非金刚石相碳成分对金刚石薄膜晶形的影响

应用Raman光谱和SEM方法研究了在用热丝CVD方法生长金刚石薄膜中,生长膜中非金刚石相碳成分对金刚石晶粒晶形的影响。还讨论了生长条件如碳源浓度、衬底温度等对生长膜中非金刚石相碳成分的影响     

石墨表面状态及加入方式对制备Al-Ti-C晶粒细化剂的影响

采用不同表面状态的石墨粉和以不同方式加入到Al-Ti合金的方法来制备Al-Ti-C晶粒细化剂。采用金相显微镜观察了Al-Ti-C合金的微观组织，采用Leco装置检测了Al-Ti-C合金中的碳含量。结果表明，在制备Al-Ti-C合金过程中,石墨表面经预处理后可以提高石墨收得率，在石墨粉中掺入铝粉及添加剂R能急剧提高石墨的收得率。     

蠕墨铸铁喂线蠕化处理工艺的研究

研究喂线蠕化处理工艺生产蠕墨铸铁的可行性,通过试验分析了蠕化芯线的化学成分及加入量对蠕化率的影响,确定了喂线蠕化的工艺参数.试验还通过对喂线法和冲入法的比较,体现出喂线工艺在生产中的优势.结果表明,喂线蠕化处理工艺可行,蠕化情况良好,蠕化率稳定.     

铸铁孕育处理时的石墨核心研究

将铁水用75FeSi孕育后液淬,终止其溶解过程,在溶解区中出现已经生长石墨相的非金属夹杂物,它们随后又溶回铁水中去.但已经复盖有石墨相的晶核能存在较长的时间孕育剂的作用是提供一个碳的过冷溶液,使位于其中的非金属夹杂物活化成为晶核     

Effect of gas composition on cementite decomposition and coke formation on iron

Cementite decomposition and coke formation in the metal dusting process of iron were investigated at 700 °C in CO-H₂-H₂O gas mixtures. The presence of graphite deposited on the surface initiates the decomposition of cementite into iron and graphite. The morphology of the reaction products varies with gas composition. For CO concentrations less than 5 vol%, particles of iron or even closed iron layers have been observed at the cementite/graphite interface. With increasing CO content the amount of iron in the interface decreases. At CO concentrations higher than 30 vol%, iron could not be detected at the interface by optical microscopy. Thermo-gravimetric analysis shows that the rate of carbon take-up increases with increasing CO concentration reaching a maximum at about 60-75 vol%.The morphologies of graphite in the coke layer can be identified as three types: porous graphite clusters with embedded iron-containing particles, compact bulk graphite with a uniform thickness and a columnar layered structure, and filamentous carbon with iron-containing phases at the tip or along its length. For gas mixtures with low CO concentrations, e.g. 5 vol%, porous graphite clusters are the main form of carbon although filamentous carbon can be seen at the early stage of reaction. With increasing CO concentrations to, e.g. 30 vol%, a compact bulk graphite is formed on the top of the surface. Under this compact graphite, there is an inner layer of graphite which is the combination of porous graphite clusters and filaments. These two layers of graphite are clearly distinguishable when CO content reaches more than 75 vol%. In this case, the main form of graphite in the inner layer is filamentous carbon. The compact graphite layer suffers a serious deformation and forms many cracks because of the growth of catalytic filamentous carbon underneath. These filaments grow outside from compact graphite crevices and finally cover the whole surface. The higher the CO content in the gas, the more the tendency of filamentous carbon formation. The interplay between morphologies of carbon formation and metal dusting has been discussed.     

20寸锆右球阀铸造工艺研究

本文针对结构尺寸较大的20寸Zr702C右球阀铸件进行了铸造工艺研究。采用了机加工石墨型真空铸造方法,进行了顶注式与底注式两种浇注工艺方式比对,对较为合理的底注加顶部冒口的浇注工艺进行分析与工艺调整,通过控制金属过热度与加大铸型排气力度成功制造出了符合图纸尺寸及技术要求的Zr702C右球阀铸件。     

球铁塑性变形中石墨球变形行为的观察与分析

用光镜和电镜对球铁不同变形条件下石墨球的变形形貌进行观察和分析,揭示了石墨球的变形行为和影响因素。     

Effect of solid fraction on steel-mushy Cu-graphite pressing bonding

The pressing bonding of steel plate to QTi3.5-3.5graphite slurry was studied. The bonding conditions were 620℃ for preheating temperature of steel plate, 530℃ for preheating temperature of dies, 50 MPa for pressure and 2 min for pressing time. The relationship between the solid fraction of QTi3.5-3.5graphite slurry and the interracial mechanical property of bonding plate was obtained. The results show that when the solid fraction of QTi3.5-3.5graphite slurry is smaller than 45.8%, the interracial shear strength of bonding plate increases with the increasing of solid fraction. When the solid fraction is larger than 45.8%, the interracial shear strength decreases with the increasing of solid fraction. When the solid fraction is 45.8%, the largest interracial shear strength of bonding plate 127 MPa can be got, and the interface is made up of Fe-Cu solid solution.     

基体组织对球铁抗热疲劳性能的影响

研究了不同基体组织对球墨铸铁抗热疲劳性能的影响.结果表明:铁素体基体球铁的抗热疲劳性能最好,复相基体组织不利于提高球铁的抗热疲劳性能.     

扁锭结晶器的故障诊断及排除方法

从国外引进的低液位组合结晶器，内置水套，石墨环镶嵌在结晶器四周内壁上，分上下两级水道。在铸造中，由于水质原因会造成喷水水眼堵塞，人为因素也会造成石墨环损坏，结晶器缺陷会造成铸造缺陷，严重时会生产不合格产品。从生产实践出发，对结晶器故障诊断、排除及日常维护技术进行了研究。