔG _ads values of SBO and HOSBO obtained using either the Langmuir or Temkin models. This was interpreted as an indication of the lack of appreciable net lateral interaction between triglyceride adsorbates.