舰载雷达探测误差传递与灵敏度分析

在舰艇及编队指控系统中,来自不同平台的传感器探测系统偏差失配是影响态势一致性的关键因素。本文采用理论建模和数字仿真相结合的方法,对舰载雷达探测和处理涉及各环节的偏差进行分析,建立了雷达测量、坐标转换、平台定姿定位和基线转换等各环节偏差影响模型和舰载雷达探测的等效偏差模型。理论分析和计算机仿真结果表明,雷达方位测量、平台艏向和甲板艏向形变引起的偏差均可以直接迭加到方位上,合并为方位偏差;同时,在目标俯仰角小于10°的情况下,基本上可以忽略甲板形变、平台姿态偏差对目标方位测量的影响。     

长轴表面激光淬火变形与控制

应用激光淬火强化技术控制长轴的淬火变形，分析了激光淬火变形的原因和影响因素。研究结果表明，激光淬火不仅可使长轴振摆变形量控制在很小的范围内，而且可将已变形的长轴校直到很高的精度。     

纳米晶体Se的微观结构特征

本文采用Ｘ射线衍射和透射电子显微镜研究了纳米晶体Ｓｅ的微观结构特征．通过测定不同晶粒尺寸的纳米晶体Ｓｅ的点阵参数ａ和ｃ，发现纳米晶体Ｓｅ中存在晶格畸变，畸变量与晶粒尺寸有关．得到了纳米晶体Ｓｅ中晶胞体积变化与晶粒尺寸的关系．并由点阵参数计算出纳米晶体Ｓｅ的键长．用非晶态Ｓｅ中的无规链折叠的晶化机制解释了纳米晶体Ｓｅ中晶格畸变现象．     

Multidisciplinary optimization of gas-quenching process

Distortion as a result of the quenching process is predominantly due to the thermal gradient and phase transformations within the component. Compared with traditional liquid quenching, the thermal boundary conditions during gas quenching are relatively simple to control. By adjusting the gas-quenching furnace pressure, the flow speed, or the spray nozzle configuration, the heat-transfer coefficients can be designed in terms of both the component geometry and the quenching time. The purpose of this research is to apply the optimization methodology to design the gas-quenching process. The design objective is to minimize the distortion caused by quenching. Constraints on the average surface hardness, and its distribution and residual stress are imposed. The heat-transfer coefficients are used as design variables. DEFORM-HT is used to predict material response during quenching. The response surface method is used to obtain the analytical models of the objective function and constraints in terms of the design variables. Once the response surfaces of the objective and constraints are obtained, they are used to search for the optimum heat-transfer coefficients. This process is then used instead of the finite-element analysis. A one-gear blank case study is used to demonstrate the optimization scheme.     

异形坯连铸坯壳应力与鼓肚变形分析

坯壳应力引起的鼓肚变形是影响铸坯质量的重要因素,为防止过大的鼓肚变形,依据湍动能理论、热流传递理论和粘弹性理论,建立了异形坯三维热-力耦合模型,开发了鼓肚分析软件,从而避免了漏钢事故的发生.该模型将温度场和应力场的计算相互耦合,交替进行.结果表明:异形坯截面最危险点位于腹板中部,其次为翼板中点,在两者相结合的圆角部,由于凝固坯壳比较薄,其应力值也比较大;当坯壳厚度小于20 mm时,两点的鼓肚变形量将分别超过其极限变形量,铸坯出结晶器时必然发生漏钢事故.该模型通过预测坯壳应力和鼓肚变形量为现场安全生产提供了理论依据.     

基于遗传算法的图像恢复研究

通过对遗传算法和图像恢复理论的分析，提出了基于遗传算法的图像恢复方式。该方式具有优化、收敛性快等优点。     

Synthesis and electrochemical characterization of a new Se-doped spinel material for lithium secondary batteries

A new Se-doped spinel material, LiAl_0.18Se_0.02Mn_1.8O₄ powder with a phase-pure polycrystalline was synthesized by a sol–gel method. The material in the 3 V region (2.4 3.5 V) and both the 3 and 4 V region (2.4 4.4 V) initially deliver a discharge capacity of 81 and 178 mA h g^–1 which increase with cycling to reach 110 and 204 after 50 cycles, respectively. The material shows excellent cycleability in the 4 V region (3.0 4.4 V) with almost no capacity loss. The structural integrity of the Se-doped spinel was characterized by charge–discharge cycling tests and X-;ray diffraction.     

Premodification of Pt/γAl2O3 with Cinchonidine for the Enantioselective Hydrogenation of Ethyl Pyruvate: Effect of Premodification Conditions on Reaction Rate and Enantioselection

The premodification of a 5 wt% Pt/-Al₂O₃ catalyst with cinchonidine (0.01 and 0.2 g g^-1 _catalyst) is described and discussed. Premodification is carried out by treating the catalyst with a solution of cinchonidine followed by solvent removal. Catalysts premodified in this way give the same ee and initial rate of reaction for the enantioselective hydrogenation of ethyl pyruvate as those using the standard in situ modification procedure. Investigations of different solvents for premodification and reaction (dichloromethane, ethanol) show that it is the solvent used for the reaction that controls the observed enantioselection. Premodified catalysts also display the initial transient behavior typically observed with in situ modified catalysts in which the ee increases with conversion in the early part of the reaction. Premodified catalysts show an enhanced rate of reaction when ethanol is used as the reaction solvent compared with in situ modified catalysts under the same conditions. Premodification using aerobic conditions gives the best results and premodified catalysts can be stored prior to use for up to a week without loss of catalytic performance.     

Role of La2O3 in Pd-Supported Catalysts for Methanol Decomposition

Systems of Pd supported on various La₂O₃-modified -Al₂O₃ and CeO₂–Al₂O₃ catalysts were tested for catalytic methanol decomposition and characterized by means of XRD, BET, TPR, H₂-chemisorption and CO–FTIR. The addition of lanthanum significantly improved the selectivity of CO and H₂ for all the catalysts but showed a different influence on the catalytic activity in two systems. Methanol conversion decreased on La₂O₃-modified Pd/-Al₂O₃ catalysts, in line with the reduction of Pd dispersion, while the addition of La₂O₃ improved the dispersion of Pd and reinforced Pd–CeO₂ interaction for La₂O₃-modified Pd/CeO₂–Al₂O₃ catalysts, which resulted in a high production rate of CO and H₂. Thus, a synergistic effect between CeO₂ and La₂O₃ was observed on -Al₂O₃-supported Pd catalyst for methanol decomposition.     

Structure–Function Relations in Supported Ni–W Sulfide Hydrogenation Catalysts

Ni–W catalysts were prepared by impregnation of commercial -alumina and silica supports. The sulfidation, performed directly after drying at 100°C, yielded fully sulfided Ni–W species on both supports (SEM-EDAX, XPS, XRD). At optimal metals loading (50 wt% NiO + WO₃, Ni/W = 2), the sulfided catalysts had similar texture (N₂ adsorption) and displayed similar activity in dibenzothiophene hydrodesulfurization (DBT HDS), while the activity of the Ni–W/SiO₂ catalyst in toluene hydrogenation (HYD) was six times higher than that of Ni–W/Al₂O₃. This is due to the more than two times higher WS₂ slabs stacking number in Ni–W/SiO₂ compared with Ni–W/Al₂O₃ (XRD, HR-TEM), yielding stronger adsorption of toluene (TPD).