全文获取类型
收费全文 | 110459篇 |
免费 | 11300篇 |
国内免费 | 6442篇 |
专业分类
电工技术 | 8191篇 |
技术理论 | 9篇 |
综合类 | 8313篇 |
化学工业 | 28261篇 |
金属工艺 | 7747篇 |
机械仪表 | 4877篇 |
建筑科学 | 7771篇 |
矿业工程 | 4250篇 |
能源动力 | 2556篇 |
轻工业 | 7634篇 |
水利工程 | 3194篇 |
石油天然气 | 6600篇 |
武器工业 | 1209篇 |
无线电 | 9744篇 |
一般工业技术 | 11941篇 |
冶金工业 | 6252篇 |
原子能技术 | 1309篇 |
自动化技术 | 8343篇 |
出版年
2024年 | 373篇 |
2023年 | 1383篇 |
2022年 | 2560篇 |
2021年 | 3342篇 |
2020年 | 3510篇 |
2019年 | 3011篇 |
2018年 | 2921篇 |
2017年 | 3535篇 |
2016年 | 4110篇 |
2015年 | 4184篇 |
2014年 | 6645篇 |
2013年 | 6098篇 |
2012年 | 7973篇 |
2011年 | 8572篇 |
2010年 | 6154篇 |
2009年 | 6571篇 |
2008年 | 5873篇 |
2007年 | 7540篇 |
2006年 | 6899篇 |
2005年 | 6021篇 |
2004年 | 4975篇 |
2003年 | 4610篇 |
2002年 | 4007篇 |
2001年 | 3450篇 |
2000年 | 2908篇 |
1999年 | 2382篇 |
1998年 | 1742篇 |
1997年 | 1274篇 |
1996年 | 1152篇 |
1995年 | 927篇 |
1994年 | 800篇 |
1993年 | 559篇 |
1992年 | 466篇 |
1991年 | 344篇 |
1990年 | 269篇 |
1989年 | 199篇 |
1988年 | 160篇 |
1987年 | 106篇 |
1986年 | 77篇 |
1985年 | 80篇 |
1984年 | 65篇 |
1983年 | 33篇 |
1982年 | 38篇 |
1981年 | 38篇 |
1980年 | 40篇 |
1979年 | 27篇 |
1978年 | 16篇 |
1966年 | 11篇 |
1964年 | 29篇 |
1959年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Electrical Breakdown Properties and Space Charge Formation in High Temperature Region in Ultraviolet Ray Irradiated PVC
下载免费PDF全文
![点击此处可从《Electrical Engineering in Japan》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Polyvinyl chloride (PVC) is the most popular insulating material for electric wiring instruments. However, an exothermic reaction above 150 °C may cause deterioration of the insulating properties of PVC. Therefore, it is important to clarify the heat degradation in PVC, not only to investigate the ignition of electrical wiring products but also to use electrical products safely. It is known that ultraviolet (UV) irradiation causes chemical deterioration of PVC and an increase in its conductivity. Generally, it has been thought that the electrical breakdown properties, electrical conduction, and insulating performance are affected by space charge accumulation in an insulating material. A high temperature pulsed electroacoustic (PEA) system usable up to 250 °C has been developed, and the PEA system can measure the space charge distribution and conduction current in the high temperature range simultaneously. In this investigation, the space charge distribution and conduction current were measured up to electrical breakdown in a non‐UV irradiated sample (normal PVC) and in 353 nm and 253 nm UV‐irradiated PVC samples in the range from room temperature to 200 °C in a DC electric field. In the short wavelength UV irradiated PVC sample (253 nm, 300 h), a deterioration of breakdown strength at 90 °C to 150 °C and negative packet‐like charges were observed at 60 °C and 100 °C, a positive charge accumulated in front of both the anode and cathode above 90 °C, and a higher electric field near the cathode side because the positive charge of the cathode side was greater. 相似文献
52.
In this study, we have proposed an automated classification approach to identify meaningful patterns in wind field data. Utilizing an extensive simulated wind database, we have demonstrated that the proposed approach can identify low‐level jets, near‐uniform profiles, and other patterns in a reliable manner. We have studied the dependence of these wind profile patterns on locations (eg, offshore vs onshore), seasons, and diurnal cycles. Furthermore, we have found that the probability distributions of some of the patterns depend on the underlying planetary boundary layer schemes in a significant way. The future potential of the proposed approach in wind resource assessment and, more generally, in mesoscale model parameterization improvement is touched upon in this paper. 相似文献
53.
54.
《能源学会志》2020,93(6):2381-2387
To enhance the activity of catalysts for CO removal, the perovskite-type catalysts La1-xSrxCoO3 (x = 0, 0.2, 0.4, 0.6, and 0.8) with different Sr2+ doping amount were synthesized by flame spray synthesis (FSS) method. The perovskite-type catalyst synthesized by FSS has a much larger specific surface area (SSA) than that prepared by other conventional methods. The SSA of catalyst increases with the increase of Sr2+ doping amount and the SSA of La0.2Sr0.8CoO3 reaches 31.65 m2/g. Compared with other conventional methods, FSS method significantly improves the activity of catalyst and makes it close to the performances of catalysts with surface modification. The substitution of La3+ by Sr2+ promotes the generation of secondary phase Co3O4 and SrCO3. The catalytic activity of La1-xSrxCoO3 increases with the addition of Sr2+, which results from the increasing active sites and oxygen vacancies. Interestingly, La0.4Sr0.6CoO3 performs the highest activity for CO oxidation and the CO conversion reaches 50% at 148.6 °C and 90% at 165.9 °C. The oxidation of CO over La1-xSrxCoO3 catalyst may follow a combination of MvK and L-H mechanisms according to the experimental results of H2-TPR. Moreover, the catalyst exhibits good catalytic activity in consecutive oxidation cycles. In consecutive oxidation experiments with La0.4Sr0.6CoO3, the CO conversion reaches 50% at 168.8 °C and 90% at 197.8 °C in the eighth oxidation cycle. These results prove that FSS method can further improve the activity of catalysts and is suitable for the preparation of efficient catalysts. 相似文献
55.
A novel synthetic route has been proposed to prepare hausmannite nanoparticles. The synthetic route comprises an iron mediated constant current cathodic electrodeposition of manganite and heat treatment of the latter to obtain hausmannite. The obtained nanostructures have been characterized using X-ray Diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and Fourier transform Infrared Spectrometry (FTIR). The role of iron in the formation of manganite precursor has been studied by cyclic voltammetry (CV) and differential thermal analysis (DTA). A formation mechanism based on iron mediated formation of Mn3+ and subsequent cathodic reduction of the disproportionated products has been proposed accordingly. The prepared nanoparticles exhibited specific capacitance of 143 F g−1 in 0.5 M Na2SO4 solution. The retained specific capacity was 87% after 2000 cycles. 相似文献
56.
为了实现对微小环片零件的自动化装配,搭建了自动装配系统.通过4根直线导向轴与4个直线轴承来提高系统的导向精度和刚度.采用直线导轨进行各装配作业模块之间的切换,保证了微小环片零件的自动装配与取出.在环片的装配方向上,螺旋升降机和光栅尺实现环片的位置精度控制.在Lab VIEW编程环境中,采用分层软件架构和模块化控制思想,避免了不必要的数据循环检测与丢失,能够达到环片组件的装配精度要求.控制系统分为系统初始化模块、参数设置模块、装配模块和取出模块,自动装配系统通过各个模块间的相互交流配合完成装配任务.采用本文中自动装配系统装配环片的实验结果表明,环片零件装配的最大位置误差为26μm,垂直度误差为17μm,平均装配时间为75 s/片,可满足环片组件所需的精度要求. 相似文献
57.
为了寻找抗菌候选化合物,采用基于片段的药物发现方法,以氨基膦酸酯和磺酰氯为原料,设计合成了15个含膦酸酯结构单元的磺胺衍生物,经IR、1HNMR和13CNMR确认结构。采用两倍稀释法测定目标化合物的MIC(最小抑菌浓度)。结果表明:部分目标化合物呈潜在的抗菌活性,对所测试标准菌和耐药菌均有抑制活性。其中,化合物Ⅱf〔N-[(二乙氧基膦酰基)-4-氟苯甲基]-4-甲氧基苯磺酰胺〕对金黄色葡萄球菌(S. aureus)、大肠埃希菌(E. coli)、耐甲氧西林金黄色葡萄球菌(MRSA)及耐氟喹诺酮类大肠杆菌(MREC)的MIC分别为32、64、128和128μg/mL,化合物Ⅱl〔N-[(二乙氧基膦酰基)-4-氟苯甲基]-4-氟苯磺酰胺〕对S. aureus、E. coli、MRSA及MREC的MIC分别为32、32、64和64μg/mL,抗菌活性优于对照药磺胺嘧啶。 相似文献
58.
《International Journal of Hydrogen Energy》2020,45(27):13975-13984
An intervening barrier for photocatalytic water decomposition and pollutant degradation is the frustratingly quick recombination of e− - h+ pairs. Delicate design of heterojunction photocatalysts by coupling the semiconductors at nanoscale with well-matched geometrical and electronic alignments is an effective strategy to ameliorate the charge separation. Here a facile and environment-friendly l-cysteine-assisted hydrothermal process under weakly alkaline conditions is demonstrated for the first time to fabricate ZnIn2S4/In(OH)3 hollow microspheres with intimate contact, which are verified by XRD, SEM, (HR)TEM, XPS, N2 adsorption-desorption, UV–Vis DRS and photoluminescence spectra. ZnIn2S4/In(OH)3 heterostructure (L-cys/Zn2+ = 4, molar ratio) with a band-gap of 2.50 eV, demonstrates the best photocatalytic performance for water reduction and MB degradation under visible light, outperforming its counterparts (In(OH)3 and ZnIn2S4). The excellent activity of ZnIn2S4/In(OH)3 heterostructure arises from the intercrossed band-edge positions as well as the unique hollow structure with large surface area and wide pore-size distribution, which are beneficial for the efficient charge migration from bulk to surface as well as at the interface between ZnIn2S4 and In(OH)3. This work provides an efficient and eco-friendly strategy for one-pot synthesis of heterostructured composites with intimate contact for photocatalytic application. 相似文献
59.
Dr. Vlastimil Jirasko Dr. Nils-Alexander Lakomek Dr. Susanne Penzel Dr. Marie-Laure Fogeron Prof. Dr. Ralf Bartenschlager Prof. Dr. Beat H. Meier Dr. Anja Böckmann 《Chembiochem : a European journal of chemical biology》2020,21(10):1453-1460
Proton-detected 100 kHz magic-angle-spinning (MAS) solid-state NMR is an emerging analysis method for proteins with only hundreds of microgram quantities, and thus allows structural investigation of eukaryotic membrane proteins. This is the case for the cell-free synthesized hepatitis C virus (HCV) nonstructural membrane protein 4B (NS4B). We demonstrate NS4B sample optimization using fast reconstitution schemes that enable lipid-environment screening directly by NMR. 2D spectra and relaxation properties guide the choice of the best sample preparation to record 2D 1H-detected 1H,15N and 3D 1H,13C,15N correlation experiments with linewidths and sensitivity suitable to initiate sequential assignments. Amino-acid-selectively labeled NS4B can be readily obtained using cell-free synthesis, opening the door to combinatorial labeling approaches which should enable structural studies. 相似文献
60.