兆瓦级风电球铁件低温冲击韧性的影响因素

为了获得具有良好低温冲击性能的兆瓦级风电球铁铸件,对实际生产中的附铸试件-20℃ V型缺口冲击性能进行了测试,并对其成分、基体组织、石墨球大小及分布情况进行分析,研究了兆瓦级风力发电机组球铁件低温冲击韧性影响因素.结果表明：在低P、S的前提下,通过合理的熔炼工艺控制,终Si量在2.3%时可以使单位面积的石墨球数量增加,石墨球细小,低温冲击值最佳;Mn在0.2%~0.3%之间变化时对低温冲击韧性影响并不明显;基体组织中珠光体在5%以下时,低温冲击值无明显变化,珠光体大于12.5%时,低温冲击值急剧下降.     

膨胀石墨的饱和吸附量与微观结构的关系

采用不同的方法测定膨胀石墨对不同油质的饱和吸附量,来探讨膨胀石墨的结构与饱和吸附量的关系.由扫描电镜可知,膨胀石墨具有较大的比表面积,其孔结构是以中、大孔为主;蠕虫石墨的表面结构与其内部结构不同,其内部为典型的片层结构.通过观察石墨内部孔结构特征变化,可以分析膨胀石墨对油的去除效率以及影响因素.     

天然鳞片石墨在水中的分散性研究

利用ζ电位、润湿性、沉降性、流变学测试研究了表面活性剂、表面包覆Al(OH)3对天然鳞片石墨在水中分散性的影响。结果表明：经过表面活性剂处理和Al(OH)3表面包覆能使石墨在水中的分散性能得以改善，石墨在水中的分散性取决于石墨与水的润湿性。     

膨胀石墨在聚乙烯中阻燃协效作用的研究

以膨胀石墨(EG)与聚磷酸铵(APP)复配组成膨胀型阻燃剂，应用于高密度聚乙烯(PE-HD)中。热分析表明APP／FG的添加使得PE-HD材料的热稳定性增强，降解过程变缓，剩炭率增加。氧指数(LOI)结果表明APP／EG具有良好的阻燃协同作用。扫描电镜(SEM)显示APP／EG的加入可使得PE-HD样品生成连续致密的炭层。同时力学性能研究表明APP／EG对材料的力学性能的影响比其它膨胀型阻燃剂要小。     

Mechanism of Fume Suppression and Performance on Asphalt of Expanded Graphite for Pavement under High Temperature Condition

Fume suppression mechanisms and the effect of expanded graphite on the performance of asphalt were studied by applying infrared spectroscopy(FT-IR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and comprehensive thermal analysis(TG, DSC). The experimental results confirm that asphalt which is mixed with expandable graphite will expand in the process of hot mix, and the expanded graphite layer will swell by the light component in the asphalt. The light component in the asphalt and PAHs adsorption on expanded graphite surface or part of the plug in the expanded graphite layer between plates made nucleation crystallization growth. And the Van der Waals force and the bonding of the lattice can effectively restrain the asphalt fume release. Meanwhile, the expanding agent with oxidative can spread into the asphalt, leading to asphalt oxygenated and plastic abate, while the ductility decreases. Expanded graphite, SBS modifier and environment- friendly plasticizers are used to composite modified asphalt. According to asphalt fume release experiment, normal test of asphalt performance, Brookfield viscosity test, RTFOT test and asphalt mixture tests(high temperature stability, low temperature stability, water stability), it has been proven that the modified asphalt's performance is better than that of matrix asphalt and equivalent to that of SBS modified asphalt. Furthermore, it has good fume suppression effect.     

改性UHMWPE塑料的摩擦磨损性能研究

分别研究MoS2、PTFE和石墨对UHMWPE耐摩擦性能的影响。结果表明:在载荷200 N,转速400 r/min的试验条件下,UHMWPE/石墨、UHMWPE、UHMWPE/MoS2和UHMWPE/PTFE的平均摩擦系数分别为0.27,0.30,0.35和0.39。掺杂石墨(质量分数9%)降低了UHMWPE的摩擦系数,在试验过程中减少了由于摩擦而产生的热量,从而提高了UHMWPE/石墨复合材料的耐磨性能。     

提高离心球墨铸铁管水泥内衬质量的方法

分析影响离心球墨铸铁管水泥内衬质量的因素,对水泥内衬质量不稳定,内衬层厚度不均匀,水泥中间起泡,衬层密实度不够,内裂、离鼓严重,衬层内壁有泪痕等质量缺陷,针对性地采取措施,加强人力资源管理和考核,对承口挡轮、托压轮、搅拌机等相应设备进行改造,对养生池进行扩建,攻关后水泥衬层一级品率由原来的64%提升到99%,取得了预期的效果。     

用含Pb、As、Sn地方生铁砂型铸造生产D型石墨铸铁的研究

基于Ph、As、Sn等元素有增大铁液过冷倾向的作用，利用含Ph、As、Sn的地方生铁，采用合金化和砂型铸造可以获得D型石墨铸铁，对其工艺方案进行了研究。用正交试验法设计试验方案，得到最佳工艺方案为：在亚共晶成分（WB％：3．2C，2．1si）的铁液中加入适量的铝（0．6％）和钛（0．8％），可以得到含有100％D型石墨的铸铁，其抗拉强度最高可达276MPa。     

稀土对D型石墨铸铁强化机理的研究

通过试验研究,发现微量稀土能促进D型石墨铸铁中初晶奥氏体骨架的生长,对强化基体组织有一定的作用。微量稀土能细化D型石墨,石墨数量增多,石墨生长前端钝化、分枝、花瓣状形态也有所改善,大大减轻了石墨对基体的破坏作用,从而提高D型石墨铸铁的力学性能。     

Characteristics of graphite felt electrode electrochemically oxidized for vanadium redox battery application

The graphite felt was oxidized at a positive electrode potential in sulfuric acid solution.The electrochemical performance of the treated graphite felt served as electrode for vanadium redox battery was investigated with FT-IR,SEM,XPS,BET,cyclic voltammetry and testing VRB system,respectively.The results show that the molar ratio of O to C increases from 0.085 to 0.15 due to the increase of—COOH functional groups during electrochemical oxidation treatment,and the GF surface is eroded by electrochemical oxidation,resulting in the surface area increase from 0.33 m2/g to 0.49 m 2/g.The VRB with modified GF electrode exhibits excellent performance under a current density of 30 mA/cm 2 .The average current efficiency reaches 94%and average voltage efficiency reaches 85%.The improvement of electrochemical activity for the electrode is ascribed to the increase of the number of—COOH group and the special surface of GF.