Microalloyed high-strength low-alloy (HSLA) steels contain additions of Nb, V, Ti, or in combination, in amounts of 0.01 to 0.1 weight percent to improve mechanical properties, which are strongly dependent on the thermomechanical interaction taking place in the course of rolling mill processes. The recrystallizatian of hat-twisted austenite has been investigated in a cylindrical specimen (f 6×50 mm) machined from hat rolled plates of 0,052 wt % Niobium microalloyed steel. Continuous and interrupted torsion test were carried out in the temperature range 1123 K to 1173 K after a solution treatment of 1.5 minutes at 1423 K and torque-twist data were analysed. The various methods were discussed for obtaining results from torsion tests. The effect of precipitation kinetics was appreciated by way of connection tp/tp(red), where tp is the experimental measured time for the peak stress and tp(red) is the newly defined reduced time. The softening ratio X and time t0.05R for start of static recrystallization were established.
The correlation between precipitation and recrystallization is presented as a graphs for chosen requirements (temperature of austenitization, carbon and niobium content and strain rate). If temperature goes below 850°C, the restoration processes are hardly suppressed, both are limited by diffusion and Nb(CN) precipitation, which are extended dynamically in the range of strains rates 10−2 to 1 s−1.
In the present paper, an attempt is made to derive the PRTT diagram and to define all mathematical equations for describing recrystallization times t0.05R, t0.5R, t0.95R and t0.05P for the start of precipitation. In real metal forming processes such as the hot rolling of plates or strips the knowledge of these parameters and results is extremely important for the the correct microstructure and sheet quality to be obtained. 相似文献
In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C5H4XNH+ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed. 相似文献
Based on the thermodynamic point of view, a method for predication of the composition range of amorphous ter-nary alloys was proposed. The composition range of amorphous ternary alloys is determined by the comparison of the excess free energy of the amorphous alloy and the free energy of competing crystalline states. The free energy is extrapolated from the data of three binary alloys by using Toop‘s model. The method was applied to predict the composition range of amor-phous Mg-Ni-Y alloys. The theoretical results are in good agreement with the available experimental results. It indicates that the present method can be used to predict the composition range for amorphous ternary alloys. 相似文献